{"进展评述":[{"abstractInfo":"细胞是生物体基本的结构和功能单元，对活细胞中特定生物组分进行动态分析，将为相关生命活动过程的研究提供重要信息。荧光成像为细胞分析提供了一种操作简单、灵敏度高、可实时监测细胞微观动态分子过程的光学生物成像技术。发展高性能的荧光探针用于活细胞成像已成为研究热点。功能核酸是一类具有特殊化学和生物学功能的寡核苷酸分子，除了天然存在的核酶（Ribozyme）和核糖开关（Riboswitch）之外，还包括通过指数富集的配体系统进化技术（SELEX）筛选获得的核酸适体和脱氧核酶（DNAzyme）。功能核酸由于具有合成简单、免疫原性低、相对分子质量小、化学稳定性高、易于修饰等优点，在生物成像领域受到广泛关注。本文主要综述了基于功能核酸的荧光探针在细胞成像领域中的应用研究，总结了该领域面临的挑战，并对其未来发展方向进行了展望。","abstractInfoCn":"细胞是生物体基本的结构和功能单元，对活细胞中特定生物组分进行动态分析，将为相关生命活动过程的研究提供重要信息。荧光成像为细胞分析提供了一种操作简单、灵敏度高、可实时监测细胞微观动态分子过程的光学生物成像技术。发展高性能的荧光探针用于活细胞成像已成为研究热点。功能核酸是一类具有特殊化学和生物学功能的寡核苷酸分子，除了天然存在的核酶（Ribozyme）和核糖开关（Riboswitch）之外，还包括通过指数富集的配体系统进化技术（SELEX）筛选获得的核酸适体和脱氧核酶（DNAzyme）。功能核酸由于具有合成简单、免疫原性低、相对分子质量小、化学稳定性高、易于修饰等优点，在生物成像领域受到广泛关注。本文主要综述了基于功能核酸的荧光探针在细胞成像领域中的应用研究，总结了该领域面临的挑战，并对其未来发展方向进行了展望。","abstractInfoEn":"Cell is the structural and functional unit of organisms. Studying the spatiotemporal distribution and activity of specific biomolecules in living cells would provide valuable information in understanding various biological processes. Fluorescence imaging technology has showed great potential for live-cell imaging. On the other hand, development of high-performance fluorescent probes has become a major bottleneck in this field. Functional nucleic acids (FNAs) are a class of oligonucleotides with specific chemical and/or biological functions, including natural ribozymes and riboswitches, as well as aptamers and DNAzymes screened through the SELEX (systematic evolution of ligands by exponential enrichment) technique. Taking advantages of simple synthesis, low immunogenicity, small size, high chemical stability, easy modification, FNAs have received extensive attention in the fields of bio-analysis and bio-imaging. This review summarizes the recent applications of FNA in fluorescence cell imaging, and points out the challenges and future prospects in this field.","articleNo":"hxtb-84-2-98","authorCnList":["寻看雨"," 孙悦"," 张悦"," 邱丽萍"],"authorEnList":["Kanyu Xun"," Yue Sun"," Yue Zhang"," Liping Qiu"],"authorList":["寻看雨"," 孙悦"," 张悦"," 邱丽萍"],"authors":"寻看雨, 孙悦, 张悦, 邱丽萍","authorsCn":"寻看雨, 孙悦, 张悦, 邱丽萍","authorsEn":"Kanyu Xun, Yue Sun, Yue Zhang, Liping Qiu","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"寻看雨, 孙悦, 张悦, 邱丽萍. 基于功能核酸的细胞荧光成像. 化学通报, 2021, 84(2): 98-107.","citationCn":"寻看雨, 孙悦, 张悦, 邱丽萍. 基于功能核酸的细胞荧光成像. 化学通报, 2021, 84(2): 98-107.","citationEn":"寻看雨, 孙悦, 张悦, 邱丽萍. Functional Nucleic Acid-Based Fluorescence Cell Imaging. Chemistry, 2021, 84(2): 98-107.","doi":"","figContent":"hxtb-84-2-98-1.jpg$$hxtb-84-2-98-2.jpg$$hxtb-84-2-98-3.jpg$$hxtb-84-2-98-4.jpg$$hxtb-84-2-98-5.jpg$$hxtb-84-2-98-6.jpg$$hxtb-84-2-98-7.jpg$$hxtb-84-2-98-8.jpg","figList":["hxtb-84-2-98-1.jpg","hxtb-84-2-98-2.jpg","hxtb-84-2-98-3.jpg","hxtb-84-2-98-4.jpg","hxtb-84-2-98-5.jpg","hxtb-84-2-98-6.jpg","hxtb-84-2-98-7.jpg","hxtb-84-2-98-8.jpg"],"firstFig":"hxtb-84-2-98-1.jpg","fpage":"98","highCitedState":"","htmlCount":709,"htmlFile":"","id":"efc61116-3c30-4d01-bc57-ed6355b128bd","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"功能核酸, 荧光探针, 细胞成像, 生化分析","keywordCn":"功能核酸, 荧光探针, 细胞成像, 生化分析","keywordCnList":["功能核酸"," 荧光探针"," 细胞成像"," 生化分析"],"keywordEn":"Functional nucleic acids, Fluorescence probe, Cell imaging, Bioanalysis","keywordEnList":["Functional nucleic acids"," Fluorescence probe"," Cell imaging"," Bioanalysis"],"keywordList":["功能核酸"," 荧光探针"," 细胞成像"," 生化分析"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"107","oldUrl":"","pdfDownCount":30,"pdfSize":11490.39,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"基于功能核酸的细胞荧光成像","titleCn":"基于功能核酸的细胞荧光成像","titleEn":"Functional Nucleic Acid-Based Fluorescence Cell Imaging","viewCount":2336,"volume":"84","year":2021},{"abstractInfo":"二氧化钛在光电转化、光催化等众多领域具有重要的应用价值，但较宽的禁带宽度和较低的电子传递效率导致其光利用率较低。离子掺杂和纳米化是改变其能带结构、提高电子传输能力的有效策略，根据掺杂离子的性质，可分为金属离子掺杂和非金属元素掺杂。与传统二氧化钛相比，纳米二氧化钛具有特殊的表面效应和粒度效应，其化学活性、耐热性等都强于传统二氧化钛。本文主要对非金属元素掺杂纳米二氧化钛的研究进行评述，包括ⅢA、ⅣA、ⅤA、ⅥA、ⅦA族元素的单一元素掺杂以及和金属或非金属元素共掺杂，重点介绍了纳米二氧化钛的非金属掺杂与其能带结构、可见光响应和光催化性能之间的关系及其应用情况，并对其未来的发展趋势进行了展望。","abstractInfoCn":"二氧化钛在光电转化、光催化等众多领域具有重要的应用价值，但较宽的禁带宽度和较低的电子传递效率导致其光利用率较低。离子掺杂和纳米化是改变其能带结构、提高电子传输能力的有效策略，根据掺杂离子的性质，可分为金属离子掺杂和非金属元素掺杂。与传统二氧化钛相比，纳米二氧化钛具有特殊的表面效应和粒度效应，其化学活性、耐热性等都强于传统二氧化钛。本文主要对非金属元素掺杂纳米二氧化钛的研究进行评述，包括ⅢA、ⅣA、ⅤA、ⅥA、ⅦA族元素的单一元素掺杂以及和金属或非金属元素共掺杂，重点介绍了纳米二氧化钛的非金属掺杂与其能带结构、可见光响应和光催化性能之间的关系及其应用情况，并对其未来的发展趋势进行了展望。","abstractInfoEn":"Titanium dioxide attracts great attentions for its important applications in many fields, especially in photoelectronic conversion and photocatalysis due to its excellent light stability, non-toxicity and easy preparation. However, its relatively poor charge transport property and wide bandgap are two main limitations for its extensive application in light-responsive materials. To meet such challenges, two strategies including ion doping and going nanoscale are used and demonstrated to be effective in regulating its band gap structure and charge transport behavior. Ion doping can be divided into two categories, metal doping and nonmetal doping, according to the properties of the impurity elements. Besides, compared with traditional titanium dioxide, nano-sized titanium dioxide possesses larger surface areas and special nanosized effect, resulting in higher chemical activity and heat resistance. In this review, we focused on the research progress of non-metallic element doped titanium dioxide. Emphases was put on the relationship within the doping element, the band gap structure, visible light responsibility and photocatalytic performance of the hybrid titanium dioxide. Additionally, the application of non-metallic element doped titanium dioxide was also involved.","articleNo":"hxtb-84-2-108","authorCnList":["刘方园"," 徐鲁艺"," 修阳"," 王生杰"],"authorEnList":["Fangyuan Liu"," Luyi Xu"," Yang Xiu"," Shengjie Wang"],"authorList":["刘方园"," 徐鲁艺"," 修阳"," 王生杰"],"authors":"刘方园, 徐鲁艺, 修阳, 王生杰","authorsCn":"刘方园, 徐鲁艺, 修阳, 王生杰","authorsEn":"Fangyuan Liu, Luyi Xu, Yang Xiu, Shengjie Wang","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"刘方园, 徐鲁艺, 修阳, 王生杰. 