Home

Citation: Zhan Chuan-Lang, Wang Duo-Yuan. Determination of the Molecular First-order Hyperpolarizabilities of Six Stilbzolium-like Dyes in Solid State and the Solvent Effects[J]. Acta Physico-Chimica Sinica, ;1999, 15(09): 805-811. doi: 10.3866/PKU.WHXB19990907 shu

Determination of the Molecular First-order Hyperpolarizabilities of Six Stilbzolium-like Dyes in Solid State and the Solvent Effects

1.
Laboratory of Photochemistry,The Center for Molecule Science,The Chinese Academy of Sciences,Beijing 100101

Received Date: 20 November 1998
Available Online: 15 September 1999

By using the solvatochromism, we have studied the solvent effects on the molecular first-order hyperpolarizabilities of six stilbazolium like dyes: trans-4-(N,N-dimethylamino)-(4-N-methylpyridinio)-stilbazolium iodide (DAPSI),trans-(N-methylpyrrol-2-yl)-4-(N-methyl-pyridinio)-stilbazolium iodide(MPPSI),trans-(pyrrol-2-yl)-4-(N-methyl-pyridinio)-stilbazolium iodide(PPSI),trans-(furan-2-yl)-4-(N-methyl-pyridinio)-stilbazolium iodide (FPSI) and trans-(thiophene-2-yl)-4-(N-methyl-pyridinio)-stilbazolium iodide (TPSI),and trans-(4-methyl-pyridinio)-stilbazolium iodide(pSI),and obtained the results that the molecular hyperpolarizabilities are in linear correlation with the solvent polarity, E T(30),and introduced the concept that the effects on the energy levels of the compound by the solvent is equavalent to those by the surrounding molecules of the compound itself ,from which we calculated the molecular first order hyperpolarizabilities β s xxx of the six dyes in pure solid state, as -46,7,-7 1,-6 7,-3 1,-2 2,and 0 55×10 -27 esu for DAPSI, MPPSI, PPSI, FPSI, TPSI and PSI, respectively. And we also obtained the perfect linearity relationship between the β s xxx and the electron excessivities of the donor for the latter five dyes.
- Stibazolium-like,
- Dye,
- Pyridium,
- Solvent effect,
- Hyperpolarizability
1. [1]
  Quan Liu , Jian Feng , Yuekun Qu , Jiayao Bai , Xunian Ren , Qi Wang , Haitao Xu , Shengrui Zhang . “神笔马良”——基于热致变色染料的创意绘画科普演示实验. University Chemistry, 2026, 41(5): 149-158. doi: 10.12461/PKU.DXHX202511095
2. [2]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-0. doi: 10.3866/PKU.WHXB202309027
3. [3]
  Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
4. [4]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
5. [5]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
6. [6]
  Haiying Jiang , Liuhong Song , Yangyang Cheng , Kefen Yue , Mingli Peng , Huilin Guo . Ph―C≡C―Cu_2.5的力致变色现象探究——推荐一个物理化学实验. University Chemistry, 2025, 40(8): 249-254. doi: 10.12461/PKU.DXHX202410003
7. [7]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
8. [8]
  Guangrong Wu , Jiahui Zhu , Xiaomeng Guo , Changmiao Zhang , Mengting He , Hua Qiu , Dongwei Ma . Construction of Schottky barrier and the enhanced interface polarization effect of C@ZnO/Sn@GaN for high performance electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100324-0. doi: 10.1016/j.actphy.2026.100324
9. [9]
  Zhao Gao , Jianxiang Sun , Bin Mu , Yi Yan , Wei Tian . Exploration of Supramolecular Polymer “Chameleons” in Innovative Chemistry Experiments. University Chemistry, 2026, 41(4): 349-355. doi: 10.12461/PKU.DXHX202504044
10. [10]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
11. [11]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
12. [12]
  Yujie WANG , Laobang WANG , Zheng ZHANG , Qi LIU , Jianping LANG . Construction of W/Cu/S cluster-based supramolecular compounds via alkynyl/sulfur cycloaddition and their third-order nonlinear optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2069-2077. doi: 10.11862/CJIC.20250129
13. [13]
  Chengshan Yuan , Xiaolong Li , Xiuping Yang , Xiangfeng Shao , Zitong Liu , Xiaolei Wang , Yongwen Shen . Standardized Operational Guidelines for Mixed-Solvent Recrystallization in Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 122-127. doi: 10.12461/PKU.DXHX202504073
14. [14]
  Peipei DING , Jingying DUAN , Haoran XU , Xinru FANG , Xingyu LIU , Juntao YAN , Chunlei WANG . Preparation and adsorption properties of poplar catkin-derived porous carbon by ethanol solvothermal method. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1203-1214. doi: 10.11862/CJIC.20250370
15. [15]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
16. [16]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
17. [17]
  Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121
18. [18]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
19. [19]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
20. [20]
  Haobin Zhou , Shuai Du , Xuesong Guo , Yue Wang , Qin Zhong , Tong Wang , Yuzhi Wang , Shuangyan Huan , Hailong Yan , Kun Li . 阳极溶出伏安法测定水中微量镉的无汞化改进. University Chemistry, 2026, 41(5): 275-284. doi: 10.12461/PKU.DXHX202511142

Get Citation

PDF

XML

Metrics

PDF Downloads(2329)
Abstract views(3605)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return