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Citation: Shi Yang, Gao Zhen, Zhu Qi-He, Kong Fan-Ao. Atomic and Molecular Clustering Kinetics in Gas Phase I.Basic Model of Chemical Kinetics[J]. Acta Physico-Chimica Sinica, ;1996, 12(03): 196-201. doi: 10.3866/PKU.WHXB19960302 shu

Atomic and Molecular Clustering Kinetics in Gas Phase I.Basic Model of Chemical Kinetics

1.
State Key Laboratory of Molecular Reaction Dynamics Institute of Chemistry,Academia Sinica,Beijing 100080

Received Date: 26 May 1995
Available Online: 15 March 1996

A general model is suggested for the kinetics of clustering processes. It is considered that cluster species are composed of units of specific composition. Arbitrary combinations occur between the species. The association rate constant depends on the cluster size and the structural feature. The dissociation rate constant mainly depend on the number of bonds broken during dissociation. Thus the small fragments are easier to be cleavaged. The master equations for the kinetic model are given. They can be used for the numercial calculation of the cluster distribution at various time. Finally, the clustering processes during laser ablation and arc discharge are discussed.
- Cluster,
- Clustering kinetics,
- Size destribution of cluster
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