非金属元素掺杂纳米二氧化钛. 化学通报, 2021, 84(2): 108-119, 148.","citationCn":"刘方园, 徐鲁艺, 修阳, 王生杰. 非金属元素掺杂纳米二氧化钛. 化学通报, 2021, 84(2): 108-119, 148.","citationEn":"刘方园, 徐鲁艺, 修阳, 王生杰. Non-Metallic Element Doped Titanium Dioxide. Chemistry, 2021, 84(2): 108-119, 148.","doi":"","figContent":"hxtb-84-2-108-1.jpg$$hxtb-84-2-108-2.jpg$$hxtb-84-2-108-3.jpg$$hxtb-84-2-108-4.jpg$$hxtb-84-2-108-5.jpg$$hxtb-84-2-108-6.jpg$$hxtb-84-2-108-7.jpg$$hxtb-84-2-108-8.jpg$$hxtb-84-2-108-9.jpg","figList":["hxtb-84-2-108-1.jpg","hxtb-84-2-108-2.jpg","hxtb-84-2-108-3.jpg","hxtb-84-2-108-4.jpg","hxtb-84-2-108-5.jpg","hxtb-84-2-108-6.jpg","hxtb-84-2-108-7.jpg","hxtb-84-2-108-8.jpg","hxtb-84-2-108-9.jpg"],"firstFig":"hxtb-84-2-108-1.jpg","fpage":"108","highCitedState":"","htmlCount":749,"htmlFile":"","id":"0ccb562d-2ef9-4e26-8a01-4060271e42a2","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"二氧化钛, 非金属元素掺杂, 能带结构, 光电转化, 光催化","keywordCn":"二氧化钛, 非金属元素掺杂, 能带结构, 光电转化, 光催化","keywordCnList":["二氧化钛"," 非金属元素掺杂"," 能带结构"," 光电转化"," 光催化"],"keywordEn":"Titanium dioxide, Non-metal doping, Band gap structure, Photoelectric conversion, Photocatalysis","keywordEnList":["Titanium dioxide"," Non-metal doping"," Band gap structure"," Photoelectric conversion"," Photocatalysis"],"keywordList":["二氧化钛"," 非金属元素掺杂"," 能带结构"," 光电转化"," 光催化"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"119, 148","oldUrl":"","pdfDownCount":35,"pdfSize":7898.1,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"非金属元素掺杂纳米二氧化钛","titleCn":"非金属元素掺杂纳米二氧化钛","titleEn":"Non-Metallic Element Doped Titanium Dioxide","viewCount":2992,"volume":"84","year":2021},{"abstractInfo":"钌催化剂是近年来新兴的贵金属催化剂，其负载型催化剂具有节约成本、可回收利用、催化性能优异等优势，受到研究人员的广泛关注。本文对负载型钌基催化剂在氨合成反应、加氢反应、氧化反应的合成及应用进行了综述，主要阐述了反应过程中的载体与助剂、制备方法和催化性能，并对当前反应中存在的问题进行归纳和总结，最后提出负载型钌基催化剂现阶段亟需解决的问题以及对未来的主要发展趋势进行了展望。","abstractInfoCn":"钌催化剂是近年来新兴的贵金属催化剂，其负载型催化剂具有节约成本、可回收利用、催化性能优异等优势，受到研究人员的广泛关注。本文对负载型钌基催化剂在氨合成反应、加氢反应、氧化反应的合成及应用进行了综述，主要阐述了反应过程中的载体与助剂、制备方法和催化性能，并对当前反应中存在的问题进行归纳和总结，最后提出负载型钌基催化剂现阶段亟需解决的问题以及对未来的主要发展趋势进行了展望。","abstractInfoEn":"Ruthenium catalysts are emerging noble metal catalysts in recent years. Their supported catalysts have many advantages, such as low cost, recyclability and good catalytic performance, which has attracted extensive attention of researchers. The synthesis and application of supported ruthenium based catalysts in ammonia synthesis, hydrogenation and oxidation were reviewed. The support and promoters, preparation methods and catalytic performance in the reaction process were mainly described, and the existing problems in current reactions were summarized. Finally, the urgent problems to be solved at present and the main development trend in the future were proposed.","articleNo":"hxtb-84-2-120","authorCnList":["龙思宇"," 裴响林"," 罗丹"," 付海"," 龚维"],"authorEnList":["Siyu Long"," Xianglin Pei"," Dan Luo"," Hai Fu"," Wei Gong"],"authorList":["龙思宇"," 裴响林"," 罗丹"," 付海"," 龚维"],"authors":"龙思宇, 裴响林, 罗丹, 付海, 龚维","authorsCn":"龙思宇, 裴响林, 罗丹, 付海, 龚维","authorsEn":"Siyu Long, Xianglin Pei, Dan Luo, Hai Fu, Wei Gong","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"龙思宇, 裴响林, 罗丹, 付海, 龚维. 贵金属钌基催化剂合成及应用研究进展. 化学通报, 2021, 84(2): 120-128.","citationCn":"龙思宇, 裴响林, 罗丹, 付海, 龚维. 贵金属钌基催化剂合成及应用研究进展. 化学通报, 2021, 84(2): 120-128.","citationEn":"龙思宇, 裴响林, 罗丹, 付海, 龚维. Progress in the Synthesis and Application of Ruthenium-Based Catalysts. Chemistry, 2021, 84(2): 120-128.","doi":"","figContent":"hxtb-84-2-120-1.jpg$$hxtb-84-2-120-2.jpg$$hxtb-84-2-120-3.jpg$$hxtb-84-2-120-4.jpg$$hxtb-84-2-120-5.jpg$$hxtb-84-2-120-6.jpg","figList":["hxtb-84-2-120-1.jpg","hxtb-84-2-120-2.jpg","hxtb-84-2-120-3.jpg","hxtb-84-2-120-4.jpg","hxtb-84-2-120-5.jpg","hxtb-84-2-120-6.jpg"],"firstFig":"hxtb-84-2-120-1.jpg","fpage":"120","highCitedState":"","htmlCount":3121,"htmlFile":"","id":"ccbdbf78-3018-457f-90a4-7840fa7f411b","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"贵金属钌, 负载催化剂, 氨合成, 加氢反应, 氧化反应","keywordCn":"贵金属钌, 负载催化剂, 氨合成, 加氢反应, 氧化反应","keywordCnList":["贵金属钌"," 负载催化剂"," 氨合成"," 加氢反应"," 氧化反应"],"keywordEn":"Precious metal ruthenium, Supported catalyst, Ammonia synthesis, Hydrogenation, Oxidation","keywordEnList":["Precious metal ruthenium"," Supported catalyst"," Ammonia synthesis"," Hydrogenation"," Oxidation"],"keywordList":["贵金属钌"," 负载催化剂"," 氨合成"," 加氢反应"," 氧化反应"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"128","oldUrl":"","pdfDownCount":163,"pdfSize":3553.59,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"贵金属钌基催化剂合成及应用研究进展","titleCn":"贵金属钌基催化剂合成及应用研究进展","titleEn":"Progress in the Synthesis and Application of Ruthenium-Based Catalysts","viewCount":7049,"volume":"84","year":2021},{"abstractInfo":"SAPO-34分子筛的制备方法及其合成因素是影响其晶体形貌、晶粒大小、酸性质和孔道结构等物化性质的重要因素，与分子筛的催化性能密切相关。本文对比分析了常规水热合成法、微波辅助合成法、干胶转化合成法和无溶剂合成法的优缺点，并重点介绍了模板剂、硅铝比、水铝比、硅源铝源和金属改性等制备参数对SAPO-34分子筛物化性质及催化性能的影响；简要总结了其在甲醇制低碳烯烃、氨选择性催化还原NO<sub><i>x<\/i><\/sub>和烃类催化裂解制低碳烯烃等催化应用中的进展。本文为设计和制备新型、高效SAPO-34分子筛提供一定的借鉴意义和研究思路。","abstractInfoCn":"SAPO-34分子筛的制备方法及其合成因素是影响其晶体形貌、晶粒大小、酸性质和孔道结构等物化性质的重要因素，与分子筛的催化性能密切相关。本文对比分析了常规水热合成法、微波辅助合成法、干胶转化合成法和无溶剂合成法的优缺点，并重点介绍了模板剂、硅铝比、水铝比、硅源铝源和金属改性等制备参数对SAPO-34分子筛物化性质及催化性能的影响；简要总结了其在甲醇制低碳烯烃、氨选择性催化还原NO<sub><i>x<\/i><\/sub>和烃类催化裂解制低碳烯烃等催化应用中的进展。