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Citation: Wu Bing-Fang, Su Hai-Quan, Yan Xiu-Ying, Hu Xiang, Liu Shu-Tang, Liu Qi-Wang, Shi Jian-Qiu. Synthesis and Crystal Structure of Rh₂(μ-SC₆H₅)₂(CO)₄[J]. Acta Physico-Chimica Sinica, ;1994, 10(09): 847-851. doi: 10.3866/PKU.WHXB19940915 shu

Synthesis and Crystal Structure of Rh₂(μ-SC₆H₅)₂(CO)₄

1.
Department of Chemsitry,Nei Monggu University,Huhehot 010021

Received Date: 27 April 1993
Available Online: 15 September 1994

The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compound has been determined by X-ray diffraction. The crystal system is monoclinic, space group P21/a, a=17.390(8), b=8.983(9),c=24.35(2)Å, β =103.84(4); V=3693(5)Å3, Z=8, DC=1.93g.cm-3. R=0.057, RW=0.064, The intramolecular Rh-Rh distances are 3.090 and 3.078Å respectively.
- Dinuclear rhodium carbonyl,
- Bridging thiolate ligand,
- Crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis and Crystal Structure of Rh₂(μ-SC₆H₅)₂(CO)₄