Home

Citation: Wu Cheng-Yin, Chu Yan-Nan, Cao De-Zhao. Chemiluminescent Reactions of Fluorine Atoms with lodine Molecules[J]. Acta Physico-Chimica Sinica, ;1997, 13(10): 885-889. doi: 10.3866/PKU.WHXB19971005 shu

Chemiluminescent Reactions of Fluorine Atoms with lodine Molecules

1.
Laser Spectroscopy Laboratory,Anhui Institute of Pptics and Fine Mechanics,Academia Sinica,Hefei 230031

Received Date: 30 January 1997
Available Online: 15 October 1997

In the flowing afterglow system, strong emission spectrum of IF(B-X) has been observed from the reaction of F atoms with Iodine molecules. The IF(B) vibrational distribution was measured, it has a striking similarity to that of F atoms with other iodide flames, being Boltzmann for the lower vibrational levels (v' <5), but having an excess population for the higher levels. In addition, the IF(B) intensity shows a quadratic dependence on fluorine atom concentration. These results lead us to suggest that the simple three-body recombination of a ground state fluorine atom with an excited state iodine atom is the origin of the IF(B) in this reaction.
- Flowing afterglow,
- Chemiluminescence,
- Energy transfer,
- Chemical laser
1. [1]
  Borong Yu , Huijiao Zhang , Xinyu Zhang , Xiaoying Li , Shuming Chen , Zhangang Han . The Blue Elf in the Dark: Gradient Science Popularization Experiments on Chemiluminescence. University Chemistry, 2024, 39(9): 295-303. doi: 10.12461/PKU.DXHX202403107
2. [2]
  Xun Pei , Jiahui Liu , Haozhuo Liu , Qiuhong Wei , Xiaocui Chen , Ranxiao Tang . 微光成炬——爆炸盐“点亮”鲁米诺化学发光的奇妙之旅. University Chemistry, 2026, 41(5): 239-251. doi: 10.12461/PKU.DXHX202511119
3. [3]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
4. [4]
  Qi Wu , Changhua Wang , Yingying Li , Xintong Zhang . Enhanced photocatalytic synthesis of H₂O₂ by triplet electron transfer at g-C₃N₄@BN van der Waals heterojunction interface. Acta Physico-Chimica Sinica, 2025, 41(9): 100107-0. doi: 10.1016/j.actphy.2025.100107
5. [5]
  Wenqian Zhang , Zhi Yang , Shunxiang Wu , Lei Yang , Bang Gu . Chemiluminescence: Colorful Experiments Unveiled. University Chemistry, 2026, 41(3): 307-321. doi: 10.12461/PKU.DXHX202505037
6. [6]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
7. [7]
  Cun WANG , Shaohan XU , Yuqian ZHANG , Yaoyao ZHANG , Tao GONG , Rong WEN , Yuhang LIAO , Yanrong REN . Terbium complex electrochemiluminescent emitters: Synthesis and application in the detection of epinephrine. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1351-1360. doi: 10.11862/CJIC.20240427
8. [8]
  Tinghui AN , Dong XIANG , Jiaqi LI , Jiawei WANG , Shuming YU , Nan WANG , Kedi CAI . Research progress on the application of laser synthesis technology for electrochemical functional materials. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1731-1754. doi: 10.11862/CJIC.20240412
9. [9]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
10. [10]
  Ting Li , Xiao Zeng , Yuzhuo Yang , Xinyi Wen , Shurong Ding , Linlin Shi , Yongqiang Zhang , Siyu Lu . Towards practical circularly polarized luminescence: carbon dots-based circularly polarized lasers. Acta Physico-Chimica Sinica, 2026, 42(4): 100191-0. doi: 10.1016/j.actphy.2025.100191
11. [11]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
12. [12]
  Wenkai Chen , Yunjia Shen , Xiangmeng Kong , Yanli Zeng . Quantum Chemistry Calculation of Key Physical Quantity in Circularly Polarized Luminescence: Introducing an Exploratory Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 83-91. doi: 10.12461/PKU.DXHX202405018
13. [13]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
14. [14]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
15. [15]
  Pan Li , Huguo Shen , Cong Hua , Jinjie Fang , Xiangying Chi , Quan Jiang , Zichen Feng , Ye Kang , Bin Zheng . Synthesis and Characterization of an Aggregation-Induced Emission-Active Organic Cage Molecule: A Proposed Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(11): 337-345. doi: 10.12461/PKU.DXHX202502083
16. [16]
  Yubin Su , Chenyu Yao , Shuyan Chen , Lisha Xu , Min Peng , Yawen Wang , Yu Peng , Jianfeng Zheng . 一种聚集诱导发光荧光探针的合成及其在指纹显影中的应用——本科生综合性化学实验探索. University Chemistry, 2026, 41(5): 70-78. doi: 10.12461/PKU.DXHX202511031
17. [17]
  Xinglong ZHANG , Zhonghui LI , Jifeng BAN , Xingsheng ZHAO , Changli LIU , Xiaokang JIANG , Hengwei ZHOU . Color-tunable luminescence and energy transfer in Cs₂NaGdCl₆ via a Sb³⁺/Sm³⁺ co-doping strategy. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1237-1246. doi: 10.11862/CJIC.20250322
18. [18]
  Xuexia He , Zhibin Lei , Pei Chen , Qi Li , Weiyu Deng , Peng Hu . 以“溶度积规则”指导电荷转移共晶沉淀析出——材料类专业无机化学教学改革案例. University Chemistry, 2025, 40(8): 1-10. doi: 10.12461/PKU.DXHX202410099
19. [19]
  Yun Chen , Daijie Deng , Li Xu , Xingwang Zhu , Henan Li , Chengming Sun . Covalent bond modulation of charge transfer for sensitive heavy metal ion analysis in a self-powered electrochemical sensing platform. Acta Physico-Chimica Sinica, 2026, 42(1): 100144-0. doi: 10.1016/j.actphy.2025.100144
20. [20]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001

Get Citation

PDF

XML

Metrics

PDF Downloads(2059)
Abstract views(3539)
HTML views(93)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return