本文为设计和制备新型、高效SAPO-34分子筛提供一定的借鉴意义和研究思路。","abstractInfoEn":"The preparation methods and synthesis factors of SAPO-34 zeolites are important factors affecting its physicochemical properties such as crystal morphology, grain size, acidity and pore structure, which are closely related to the catalytic performance of SAPO-34 zeolites. In this paper, the advantages and disadvantages of conventional hydrothermal synthesis, microwave-assisted synthesis, dry gel conversion synthesis and solvent-free synthesis were compared and analyzed. The influences of preparation parameters such as template agent, Si/Al ratio, H<sub>2<\/sub>O/Al<sub>2<\/sub>O<sub>3<\/sub>, silicon source, aluminum source and metal modification on the physicochemical properties and catalytic performance of SAPO-34 zeolites were emphatically introduced. Its catalytic applications such as methanol to light olefins, ammonia selective catalytic reduction of NO<sub><i>x<\/i><\/sub> and hydrocarbon catalytic cracking to light olefins were briefly summarized. It provides some reference significance and research ideas for the design and preparation of new and efficient SAPO-34 zeolites.","articleNo":"hxtb-84-2-129","authorCnList":["许中亮"," 肖霞"," 赵震"," 孙兵"],"authorEnList":["Zhongliang Xu"," Xia Xiao"," Zhen Zhao"," Bing Sun"],"authorList":["许中亮"," 肖霞"," 赵震"," 孙兵"],"authors":"许中亮, 肖霞, 赵震, 孙兵","authorsCn":"许中亮, 肖霞, 赵震, 孙兵","authorsEn":"Zhongliang Xu, Xia Xiao, Zhen Zhao, Bing Sun","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"许中亮, 肖霞, 赵震, 孙兵. SAPO-34分子筛的制备及其催化应用研究进展. 化学通报, 2021, 84(2): 129-138.","citationCn":"许中亮, 肖霞, 赵震, 孙兵. SAPO-34分子筛的制备及其催化应用研究进展. 化学通报, 2021, 84(2): 129-138.","citationEn":"许中亮, 肖霞, 赵震, 孙兵. Advances in Preparation and Catalytic Applications of SAPO-34 Zeolites. Chemistry, 2021, 84(2): 129-138.","doi":"","figContent":"hxtb-84-2-129-1.jpg$$hxtb-84-2-129-2.jpg$$hxtb-84-2-129-3.jpg$$hxtb-84-2-129-4.jpg$$hxtb-84-2-129-5.jpg","figList":["hxtb-84-2-129-1.jpg","hxtb-84-2-129-2.jpg","hxtb-84-2-129-3.jpg","hxtb-84-2-129-4.jpg","hxtb-84-2-129-5.jpg"],"firstFig":"hxtb-84-2-129-1.jpg","fpage":"129","highCitedState":"","htmlCount":402,"htmlFile":"","id":"b8e082bb-9b12-4844-8417-37b01157a5dc","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"SAPO-34, 分子筛, 制备, 催化应用","keywordCn":"SAPO-34, 分子筛, 制备, 催化应用","keywordCnList":["SAPO-34"," 分子筛"," 制备"," 催化应用"],"keywordEn":"SAPO-34, Zeolites, Preparation, Catalytic application","keywordEnList":["SAPO-34"," Zeolites"," Preparation"," Catalytic application"],"keywordList":["SAPO-34"," 分子筛"," 制备"," 催化应用"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"138","oldUrl":"","pdfDownCount":11,"pdfSize":7247.81,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"SAPO-34分子筛的制备及其催化应用研究进展","titleCn":"SAPO-34分子筛的制备及其催化应用研究进展","titleEn":"Advances in Preparation and Catalytic Applications of SAPO-34 Zeolites","viewCount":1611,"volume":"84","year":2021},{"abstractInfo":"近年来，抗生素作为基本的治疗药物在医学、畜牧业、水产养殖业等方面被广泛应用，但其过量使用造成的抗生素残留问题也给生态环境、食品安全和人类健康造成严重的威胁。鉴于此，纳米电化学传感器在抗生素快速检测方面的研究成为热点，也取得了可观的进展。本文首先对抗生素进行了简单介绍，通过分析抗生素的电化学性质，综述了不同结构和类型的纳米电化学传感器在多种基质中检测抗生素的应用，以强调纳米材料构建电化学平台对抗生素检测的重要性，并对该领域的发展前景做了展望。","abstractInfoCn":"近年来，抗生素作为基本的治疗药物在医学、畜牧业、水产养殖业等方面被广泛应用，但其过量使用造成的抗生素残留问题也给生态环境、食品安全和人类健康造成严重的威胁。鉴于此，纳米电化学传感器在抗生素快速检测方面的研究成为热点，也取得了可观的进展。本文首先对抗生素进行了简单介绍，通过分析抗生素的电化学性质，综述了不同结构和类型的纳米电化学传感器在多种基质中检测抗生素的应用，以强调纳米材料构建电化学平台对抗生素检测的重要性，并对该领域的发展前景做了展望。","abstractInfoEn":"In recent years, antibiotics have been widely used as basic therapeutic drugs in medicine, animal husbandry, aquaculture industries and so on. However, we are now facing serious contamination of antibiotics (e.g., ecological environment and food) and the associated health concerns because of their uncontrolled disposal. In an effort to resolve this problem, nanostructured electrochemical platforms comprising of diverse materials have been proposed to rapidly detect antibiotic residues, and considerable progress has been made. Here, various nano-electrochemical sensors for detection of antibiotics residues are reviewed. The present review begins with a brief introduction to antibiotics followed by an analysis of the electrochemical properties of antibiotics. Then, the review summaries the application of existing nano-electrochemical platforms comprising of diverse nanostructured materials to highlight the significance of the nanomaterials for detection of antibiotics in diverse matrices. Finally, we provide an outlook on the future concepts of this research field to help upgrade the detecting techniques for antibiotics.","articleNo":"hxtb-84-2-139","authorCnList":["黄翠萍"," 黎杉珊"," 陆杜鹃"," 漆天乐"," 申光辉"," 张志清"],"authorEnList":["Cuiping Huang"," Shanshan Li"," Dujuan Lu"," Tianle Qi"," Guanghui Shen"," Zhiqing Zhang"],"authorList":["黄翠萍"," 黎杉珊"," 陆杜鹃"," 漆天乐"," 申光辉"," 张志清"],"authors":"黄翠萍, 黎杉珊, 陆杜鹃, 漆天乐, 申光辉, 张志清","authorsCn":"黄翠萍, 黎杉珊, 陆杜鹃, 漆天乐, 申光辉, 张志清","authorsEn":"Cuiping Huang, Shanshan Li, Dujuan Lu, Tianle Qi, Guanghui Shen, Zhiqing Zhang","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"黄翠萍, 黎杉珊, 陆杜鹃, 漆天乐, 申光辉, 张志清. 用于抗生素检测的纳米材料基电化学传感器研究进展. 化学通报, 2021, 84(2): 139-148.","citationCn":"黄翠萍, 黎杉珊, 陆杜鹃, 漆天乐, 申光辉, 张志清. 用于抗生素检测的纳米材料基电化学传感器研究进展. 