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Citation: Sun Jian, Liu Yang, Chen De-Wen, Zhang Qi-Yuan. Catalysis of Methyl Viologen in the Reaction between C₆₀ and Et₃N[J]. Acta Physico-Chimica Sinica, ;1999, 15(12): 1088-1091. doi: 10.3866/PKU.WHXB19991207 shu

Catalysis of Methyl Viologen in the Reaction between C₆₀ and Et₃N

1.
State Key Laboratory of Structural Chemistry for Unstable and Stable Species,Institute of Chemistry,The Chinese Academy of Sciences,Beijing 100080

Received Date: 12 March 1999
Available Online: 15 December 1999

The catalytic role of MV 2+ in the electron transfer reaction between C 60 and Et 3N was directly proved by means of ESR technique. The active radical intermediate produced during the catalysis was confirmed to be MV +• andC 60-•radicals. In contrast, without the presence of MV 2+ the process of the electron transfer can not proceed at room temperature any more.
- Electron transfer reaction;C₆₀;Methyl viologen;Catalysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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Catalysis of Methyl Viologen in the Reaction between C60 and Et3N

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通讯作者: 陈斌, bchen63@163.com

Catalysis of Methyl Viologen in the Reaction between C₆₀ and Et₃N