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Citation: Liu Chi-Biao, Zhao Zhen, Yang Xiang-Guang, Ye Xing-Kai, Wu Yue. Investigation of Catalysis of Y-Ba-Cu-O Mixed Oxides in Phenol Hydroxylation[J]. Acta Physico-Chimica Sinica, ;1996, 12(11): 1044-1048. doi: 10.3866/PKU.WHXB19961119 shu

Investigation of Catalysis of Y-Ba-Cu-O Mixed Oxides in Phenol Hydroxylation

1.
Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022

Received Date: 15 April 1996
Available Online: 15 November 1996

Superconductor Y-Ba-Cu-O mixed oxides were synthesized and their catalysis in phenol hydroxylation was studied too. Results show that, Y2BaCuO5 has better activity than that of YBa2Cu3O7-x, With the catalysis study of another mixed oxide La2CuO4 a conclusion that AO structure unit is the key for mixed oxides to have high activity in phyenol hydroxylation was drawn. Meanwhile, the effects of reaction temperature, medium and medium (water) pH on phenol hydroxylation catalyzed by Y2BaCuO5 and the stability of the mixed oxides were also studied.
- Mixed oxide,
- Phenol hydroxylation,
- Hydrogen peroxide,
- Phenol
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