化学通报, 2021, 84(2): 139-148.","citationEn":"黄翠萍, 黎杉珊, 陆杜鹃, 漆天乐, 申光辉, 张志清. Progress in Nanomaterial-Based Electrochemical Sensors for Antibiotic Detection. Chemistry, 2021, 84(2): 139-148.","doi":"","figContent":"hxtb-84-2-139-1.jpg$$hxtb-84-2-139-2.jpg$$hxtb-84-2-139-3.jpg","figList":["hxtb-84-2-139-1.jpg","hxtb-84-2-139-2.jpg","hxtb-84-2-139-3.jpg"],"firstFig":"hxtb-84-2-139-1.jpg","fpage":"139","highCitedState":"","htmlCount":137,"htmlFile":"","id":"03001914-3850-4331-b1e2-99b9dc775b5d","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"抗生素, 纳米材料, 纳米结构, 电化学传感器","keywordCn":"抗生素, 纳米材料, 纳米结构, 电化学传感器","keywordCnList":["抗生素"," 纳米材料"," 纳米结构"," 电化学传感器"],"keywordEn":"Antibiotics, Nanomaterials, Nanostructures, Electrochemical sensor","keywordEnList":["Antibiotics"," Nanomaterials"," Nanostructures"," Electrochemical sensor"],"keywordList":["抗生素"," 纳米材料"," 纳米结构"," 电化学传感器"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"148","oldUrl":"","pdfDownCount":5,"pdfSize":6055.35,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"用于抗生素检测的纳米材料基电化学传感器研究进展","titleCn":"用于抗生素检测的纳米材料基电化学传感器研究进展","titleEn":"Progress in Nanomaterial-Based Electrochemical Sensors for Antibiotic Detection","viewCount":674,"volume":"84","year":2021},{"abstractInfo":"共价有机骨架（COFs）是一种新型的纳米结构材料，由于其独特的性质而受到人们的广泛关注。COFs的结晶度高，孔径可调，比表面积大，具有良好的抗氧化性能和独特的分子结构，在能源、环境等方面得到了广泛的应用。COFs材料有较高的应用价值，促使人们不断努力研究其基本性质，并调控其结构和功能来提高性能。通过COFs的可设计性，按需合成结构-性能相关的材料，是解决可持续能源、环境（如气体储存、气体分离、催化、环境修复和化学传感等方面）等持久挑战的理想候选材料。","abstractInfoCn":"共价有机骨架（COFs）是一种新型的纳米结构材料，由于其独特的性质而受到人们的广泛关注。COFs的结晶度高，孔径可调，比表面积大，具有良好的抗氧化性能和独特的分子结构，在能源、环境等方面得到了广泛的应用。COFs材料有较高的应用价值，促使人们不断努力研究其基本性质，并调控其结构和功能来提高性能。通过COFs的可设计性，按需合成结构-性能相关的材料，是解决可持续能源、环境（如气体储存、气体分离、催化、环境修复和化学传感等方面）等持久挑战的理想候选材料。","abstractInfoEn":"Covalent organic frameworks (COFs) are a new type of nanostructure materials, which have attracted much attention due to their unique properties. COFs with high crystallinity, adjustable pore size, large specific surface area, good oxidation resistance and unique molecular structure, have been widely used in energy and environment aspects. COFs materials have high economic benefits, which urge people to study their basic properties and regulate their structure and function to improve their performance. Through the designability of COFs, on-demand synthesized structure-performance related materials are ideal candidate materials to solve the persistent challenges of sustainable energy and environment (such as gas storage, gas separation, catalysis, environmental remediation and chemical sensing).","articleNo":"hxtb-84-2-149","authorCnList":["徐世娴"," 万伊娜"],"authorEnList":["Shixian Xu"," Yina Wan"],"authorList":["徐世娴"," 万伊娜"],"authors":"徐世娴, 万伊娜","authorsCn":"徐世娴, 万伊娜","authorsEn":"Shixian Xu, Yina Wan","categoryName":"进展评述","categoryNameCn":"进展评述","categoryNameEn":"","citation":"徐世娴, 万伊娜. 共价有机骨架的合成及其在气体吸附存储方面的应用. 化学通报, 2021, 84(2): 149-153, 166.","citationCn":"徐世娴, 万伊娜. 共价有机骨架的合成及其在气体吸附存储方面的应用. 化学通报, 2021, 84(2): 149-153, 166.","citationEn":"徐世娴, 万伊娜. Synthesis of Covalent Organic Frameworks and Their Applications in Gas Adsorption Storage. Chemistry, 2021, 84(2): 149-153, 166.","doi":"","figContent":"hxtb-84-2-149-1.jpg$$hxtb-84-2-149-2.jpg","figList":["hxtb-84-2-149-1.jpg","hxtb-84-2-149-2.jpg"],"firstFig":"hxtb-84-2-149-1.jpg","fpage":"149","highCitedState":"","htmlCount":330,"htmlFile":"","id":"21213da5-4117-4a56-b110-04d1e95fea4b","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"多孔材料, 共价有机骨架, 吸附存储","keywordCn":"多孔材料, 共价有机骨架, 吸附存储","keywordCnList":["多孔材料"," 共价有机骨架"," 吸附存储"],"keywordEn":"Porous materials, Covalent organic framework, Adsorption storage","keywordEnList":["Porous materials"," Covalent organic framework"," Adsorption storage"],"keywordList":["多孔材料"," 共价有机骨架"," 吸附存储"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"153, 166","oldUrl":"","pdfDownCount":9,"pdfSize":4757.69,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"共价有机骨架的合成及其在气体吸附存储方面的应用","titleCn":"共价有机骨架的合成及其在气体吸附存储方面的应用","titleEn":"Synthesis of Covalent Organic Frameworks and Their Applications in Gas Adsorption Storage","viewCount":1083,"volume":"84","year":2021}],"其他":[{"abstractInfo":"Inthepresentinvestigation,asimpleandfacilesynthesisofaseriesofstructurallynovelandintriguingquinoxaline-basedisoindolin-1-onesthroughtheone-stepreactionofethyl3-bromomethylquinoxaline-2-carboxylatewithwitharylaminesoraliphaticaminesinrefluxingethanolmediumhasbeendescribed.Thepreliminaryscreeningfortheir<i>invitro<\/i>anti-tumoractivityagainstA549andHT29usingtheMTTassayrevealedthathalo-substituted(F,Cl,Br,I)compounds<b>7h~7k<\/b>showedpromisinginhibitoryactivity,amongwhichfluro-substituted<b>7h<\/b>possessedthebestactivityagainstthetwocelllineswiththeIC<sub>50<\/sub>valuesof1.50and3.77μg/mL,respectively,whichwerehigherthanthatofthereferencedrugcisplatin.","abstractInfoCn":"本文通过3-溴甲基喹喔啉-2-羧酸乙酯与芳胺或脂肪胺在回流的乙醇中经一步反应简便而有效合成了一系列结构新颖的基于喹喔啉结构的异吲哚啉酮类化合物。采用MTT法初步评价了目标化合物对肺癌细胞株A549和直肠癌细胞株HT29的体外增殖抑制活性。结果表明，含有卤素（F，Cl，Br，I）取代的化合物<b>7h~7k<\/b>对这两个细胞株表现出良好的抑制活性，其中氟取代的化合物<b>7h<\/b>的活性最高，其IC<sub>50<\/sub>值分别为1.50和3.77 μg/mL，活性高于参考药物顺铂。","abstractInfoEn":"In the present investigation, a simple and facile synthesis of a series of structurally novel and intriguing quinoxaline-based isoindolin-1-ones through the one-step reaction of ethyl 3-bromomethylquinoxaline-2-carboxylatewith with arylamines or aliphatic amines in refluxing ethanol medium has been described. The preliminary screening for their <i>in vitro<\/i> anti-tumor activity against A549 and HT29 using the MTT assay revealed that halo-substituted (F, Cl, Br, I) compounds <b>7h~7k<\/b> showed promising inhibitory activity, among which fluro-substituted <b>7h<\/b> possessed the best activity against the two cell lines with the IC<sub>50<\/sub> values of 1.50 and 3.77 μg/mL, respectively, which were higher than that of the reference drug cisplatin.","articleNo":"hxtb-84-2-154","authorCnList":["常明琴"," 奚倩"," 纪铭"," 黄文远"," 高婷妤"," 李阳"],"authorEnList":["Mingqin Chang"," Qian Xi"," Ming Ji"," Wenyuan Huang"," Tingyu Gao"," Yang Li"],"authorList":["Mingqin Chang"," Qian Xi"," Ming Ji"," Wenyuan Huang"," Tingyu Gao"," Yang Li"],"authors":"Mingqin Chang, Qian Xi, Ming Ji, Wenyuan Huang, Tingyu Gao, Yang Li","authorsCn":"常明琴, 奚倩, 纪铭, 黄文远, 高婷妤, 李阳","authorsEn":"Mingqin Chang, Qian Xi, Ming Ji, Wenyuan Huang, Tingyu Gao, Yang Li","categoryName":" ","categoryNameCn":"研究论文","categoryNameEn":" ","citation":"Mingqin Chang, Qian Xi, Ming Ji, Wenyuan Huang, Tingyu Gao, Yang Li. Synthesis and In Vitro Antitumor Activity of Novel Quinoxaline-Based Isoindolin-1-Ones. Chemistry, 2021, 84(2): 154-161, 171.","citationCn":"Mingqin Chang, Qian Xi, Ming Ji, Wenyuan Huang, Tingyu Gao, Yang Li. 