Citation:
Hu Yi-Hua, Chu Yan-Nan, Ni Jin-Zhi, Li Ying-Chun, LI Shu-Chao, Cao De-Zhao, Guo Jing-Zhong, Liu Chuan-Pu, Gu Yue-Shu. Chemiluminescence of the Reaction of He*(23S)/CO2 with CS2[J]. Acta Physico-Chimica Sinica,
;1994, 10(04): 293-296.
doi:
10.3866/PKU.WHXB19940402
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The reaction of He~*(2~3S)/CO_2 with CS_2 has been studied in discharge fiowing-afterglow apparatus. The emission spectra from exited state products CS~+_2(A)、CS (A,a) have been observed. The formation mechbosm proposed is:
CO~+_2(X)+CS_2→CS~+_2(A)+CO_2
CO(a)+CS_2→OCS(X)+CS(A)
CO(a)+CS_2→OCS(X)+CS(a)-
Keywords:
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Energy transfer
, - Chemiluminescence,
- CS2,
- Charge-transfer reaction
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