Home

Citation: Gao Cai, Zhou Guo-Yan, Xu Yi, Hua Ze-Zhao. Freezing Properties of EG and Glycerol Aqueous Solutions Studied by DSC[J]. Acta Physico-Chimica Sinica, ;2004, 20(02): 123-128. doi: 10.3866/PKU.WHXB20040203 shu

Freezing Properties of EG and Glycerol Aqueous Solutions Studied by DSC

1.
Institute of Cryomedicine and Food Freezing, Shanghai University for Science and Technology, Shanghai　200093

Received Date: 18 June 2003
Available Online: 15 February 2004

In order to examine possible relationship between freezing properties and the number of hydroxyl group in solute molecules, a differential scanning calorimeter(Pyris-Diamond DSC)was employed to study the thermal behaviors(supercooling degree of heterogeneous nucleating temperature, hydration properties, glass transition and devitrification) of ethylene glycol and glycerol aqueous solutions. Experiments were conducted on 12 groups (24 in total) aqueous solutions with different concentrations. At the same concentrations (mass fraction, w), the supercooling behaviors of these two polyols aqueous solutions followed similar rules of change. At concentration of 0～5％(w), supercooling degrees decreased first and then increased with increasing concentration. But at concentration of 5％～25％(w), experimental results showed that supercooling behaviors became disorder. At concentrations >25％, supercooling degrees enhanced monotonically with the increasing solutes contents. Hydration experiments showed that the unfreezable water content in aqueous solutions of these two polyols solutions had no significant difference(ratios of unfreezable water contents are 1.04～1.15 ) with the same mass percentage. However, the temperature of glass transition and devitrification exhibited distinct difference. It can be concluded that “hydroxyl-group concentration” of this two polyols aqueous solutions could predict supercooling behaviors and hydration capabilities. Neither mass percentage nor molality of these two polyols solutions could characterize glass transition and devitrification temperature.
- Ethylene glycol(EG);Glycerol;Differential scanning calorimetry(DSC);　Supercooling degree;Hydration;Glass transition and devitrification
1. [1]
  Gang Ma , Siyu Jin , Bo Zheng , Lingyan Gao . Bound Water: Intelligent Regulation from Biological Hydrogen-Bond Networks to Artificial Materials. University Chemistry, 2026, 41(4): 275-279. doi: 10.12461/PKU.DXHX202504088
2. [2]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
3. [3]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
4. [4]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
5. [5]
  Shiyi Chen , Jialong Fu , Jianping Qiu , Guoju Chang , Shiyou Hao . Waste medical mask-derived carbon quantum dots enhance the photocatalytic degradation of polyethylene terephthalate (PET) over BiOBr/g-C₃N₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(1): 100135-0. doi: 10.1016/j.actphy.2025.100135
6. [6]
  Ranhui Fu , Shixin Zhou , Ran Ji , Feifei Gao , Hui Xu . 季膦盐合成实验的改进与拓展——水相一步法合成乙基三苯基溴化膦及其力致发光锰配合物的制备及表征. University Chemistry, 2026, 41(5): 252-263. doi: 10.12461/PKU.DXHX202510018
7. [7]
  Dawei Zhang , Lei Zhang , Yibo Zhou , Yajie Li , YuPeng Guo . Developing a “One Core, Three Dimensions, Five Integrations” Chemistry Curriculum System for Non-Chemistry Majors at Jilin University. University Chemistry, 2025, 40(12): 147-156. doi: 10.12461/PKU.DXHX202510089
8. [8]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
9. [9]
  Yuai Duan , Xuanyu Gan , Yao Fu , Yingjie Cao , Hongliang Han , Zhanfang Ma . Application and Innovative Design of Digital Technology in the Preparation Experiment of Cis(Trans)-Diglycine Copper Complexes. University Chemistry, 2026, 41(1): 373-381. doi: 10.12461/PKU.DXHX202504048
10. [10]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
11. [11]
  Baitong Wei , Rongxiu Zhu , Zhenghu Xu . Thalidomide: Defeating the Three Evils. University Chemistry, 2026, 41(2): 273-278. doi: 10.12461/PKU.DXHX202502020
12. [12]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
13. [13]
  Xiaopei HE , Jing HAN , Zhong YU , Na YE , Yi WAN . Preparation and antimicrobial properties of polyvinyl alcohol composite film based on Ag(Ⅰ) complex. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 531-542. doi: 10.11862/CJIC.20250271
14. [14]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
15. [15]
  Xiqing Liang , Tian Zhao , Jiawei Li , Haohui Tan , Hai Chen , Liyan Zeng . Pentaerythritol’s Journey of Making Friends. University Chemistry, 2025, 40(10): 175-185. doi: 10.12461/PKU.DXHX202412009
16. [16]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
17. [17]
  Zehua Zhao , Xiaoyan An , Jinrong Xu , Ling Yang , Hao Zhao , Zhongyun Wu . Independent Development and Application of Calorimetric Experiment Data Acquisition and Processing Software. University Chemistry, 2025, 40(11): 402-408. doi: 10.12461/PKU.DXHX202505045
18. [18]
  Hui Wang , Yiwen Zhang , Dong Liu . “三全育人”理念下培养应用型创新人才——以“赛教结合”模式为例的探索与实践. University Chemistry, 2025, 40(6): 37-42. doi: 10.12461/PKU.DXHX202407091
19. [19]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
20. [20]
  Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121

Get Citation

PDF

XML

Metrics

PDF Downloads(3393)
Abstract views(4493)
HTML views(79)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return