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Citation: Wei Wu-Ji, Fu Hai-Tao, Li Ying, Zhu Yi-Fan. SERS Study on Adsorption of AMT on Bronze[J]. Acta Physico-Chimica Sinica, ;2002, 18(02): 152-155. doi: 10.3866/PKU.WHXB20020212 shu

SERS Study on Adsorption of AMT on Bronze

1.
Nanjing University of Technology， Nanjing　210009;State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang　110015

Received Date: 23 July 2001
Available Online: 15 February 2002

New aspects of molecular interaction in corrosion inhibition are firstly reported in this investigation of 2-amino-5-mercapto-1,3,4-thiadiazole (AMT) on bronze using surface enhanced Raman scattering (SERS). The adsorption on bronze of the corrosion inhibitors 2-amino-5-mercapto-1，3，4-thiadiazole has been characterized in the AMT solution with and without Cl－ using electrochemical techniques and surface enhanced Raman spectroscopy. AMT is adsorbed in a perpendicular position at a given concentration. Cl－ and AMT are strongly coadsorbed on the surface of bronze in the presence of Cl－.
- Adsorption;2-amino-5-mercapto-1，3，4-thiadiazole（AMT）;Bronze;SERS; Cl^－
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