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Citation: Li Shu-Qin, Sang Wen-Qiang, Lin Rui-Sen. Volumetric Properties of Serine in Glucose-water and Sucrose-water Mixed Solvents at 298.15 K[J]. Acta Physico-Chimica Sinica, ;2002, 18(12): 1110-1115. doi: 10.3866/PKU.WHXB20021211 shu

Volumetric Properties of Serine in Glucose-water and Sucrose-water Mixed Solvents at 298.15 K

1.
Photosynthesis Center, Institute of Botany, Chinese Academy of Sciences, Beijing　100093; Department of Chemistry, Zhejiang University, Hangzhou　310027

Received Date: 18 March 2002
Available Online: 15 December 2002

Densities of serine in glucose-water and sucrose-water mixed solvents have been measured at 298.15 K by an oscillating-tube densimeter. Apparent molar volumes, limiting partial molar volumes and number of hydration of serine have been calculated. The transfer volumes from water to sugar-water mixtures have been obtained and discussed in terms of the structural hydration interaction model. The results obtained have been compared with that in glycerol-water and ethylene glycol-water mixtures. It is concluded that the magnitude of enhancement effect on volume is related to the number of OH groups.
- Serine;Glucose-water mixed solvents;Sucrose-water mixed solvents;　Limiting partial molar volumes;Structural interaction
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