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Citation: Lu Xiu-Hui, Wang Yi-Xuan, Deng Cong-Hao. A Theoretical Study on the Cycloaddition Reaction of Silylene and Ethylene[J]. Acta Physico-Chimica Sinica, ;1998, 14(04): 332-336. doi: 10.3866/PKU.WHXB19980409 shu

A Theoretical Study on the Cycloaddition Reaction of Silylene and Ethylene

1.
Chemistry Department,Jinan University,Jinan 250002

Received Date: 10 July 1997
Available Online: 15 April 1998

The cycloaddition reaction of silylene(SiH2, A) and ethylene has been studied by using ab initio calculations, a reasonable mechanism of the reaction has been suggested. The thermodynamic and kinetic properties of the reaction have been calculated by statistical thermo-dynamic method and transition-state theory(TST).
- Silylene,
- Cycloaddition reaction,
- Ab initio calculation,
- Thermodynamic and kinetic calcuulation
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