基于喹喔啉结构的异吲哚啉-1-酮类化合物合成及抗肿瘤活性. 化学通报, 2021, 84(2): 154-161, 171.","citationEn":"Mingqin Chang, Qian Xi, Ming Ji, Wenyuan Huang, Tingyu Gao, Yang Li. Synthesis and In Vitro Antitumor Activity of Novel Quinoxaline-Based Isoindolin-1-Ones. Chemistry, 2021, 84(2): 154-161, 171.","doi":"","figContent":"hxtb-84-2-154-S1.jpg$$hxtb-84-2-154-S2.jpg$$hxtb-84-2-154-S3.jpg","figList":["hxtb-84-2-154-S1.jpg","hxtb-84-2-154-S2.jpg","hxtb-84-2-154-S3.jpg"],"firstFig":"hxtb-84-2-154-S1.jpg","fpage":"154","highCitedState":"","htmlCount":67,"htmlFile":"","id":"d310e4fb-f036-40bd-92e0-c8d12ec9a21b","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"Quinoxaline, Isoindolin-1-one, One-step reaction, Anti-tumor activity","keywordCn":"喹喔啉, 异吲哚啉-1-酮, 一步反应, 抗肿瘤活性","keywordCnList":["喹喔啉"," 异吲哚啉-1-酮"," 一步反应"," 抗肿瘤活性"],"keywordEn":"Quinoxaline, Isoindolin-1-one, One-step reaction, Anti-tumor activity","keywordEnList":["Quinoxaline"," Isoindolin-1-one"," One-step reaction"," Anti-tumor activity"],"keywordList":["Quinoxaline"," Isoindolin-1-one"," One-step reaction"," Anti-tumor activity"],"language":"en","latestInfo":"","latestState":"","latestStateEn":"","lpage":"161, 171","oldUrl":"","pdfDownCount":5,"pdfSize":2952.38,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"Synthesis and In Vitro Antitumor Activity of Novel Quinoxaline-Based Isoindolin-1-Ones","titleCn":"基于喹喔啉结构的异吲哚啉-1-酮类化合物合成及抗肿瘤活性","titleEn":"Synthesis and In Vitro Antitumor Activity of Novel Quinoxaline-Based Isoindolin-1-Ones","viewCount":626,"volume":"84","year":2021}],"研究论文":[{"abstractInfo":"以2，3-二氨基吡啶和2，3-丁二酮为起始原料，经环化、催化氢化和亲核取代反应合成了10个新型哌啶并[2，3-<i>b<\/i>]哌嗪类衍生物（<b>3a~3j<\/b>），其结构经<sup>1<\/sup>HNMR、<sup>13<\/sup>CNMR和HR-MS确证。体外抗血小板聚集活性研究表明，化合物<b>3d、3e、3g、3h<\/b>和<b>3j<\/b>具有一定的抗血小板聚集作用，其中化合物<b>3h<\/b>（IC<sub>50<\/sub>=1.24mmol/L）的活性显著优于母体化合物川芎嗪（IC<sub>50<\/sub>=3.96mmol/L）和阳性药物阿司匹林（IC<sub>50<\/sub>=2.41mmol/L）。","abstractInfoCn":"以2，3-二氨基吡啶和2，3-丁二酮为起始原料，经环化、催化氢化和亲核取代反应合成了10个新型哌啶并[2，3-<i>b<\/i>]哌嗪类衍生物（<b>3a~3j<\/b>），其结构经<sup>1<\/sup>H NMR、<sup>13<\/sup>C NMR和HR-MS确证。体外抗血小板聚集活性研究表明，化合物<b>3d、3e、3g、3h<\/b>和<b>3j<\/b>具有一定的抗血小板聚集作用，其中化合物<b>3h<\/b>（IC<sub>50<\/sub>=1.24mmol/L）的活性显著优于母体化合物川芎嗪（IC<sub>50<\/sub>=3.96mmol/L）和阳性药物阿司匹林（IC<sub>50<\/sub>=2.41mmol/L）。","abstractInfoEn":"Using 2, 3-diaminopyridine and 2, 3-butanedione as the starting material, ten new piperido [2, 3-<i>b<\/i>]piperazine derivatives (<b>3a~3j<\/b>) were synthesized by cyclization, catalytic hydrogenation and nucleophilic substitution reaction. Their structures were confirmed by <sup>1<\/sup>H NMR, <sup>13<\/sup>C NMR and HRMS. The <i>in vitro<\/i> antiplatelet aggregation activity study showed that compounds <b>3d, 3e, 3g, 3h<\/b> and <b>3j<\/b> had a certain antiplatelet aggregation effect, and the activity of compound <b>3h<\/b> (IC<sub>50<\/sub>=1.24 mmol/L) was significantly better than that of the lead compound ligustrazine (IC<sub>50<\/sub>=3.96 mmol/L) and the positive drug aspirin (IC<sub>50<\/sub>=2.41 mmol/L).","articleNo":"hxtb-84-2-162","authorCnList":["李毅"," 罗碧兰"," 赵菊琴"," 李永"," 张毅"," 汤磊"," 樊玲玲"],"authorEnList":["Yi Li"," Bilan Luo"," Juqin Zhao"," Yong Li"," Yi Zhang"," Lei Tang"," Lingling Fan"],"authorList":["李毅"," 罗碧兰"," 赵菊琴"," 李永"," 张毅"," 汤磊"," 樊玲玲"],"authors":"李毅, 罗碧兰, 赵菊琴, 李永, 张毅, 汤磊, 樊玲玲","authorsCn":"李毅, 罗碧兰, 赵菊琴, 李永, 张毅, 汤磊, 樊玲玲","authorsEn":"Yi Li, Bilan Luo, Juqin Zhao, Yong Li, Yi Zhang, Lei Tang, Lingling Fan","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"李毅, 罗碧兰, 赵菊琴, 李永, 张毅, 汤磊, 樊玲玲. 哌啶并[2, 3-<i>b<\/i>]哌嗪类衍生物的设计、合成及其抗血小板聚集活性研究. 化学通报, 2021, 84(2): 162-166.","citationCn":"李毅, 罗碧兰, 赵菊琴, 李永, 张毅, 汤磊, 樊玲玲. 哌啶并[2, 3-<i>b<\/i>]哌嗪类衍生物的设计、合成及其抗血小板聚集活性研究. 化学通报, 2021, 84(2): 162-166.","citationEn":"李毅, 罗碧兰, 赵菊琴, 李永, 张毅, 汤磊, 樊玲玲. Design, Synthesis and Anti-Platelet Aggregation Activity of Piperido[2, 3-<i>b<\/i>]piperazine Derivatives. Chemistry, 2021, 84(2): 162-166.","doi":"","figContent":"hxtb-84-2-162-S1.jpg$$hxtb-84-2-162-S2.jpg","figList":["hxtb-84-2-162-S1.jpg","hxtb-84-2-162-S2.jpg"],"firstFig":"hxtb-84-2-162-S1.jpg","fpage":"162","highCitedState":"","htmlCount":104,"htmlFile":"","id":"a2904176-cf9a-495c-8c9f-abecffbd1a16","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"哌啶并[2, 3-<i>b<\/i>]哌嗪, 合成, 抗血小板聚集活性","keywordCn":"哌啶并[2, 3-<i>b<\/i>]哌嗪, 合成, 抗血小板聚集活性","keywordCnList":["哌啶并[2"," 3-<i>b<\/i>]哌嗪"," 合成"," 抗血小板聚集活性"],"keywordEn":"Piperido[2, 3-<i>b<\/i>]piperazine, Synthesis, Anti-platelet aggregation activity","keywordEnList":["Piperido[2"," 3-<i>b<\/i>]piperazine"," Synthesis"," Anti-platelet aggregation activity"],"keywordList":["哌啶并[2"," 3-<i>b<\/i>]哌嗪"," 合成"," 抗血小板聚集活性"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"166","oldUrl":"","pdfDownCount":6,"pdfSize":1877.77,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"哌啶并[2, 3-<i>b<\/i>]哌嗪类衍生物的设计、合成及其抗血小板聚集活性研究","titleCn":"哌啶并[2, 3-<i>b<\/i>]哌嗪类衍生物的设计、合成及其抗血小板聚集活性研究","titleEn":"Design, Synthesis and Anti-Platelet Aggregation Activity of Piperido[2, 3-<i>b<\/i>]piperazine Derivatives","viewCount":833,"volume":"84","year":2021},{"abstractInfo":"本文通过水热合成法合成了钴-对苯二甲酸金属有机骨架材料Co（BDC），并将其与聚丙烯酸钠（PAAS）混合后修饰到玻碳电极（GCE）表面，制得电化学传感器Co（BDC）-PAAS/GCE，通过循环伏安法和差分脉冲法研究了传感器的响应性能，并用于水产品中环丙沙星（CIP）检测。