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Citation: WANG Ying, LIU Wen-yuan, FU Zheng-wen. Electrochemistry of Mn₄N with Lithium[J]. Acta Physico-Chimica Sinica, ;2006, 22(01): 65-70. doi: 10.3866/PKU.WHXB20060113 shu

Electrochemistry of Mn₄N with Lithium

1.
Shanghai Key Laboratory of Molecular Catalysts and Functional Materials, Department of Chemistry & Institute of Laser Chemistry, Fudan University, Shanghai 200433, P. R. China

Received Date: 16 May 2005
Available Online: 15 January 2006

A new thin film composed of transition metal nitride of Mn₄N has been fabricated successfully by using reactive pulsed laser deposition and DC discharge methods in nitrogen ambient. The electrochemical reaction of the Mn₄N thin film electrode with Li was firstly investigated by the discharge/charge, cyclic voltammetry, and AC impedance spectroscopy measurements. Mn₄N thin film exhibited 420 mAh•g^-1 in the first discharge process, and a nearly 50% irreversible capacity loss occurred in the first cycle. X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were used to characterize the structure, morphology, and composition of the as-deposited, lithiated, and delithiated Mn₄N thin films. The reversible reaction of the Mn₄N thin film with lithium may involve partial conversion of metal Mn and Li₃N into Mn₄N. It should be responsible for the large capacity loss between the first and the second discharges.
- Pulsed laser deposition;Li ion batteries;Mn₄N;Thin films
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沈阳化工大学材料科学与工程学院沈阳 110142

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Electrochemistry of Mn₄N with Lithium