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Citation: Xu Zong-Rong, Gao Yan-Ling. Reactive Dynamics for Si₄₊Si₃:Influences of Vibrationally Excited State to Reaction[J]. Acta Physico-Chimica Sinica, ;1996, 12(05): 396-399. doi: 10.3866/PKU.WHXB19960503 shu

Reactive Dynamics for Si₄₊Si₃:Influences of Vibrationally Excited State to Reaction

1.
Institute of Atomic and Molecular Sciences,Sichuan Union University,Chengdu 610065

Received Date: 11 September 1995
Available Online: 15 May 1996

Using the quasiclassical trajectory method, the influences of the vibrationally excited state of reactant cluster in Si4+Si3 have been studied. The reactive cross sections for each channel in reaction Si4+Si3, Si4(n1 =5)+Si3 and Si4+Si3(n1’ =5) have been calculated and the results show that the cluster(s) in the vibrationally excited state(s) is in favor of the deeply inelastic collision. One can control the product channels by means of controling the vibrational excitation of the reactant channel.
- Si_n cluster,
- Clusters reactive dynamics,
- Reactive cross section
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Reactive Dynamics for Si4+Si3:Influences of Vibrationally Excited State to Reaction

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通讯作者: 陈斌, bchen63@163.com

Reactive Dynamics for Si₄₊Si₃:Influences of Vibrationally Excited State to Reaction