结果表明，在碱性条件下，Co（BDC）-PAAS/GCE对CIP具有较好的电催化作用。差分脉冲峰电流与CIP浓度在3.0×10<sup>-9<\/sup>~1.5×10<sup>-8<\/sup>mol/L范围内呈线性关系，线性方程为<i>I<\/i>（μA）=99.8<i>C<\/i><sub>CIP<\/sub>+5.74（<i>R<\/i><sup>2<\/sup>=0.989）；在1.5×10<sup>-8<\/sup>~1.5×10<sup>-7<\/sup>mol/L范围内呈线性关系，线性方程<i>I<\/i>（μA）=11.09<i>C<\/i><sub>CIP<\/sub>+7.09（<i>R<\/i><sup>2<\/sup>=0.992），检出限为1.0×10<sup>-9<\/sup>mol/L。使用该传感器检测实际样品草鱼肉中CIP的加标回收率在95.0%~101.9%之间。该传感器制作简单，稳定性、选择性和重复性好，可满足水产品中CIP的快速检测需要。","abstractInfoCn":"本文通过水热合成法合成了钴-对苯二甲酸金属有机骨架材料Co（BDC），并将其与聚丙烯酸钠（PAAS）混合后修饰到玻碳电极（GCE）表面，制得电化学传感器Co（BDC）-PAAS/GCE，通过循环伏安法和差分脉冲法研究了传感器的响应性能，并用于水产品中环丙沙星（CIP）检测。结果表明，在碱性条件下，Co（BDC）-PAAS/GCE对CIP具有较好的电催化作用。差分脉冲峰电流与CIP浓度在3.0×10<sup>-9<\/sup>~1.5×10<sup>-8<\/sup> mol/L范围内呈线性关系，线性方程为<i>I<\/i>（μA）=99.8 <i>C<\/i><sub>CIP<\/sub>+5.74（<i>R<\/i><sup>2<\/sup>=0.989）；在1.5×10<sup>-8<\/sup>~1.5×10<sup>-7<\/sup> mol/L范围内呈线性关系，线性方程<i>I<\/i>（μA）=11.09 <i>C<\/i><sub>CIP<\/sub>+7.09（<i>R<\/i><sup>2<\/sup>=0.992），检出限为1.0×10<sup>-9<\/sup>mol/L。使用该传感器检测实际样品草鱼肉中CIP的加标回收率在95.0%~101.9%之间。该传感器制作简单，稳定性、选择性和重复性好，可满足水产品中CIP的快速检测需要。","abstractInfoEn":"Cobalt-terephthalic acid metal organic framework material (Co(BDC)) was synthesized through a hydrothermal method and characterized by scanning electron microscope and infrared spectrum. The hybrid material of Co(BDC) and sodium polyacrylate (PAAS) was cast on a glassy carbon electrode (GCE) to get a modified electrode Co(BDC)-PAAS/GCE for the electrochemical detection of CIP. The electrochemical study showed that Co(BDC) exhibited high catalytic effect on the reduction of CIP. The results showed that the peak current increased with the CIP concentration in the range of 3.0×10<sup>-9<\/sup>~1.5×10<sup>-8<\/sup> mol/L with a calibration equation of <i>I<\/i> (μA)=99.8<i>C<\/i><sub>CIP<\/sub>+5.74(<i>R<\/i><sup>2<\/sup>=0.989), and in the range of 1.5×10<sup>-8<\/sup>~1.5×10<sup>-7<\/sup> mol/L with a calibration equation of <i>I<\/i> (μA)=11.09<i>C<\/i><sub>CIP<\/sub>+7.09 (<i>R<\/i><sup>2<\/sup>=0.992). The detection limit is 1.0×10<sup>-9<\/sup> mol/L (S/N=3). The Co(BDC)-PAAS/GCE exhibited excellent reproducibility, good stability and good selectivity and was successfully applied to the determination of CIP in aquatic samples. Recoveries obtained for the determination of CIP in spiked samples were between 95.0% and 101.9%.","articleNo":"hxtb-84-2-167","authorCnList":["陈宏"," 王悦"," 张文婷"," 朱玉"," 励建荣"],"authorEnList":["Hong Chen"," Yue Wang"," Wenting Zhang"," Yu Zhu"," Jianrong Li"],"authorList":["陈宏"," 王悦"," 张文婷"," 朱玉"," 励建荣"],"authors":"陈宏, 王悦, 张文婷, 朱玉, 励建荣","authorsCn":"陈宏, 王悦, 张文婷, 朱玉, 励建荣","authorsEn":"Hong Chen, Yue Wang, Wenting Zhang, Yu Zhu, Jianrong Li","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"陈宏, 王悦, 张文婷, 朱玉, 励建荣. 金属有机骨架材料构建环丙沙星电化学传感器的研究. 化学通报, 2021, 84(2): 167-171.","citationCn":"陈宏, 王悦, 张文婷, 朱玉, 励建荣. 金属有机骨架材料构建环丙沙星电化学传感器的研究. 化学通报, 2021, 84(2): 167-171.","citationEn":"陈宏, 王悦, 张文婷, 朱玉, 励建荣. Determination of Ciprofloxacin by Electrochemical Sensor Based on Metal Organic Framework Material. Chemistry, 2021, 84(2): 167-171.","doi":"","figContent":"hxtb-84-2-167-1.jpg$$hxtb-84-2-167-2.jpg$$hxtb-84-2-167-3.jpg$$hxtb-84-2-167-4.jpg$$hxtb-84-2-167-5.jpg$$hxtb-84-2-167-6.jpg$$hxtb-84-2-167-7.jpg","figList":["hxtb-84-2-167-1.jpg","hxtb-84-2-167-2.jpg","hxtb-84-2-167-3.jpg","hxtb-84-2-167-4.jpg","hxtb-84-2-167-5.jpg","hxtb-84-2-167-6.jpg","hxtb-84-2-167-7.jpg"],"firstFig":"hxtb-84-2-167-1.jpg","fpage":"167","highCitedState":"","htmlCount":221,"htmlFile":"","id":"319b3473-e09e-443b-92cc-72a75243443c","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"电化学传感器, 金属有机骨架材料, 环丙沙星, 水产品","keywordCn":"电化学传感器, 金属有机骨架材料, 环丙沙星, 水产品","keywordCnList":["电化学传感器"," 金属有机骨架材料"," 环丙沙星"," 水产品"],"keywordEn":"Electrochemical sensor, Metal organic framework material, Ciprofloxacin, Aquatic product","keywordEnList":["Electrochemical sensor"," Metal organic framework material"," Ciprofloxacin"," Aquatic product"],"keywordList":["电化学传感器"," 金属有机骨架材料"," 环丙沙星"," 水产品"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"171","oldUrl":"","pdfDownCount":11,"pdfSize":1607.87,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"金属有机骨架材料构建环丙沙星电化学传感器的研究","titleCn":"金属有机骨架材料构建环丙沙星电化学传感器的研究","titleEn":"Determination of Ciprofloxacin by Electrochemical Sensor Based on Metal Organic Framework Material","viewCount":1020,"volume":"84","year":2021},{"abstractInfo":"本文采用火焰刻蚀和玻璃毛细管封装法制备微纳碳电极。通过调控电解液浓度、沉积策略和时间等参数，利用电化学沉积法在微纳碳电极上得到单原子、3原子、5原子等不同尺寸的Pt原子团簇。在酸性溶液条件下，利用Pt原子团簇在微纳电极上产生的催化氢还原极限电流对Pt原子团簇的大小进行了推算；同时，利用线性扫描伏安法比较了Pt原子团簇的析氢特性，利用循环伏安法测试了Pt单原子的稳定性。本研究可为单原子及少量原子金属团簇的电沉积及其性能研究提供重要参考。","abstractInfoCn":"本文采用火焰刻蚀和玻璃毛细管封装法制备微纳碳电极。通过调控电解液浓度、沉积策略和时间等参数，利用电化学沉积法在微纳碳电极上得到单原子、3原子、5原子等不同尺寸的Pt原子团簇。在酸性溶液条件下，利用Pt原子团簇在微纳电极上产生的催化氢还原极限电流对Pt原子团簇的大小进行了推算；同时，利用线性扫描伏安法比较了Pt原子团簇的析氢特性，利用循环伏安法测试了Pt单原子的稳定性。