Home

Citation: Sheng Liu-Si, Qi Fei, Gao Hui, Zhang Yun-Wu, Yu Shu-Qin. Vacuum-ultraviolet Photoion Spectrum of Vinyl Chloride Near Ionization Threshlod[J]. Acta Physico-Chimica Sinica, ;1997, 13(07): 647-649. doi: 10.3866/PKU.WHXB19970715 shu

Vacuum-ultraviolet Photoion Spectrum of Vinyl Chloride Near Ionization Threshlod

1.
National Synchrotron Radiation Laboratory,University of Science and Technology of China,Hefei 230026

Received Date: 26 November 1996
Available Online: 15 July 1997

The photoionization efficiency curve (PIE) of C2H3Cl+ formation from C2H3Cl has been measured in wavelength region 105.0- 130.0nm, by using synchrotron radiation single- photon ionization and a quadrupole mass spectromemter as a detector. A series of peaks in region 106.0-117.0nm arise from Rydberg autoionization converging to A2A' state of the vinyl chloride ion, the average quantum defects are δ(ns) = 1.87, δ(np) = 1.51,δ(nd) = 0.22 respectively. The Rydberg transitions of π(2a") → 4d, π(2a") →5d, π(2a")→6s, π(2a") →7s have been assigned also.
- Synchrotron radiation,
- Photoionization,
- Vinyl chloride(C₂H₃Cl),
- Rydlberg state
1. [1]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-0. doi: 10.3866/PKU.WHXB202309036
2. [2]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
3. [3]
  Qi Wu , Changhua Wang , Yingying Li , Xintong Zhang . Enhanced photocatalytic synthesis of H₂O₂ by triplet electron transfer at g-C₃N₄@BN van der Waals heterojunction interface. Acta Physico-Chimica Sinica, 2025, 41(9): 100107-0. doi: 10.1016/j.actphy.2025.100107
4. [4]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
5. [5]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
6. [6]
  Chunfang Zhang , Yuehua Liu , Lin Yang , Wenhui Xu , Mingtao Run , Cuimiao Zhang . 醋酸电离平衡常数测定实验的改进. University Chemistry, 2026, 41(5): 131-140. doi: 10.12461/PKU.DXHX202511002
7. [7]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . Defective Ultrathin Two-Dimensional Materials for Photo-/Electrocatalytic CO₂ Reduction: Fundamentals and Perspectives. Acta Physico-Chimica Sinica, 2025, 41(3): 100019-0. doi: 10.3866/PKU.WHXB202308052
8. [8]
  Yanbo LIU , Jiadong LIU , Qing XIONG , Wutong ZHANG , Zhaosheng ZHANG . First-principles study on the optoelectronic properties and defect characteristics of CeBN₃ (B=Ta, Nb). Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1155-1163. doi: 10.11862/CJIC.20260018
9. [9]
  Gang ZHANG , Jian ZHANG , Haiyang CHU , Chongxin QIAN , Lai WEI . Chlorobenzene additive-assisted regulation of (PMA)₂PbBr₄ crystal growth and photoelectric properties. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 713-721. doi: 10.11862/CJIC.20250318
10. [10]
  Huahong ZHANG , Yang ZHAO , Rui NING , Shuixing WU , Xiaopeng ZHANG . Coordination equilibrium between cyclometalated Pt(Ⅱ) complexs [Pt(κ³-N^C^N′)(CNXyl)]Cl and [Pt(κ²-N^C^N′)(CNXyl)Cl]. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1840-1850. doi: 10.11862/CJIC.20250136
11. [11]
  Lihui Ou , Zhancheng Liu , Dai-Huo Liu , Zhi Zhang . Cl-adsorbed Cu(111)/H₂O interface selectively realizes electrochemical CO₂ reduction towards C₂H₄ product: Mechanistic understanding. Chinese Chemical Letters, 2026, 37(2): 111920-. doi: 10.1016/j.cclet.2025.111920
12. [12]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
13. [13]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-0. doi: 10.3866/PKU.WHXB202309027
14. [14]
  Lianghong Ye , Junqing Ni , Zhongyi Yan , Zhanming Zhang , Can Zhu , Mo Sun . Chemical Fuel-Driven Non-Equilibrium Color Change. University Chemistry, 2025, 40(3): 349-354. doi: 10.12461/PKU.DXHX202406109
15. [15]
  Kaixin Lai , Ke Wang , Xinwei Tang , Tian Sun , Yan Li , Zhiwei Hu , Wei Li , Wei Hong , Wenkai Chen , Xinyi Jiang , Zicheng Wang , Tianxi Liu . Selective thermal radiation polyimide composite fabric for efficient infrared stealth and electromagnetic protection. Acta Physico-Chimica Sinica, 2026, 42(7): 100272-. doi: 10.1016/j.actphy.2026.100272
16. [16]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
17. [17]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
18. [18]
  Xuan Pang , Leyan Nian , Yongzhang Wang , Chunmei Huang . Na2(C6H4NO3)2∙H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence. Chinese Journal of Structural Chemistry, 2026, 45(4): 100847-100847. doi: 10.1016/j.cjsc.2025.100847
19. [19]
  Huakang Zong , Xinyue Li , Yanlin Zhang , Faxun Wang , Xingxing Yu , Guotao Duan , Yuanyuan Luo . Pt/Ti₃C₂ electrode material used for H₂S sensor with low detection limit and high stability. Chinese Chemical Letters, 2025, 36(5): 110195-. doi: 10.1016/j.cclet.2024.110195
20. [20]
  Xiu-Mei Xie , Hongyang Zhang , Shao-Xuan Gong , Hong-Xia Sun , Yu-Ting Liu , Xue-Ling Chen , Shuming Chen , Tian-Yu Gao , Wai-Yeung Wong , Zhen Zhang , Da-Gang Yu . Carbonylation of C(sp³)–H bonds with CO₂: Facile synthesis of 2,4-quinolinediones and related luminescent materials. Chinese Chemical Letters, 2026, 37(3): 112003-. doi: 10.1016/j.cclet.2025.112003

Get Citation

PDF

XML

Metrics

PDF Downloads(2238)
Abstract views(3992)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return