本研究可为单原子及少量原子金属团簇的电沉积及其性能研究提供重要参考。","abstractInfoEn":"In this work, micro-nano-scale carbon electrodes were successfully prepared by flame etching and glass capillary tubes encapsulation. Pt clusters of different sizes, such as single atom, 3 atoms, 5 atoms, were obtained on as-prepared carbon electrodes by electrochemical deposition through regulating the parameters, such as electrolyte concentration, deposition strategy and deposition time. The size of Pt clusters was calculated using limiting current of the catalytic hydrogen reduction on as-prepared electrodes in an acidic solution. Meanwhile, the hydrogen evolution characteristics of Pt clusters were compared using linear scanning voltammetry, and the stability of Pt single atom was evaluated by consulting cyclic voltammetry. This study can provide an important reference for the study of the electrodeposition and properties of single-atom and few-atom metal clusters.","articleNo":"hxtb-84-2-172","authorCnList":["杨慧权"," 杨帆"," 尉明洋"," 刘立春"," 张立秋"],"authorEnList":["Huiquan Yang"," Fan Yang"," Mingyang Wei"," Lichun Liu"," Liqiu Zhang"],"authorList":["杨慧权"," 杨帆"," 尉明洋"," 刘立春"," 张立秋"],"authors":"杨慧权, 杨帆, 尉明洋, 刘立春, 张立秋","authorsCn":"杨慧权, 杨帆, 尉明洋, 刘立春, 张立秋","authorsEn":"Huiquan Yang, Fan Yang, Mingyang Wei, Lichun Liu, Liqiu Zhang","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"杨慧权, 杨帆, 尉明洋, 刘立春, 张立秋. Pt原子团簇在微纳碳电极上的电沉积研究. 化学通报, 2021, 84(2): 172-177.","citationCn":"杨慧权, 杨帆, 尉明洋, 刘立春, 张立秋. Pt原子团簇在微纳碳电极上的电沉积研究. 化学通报, 2021, 84(2): 172-177.","citationEn":"杨慧权, 杨帆, 尉明洋, 刘立春, 张立秋. Atomic Platinum Cluster Electrodeposition on Micro-Nano-Scale Carbon Electrode. Chemistry, 2021, 84(2): 172-177.","doi":"","figContent":"hxtb-84-2-172-1.jpg$$hxtb-84-2-172-2.jpg$$hxtb-84-2-172-3.jpg$$hxtb-84-2-172-4.jpg","figList":["hxtb-84-2-172-1.jpg","hxtb-84-2-172-2.jpg","hxtb-84-2-172-3.jpg","hxtb-84-2-172-4.jpg"],"firstFig":"hxtb-84-2-172-1.jpg","fpage":"172","highCitedState":"","htmlCount":727,"htmlFile":"","id":"8bd2e5f5-8664-4856-ad2c-a20284d8a979","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"碳电极, 催化剂, 单原子, 铂, 电沉积","keywordCn":"碳电极, 催化剂, 单原子, 铂, 电沉积","keywordCnList":["碳电极"," 催化剂"," 单原子"," 铂"," 电沉积"],"keywordEn":"Carbon electrode, Catalyst, Single atom, Pt, Electrochemical deposition","keywordEnList":["Carbon electrode"," Catalyst"," Single atom"," Pt"," Electrochemical deposition"],"keywordList":["碳电极"," 催化剂"," 单原子"," 铂"," 电沉积"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"177","oldUrl":"","pdfDownCount":16,"pdfSize":3028.16,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"Pt原子团簇在微纳碳电极上的电沉积研究","titleCn":"Pt原子团簇在微纳碳电极上的电沉积研究","titleEn":"Atomic Platinum Cluster Electrodeposition on Micro-Nano-Scale Carbon Electrode","viewCount":2339,"volume":"84","year":2021}],"研究简报":[{"abstractInfo":"在酸催化作用下，成功实现了3-氨基-2-环丁烯酮开环重排一步合成喹啉类化合物，对反应溶剂、催化剂、温度、投料比等影响因素进行了考察，在优化反应条件下催化合成了一系列喹啉类化合物，获得了较好的产率。该合成方法具有反应温度低、产率高以及反应迅速等优点，为喹啉类衍生物的合成建立了一种简单有效的新方法。","abstractInfoCn":"在酸催化作用下，成功实现了3-氨基-2-环丁烯酮开环重排一步合成喹啉类化合物，对反应溶剂、催化剂、温度、投料比等影响因素进行了考察，在优化反应条件下催化合成了一系列喹啉类化合物，获得了较好的产率。该合成方法具有反应温度低、产率高以及反应迅速等优点，为喹啉类衍生物的合成建立了一种简单有效的新方法。","abstractInfoEn":"A series of quinoline derivatives were successfully obtained through opening-cyclization reaction of 3-amino-2-cyclobutanones in the presence of acid. By screening the reaction solvent, catalyst, temperature, feed ratio and other factors, the optimal reaction conditions were obtained. The method exhibits many advantages such as low temperature, high yield, rapid response and so on, and it establishes a simple and effective new method for the synthesis of quinoline derivatives.","articleNo":"hxtb-84-2-178","authorCnList":["付建平"," 熊伟"," 胡居吾"," 韩晓丹"],"authorEnList":["Jianping Fu"," Wei Xiong"," Juwu Hu"," Xiaodan Han"],"authorList":["付建平"," 熊伟"," 胡居吾"," 韩晓丹"],"authors":"付建平, 熊伟, 胡居吾, 韩晓丹","authorsCn":"付建平, 熊伟, 胡居吾, 韩晓丹","authorsEn":"Jianping Fu, Wei Xiong, Juwu Hu, Xiaodan Han","categoryName":"研究简报","categoryNameCn":"研究简报","categoryNameEn":"","citation":"付建平, 熊伟, 胡居吾, 韩晓丹. 环丁烯酮化合物高效合成喹啉衍生物的应用研究. 化学通报, 2021, 84(2): 178-181.","citationCn":"付建平, 熊伟, 胡居吾, 韩晓丹. 环丁烯酮化合物高效合成喹啉衍生物的应用研究. 化学通报, 2021, 84(2): 178-181.","citationEn":"付建平, 熊伟, 胡居吾, 韩晓丹. Study on the Efficient Synthesis of Quinoline Derivatives from Cyclobutenones. Chemistry, 2021, 84(2): 178-181.","doi":"","figContent":"hxtb-84-2-178-S1.jpg$$hxtb-84-2-178-S2.jpg$$hxtb-84-2-178-S3.jpg","figList":["hxtb-84-2-178-S1.jpg","hxtb-84-2-178-S2.jpg","hxtb-84-2-178-S3.jpg"],"firstFig":"hxtb-84-2-178-S1.jpg","fpage":"178","highCitedState":"","htmlCount":182,"htmlFile":"","id":"3b755563-a155-48d3-903e-9b57f994c2f3","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"环丁烯酮, 开环反应, 喹啉","keywordCn":"环丁烯酮, 开环反应, 喹啉","keywordCnList":["环丁烯酮"," 开环反应"," 喹啉"],"keywordEn":"Cyclobutanones, Ring opening reaction, Quinoline","keywordEnList":["Cyclobutanones"," Ring opening reaction"," Quinoline"],"keywordList":["环丁烯酮"," 开环反应"," 喹啉"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"181","oldUrl":"","pdfDownCount":14,"pdfSize":715.05,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"环丁烯酮化合物高效合成喹啉衍生物的应用研究","titleCn":"环丁烯酮化合物高效合成喹啉衍生物的应用研究","titleEn":"Study on the Efficient Synthesis of Quinoline Derivatives from Cyclobutenones","viewCount":884,"volume":"84","year":2021}],"化学教学":[{"abstractInfo":"本文指出了滴定计算中等物质的量规则的缺陷，并提出了等物质的量定律，将这个反映化学反应客观规律的定律定义为：在氧化还原反应体系中氧化剂与还原剂得与失电子的物质的量相等；在酸碱反应体系中酸与碱得与失质子的物质的量相等；在沉淀反应中阳离子与阴离子所具有电荷的物质的量相等；在络合滴定中金属离子与氨羧络合剂的物质的量相等。等物质的量定律可用下式表达：<inline-formula><tex-mathid=\"M1\">\\begin{document}$\\sum\\limits_{i=1}^{i=k}{\\Deltan\\left({\\frac{1}{{{z_{Ai}}}}}\\right)}{A_i}=\\sum\\limits_{i=1}^{i=p}{\\Deltan\\left({\\frac{1}{{{z_{Bi}}}}}\\right)}{B_i}$\\end{document}<\/tex-math><\/inline-formula>。这个定律及其表达式能使复杂的滴定分析计算简单化、规范化。","abstractInfoCn":"本文指出了滴定计算中等物质的量规则的缺陷，并提出了等物质的量定律，将这个反映化学反应客观规律的定律定义为：在氧化还原反应体系中氧化剂与还原剂得与失电子的物质的量相等；在酸碱反应体系中酸与碱得与失质子的物质的量相等；在沉淀反应中阳离子与阴离子所具有电荷的物质的量相等；在络合滴定中金属离子与氨羧络合剂的物质的量相等。等物质的量定律可用下式表达：<inline-formula><tex-math id=\"M1\">\\begin{document}$ \\sum\\limits_{i = 1}^{i = k} {\\Delta n\\left( {\\frac{1}{{{z_{Ai}}}}} \\right)} {A_i} = \\sum\\limits_{i = 1}^{i = p} {\\Delta n\\left( {\\frac{1}{{{z_{Bi}}}}} \\right)} {B_i}$\\end{document}<\/tex-math><\/inline-formula>。这个定律及其表达式能使复杂的滴定分析计算简单化、规范化。","abstractInfoEn":"The paper presents a strict definition for the law of equal amount of substance in titration: the amount of substance of electron lost is equal to the amount of substance of electron got in oxide-reduction titration; the amount of substance of proton lost equals the amount of substance of proton got in neutralization titration; the amount of substance of negative charge equals the amount of substance of positive charge in precipitation titration; the amount of substance of metal ions is equal to the amount of substance of complexone in complexometry. The law can be expressed by follow formula, <inline-formula><tex-math id=\"M2\">\\begin{document}$ \\sum\\limits_{i = 1}^{i = k} {\\Delta n\\left( {\\frac{1}{{{z_{Ai}}}}} \\right)} {A_i} = \\sum\\limits_{i = 1}^{i = p} {\\Delta n\\left( {\\frac{1}{{{z_{Bi}}}}} \\right)} {B_i}$\\end{document}<\/tex-math><\/inline-formula>. The definition and formula can simplify and standardize complex titration calculations.","articleNo":"hxtb-84-2-182","authorCnList":["赵梦月"," 赵建宏"],"authorEnList":["Mengyue Zhao"," Jianhong Zhao"],"authorList":["赵梦月"," 赵建宏"],"authors":"赵梦月, 赵建宏","authorsCn":"赵梦月, 赵建宏","authorsEn":"Mengyue Zhao, Jianhong Zhao","categoryName":"化学教学","categoryNameCn":"化学教学","categoryNameEn":"","citation":"赵梦月, 赵建宏. 等物质的量定律及其应用. 化学通报, 2021, 84(2): 182-184.","citationCn":"赵梦月, 赵建宏. 等物质的量定律及其应用. 化学通报, 2021, 84(2): 182-184.","citationEn":"赵梦月, 赵建宏. Law of Equal Amount of Substance and Its Application. Chemistry, 2021, 84(2): 182-184.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"182","highCitedState":"","htmlCount":639,"htmlFile":"","id":"812ea372-7e4c-40fa-b99a-4ff91bcb4831","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"物质的量, 基本单元, 等物质的量定律","keywordCn":"物质的量, 基本单元, 等物质的量定律","keywordCnList":["物质的量"," 基本单元"," 等物质的量定律"],"keywordEn":"Amount of substance, Elementary entity, Law of equal amount of substance","keywordEnList":["Amount of substance"," Elementary entity"," Law of equal amount of substance"],"keywordList":["物质的量"," 基本单元"," 等物质的量定律"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"184","oldUrl":"","pdfDownCount":16,"pdfSize":689.92,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"等物质的量定律及其应用","titleCn":"等物质的量定律及其应用","titleEn":"Law of Equal Amount of Substance and Its Application","viewCount":2239,"volume":"84","year":2021}],"化学史":[{"abstractInfo":"1914年，美国物理学家布里奇曼无意间制得了黑磷并证明了这是磷的一种新的相变体，但在很长的一段时间内并没有引起人们的关注。20世纪中期以后，黑磷的制备方法得到了一定程度的发展。至2014年，研究者成功制备了二维黑磷场效应晶体管，随后人们发现黑磷在储能设备、光电子器件、光催化、生物传感等方面都有巨大的应用潜力。随着黑磷制备方法的发展和人们对黑磷认识的深入，黑磷的应用也会有更广阔的前景。","abstractInfoCn":"1914年，美国物理学家布里奇曼无意间制得了黑磷并证明了这是磷的一种新的相变体，但在很长的一段时间内并没有引起人们的关注。20世纪中期以后，黑磷的制备方法得到了一定程度的发展。至2014年，研究者成功制备了二维黑磷场效应晶体管，随后人们发现黑磷在储能设备、光电子器件、光催化、生物传感等方面都有巨大的应用潜力。随着黑磷制备方法的发展和人们对黑磷认识的深入，黑磷的应用也会有更广阔的前景。","abstractInfoEn":"In 1914, American physicist Bridgman accidentally produced black phosphorus and proved that it was a new variant of phosphorus, but for a long time it did not attract much attention. After the mid-20th century, the preparation of black phosphorus has been developed to a certain extent. In 2014, researchers successfully prepared a two-dimensional black phosphorus field effect transistor, subsequently, it was found that black phosphorus has great application potential in energy storage devices, optoelectronic devices, photocatalysis, bio-sensing and other fields. With the development of preparation methods of black phosphorus and the deepening of people's understanding of black phosphorus, the application of black phosphorus will also have a broader prospect.","articleNo":"hxtb-84-2-185","authorCnList":["曹福臣"," 袁振东"],"authorEnList":["Fuchen Cao"," Zhendong Yuan"],"authorList":["曹福臣"," 袁振东"],"authors":"曹福臣, 袁振东","authorsCn":"曹福臣, 袁振东","authorsEn":"Fuchen Cao, Zhendong Yuan","categoryName":"化学史","categoryNameCn":"化学史","categoryNameEn":"","citation":"曹福臣, 袁振东. 黑磷的发现及其制备和应用发展史. 化学通报, 2021, 84(2): 185-191.","citationCn":"曹福臣, 袁振东. 黑磷的发现及其制备和应用发展史. 化学通报, 2021, 84(2): 185-191.","citationEn":"曹福臣, 袁振东. The Discovery, Preparation and Application History of Black Phosphorus. Chemistry, 2021, 84(2): 185-191.","doi":"","figContent":"hxtb-84-2-185-1.jpg$$hxtb-84-2-185-2.jpg$$hxtb-84-2-185-3.jpg$$hxtb-84-2-185-4.jpg$$hxtb-84-2-185-5.jpg$$hxtb-84-2-185-6.jpg","figList":["hxtb-84-2-185-1.jpg","hxtb-84-2-185-2.jpg","hxtb-84-2-185-3.jpg","hxtb-84-2-185-4.jpg","hxtb-84-2-185-5.jpg","hxtb-84-2-185-6.jpg"],"firstFig":"hxtb-84-2-185-1.jpg","fpage":"185","highCitedState":"","htmlCount":844,"htmlFile":"","id":"69eb8c53-713b-42fa-8c1d-530eff5faeca","issnPpub":"0441-3776","issue":"2","journalPublishId":"hxtb","journalReferenceCodeType":0,"journalTitleCn":"化学通报","journalTitleEn":"Chemistry","keyword":"黑磷, 二维材料, 制备与应用","keywordCn":"黑磷, 二维材料, 制备与应用","keywordCnList":["黑磷"," 二维材料"," 制备与应用"],"keywordEn":"Black phosphorus, 2D Material, Preparation and application","keywordEnList":["Black phosphorus"," 2D Material"," Preparation and application"],"keywordList":["黑磷"," 二维材料"," 制备与应用"],"language":"zh","latestInfo":"","latestState":"","latestStateEn":"","lpage":"191","oldUrl":"","pdfDownCount":43,"pdfSize":3315.8,"pubDate":"2021-02-18","recommendState":"","releaseState":"1","secCount":0,"title":"黑磷的发现及其制备和应用发展史","titleCn":"黑磷的发现及其制备和应用发展史","titleEn":"The Discovery, Preparation and Application History of Black Phosphorus","viewCount":2754,"volume":"84","year":2021}]}