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Citation: Li Chong-Jia, Zhang Wen-Tao, Guo Guo-Lin, Xie You-Chang. A Study on the Co(II) Schiff Base Complex with Carrying O₂ and N₂ Properties[J]. Acta Physico-Chimica Sinica, ;1994, 10(03): 230-234. doi: 10.3866/PKU.WHXB19940308 shu

A Study on the Co(II) Schiff Base Complex with Carrying O₂ and N₂ Properties

1.
Institute of Physical Chemistry, Peking University, Beijing 100871

Received Date: 12 August 1992
Available Online: 15 March 1994

The character of Co(Ⅱ) Schiff base complex carrying O_2 was studied by INDO-UHF method. The results showed that the interaction between Co(Ⅱ) and O_2 was completed through σ bond, and the antiferro magnetic coupling was obvious. The ne cessity of fifth axial ligand in the reversible process of O_2 carring was discussed. The interaction between Co(Ⅱ) and N_2 was also studied in comparasion with Co-O_2. The cal culation showed that Co(Ⅱ) Schiff base have potential value for industrial application.
- Co(II) Schiff base complex,
- INDO-UHF program,
- Carrying O2 property
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A Study on the Co(II) Schiff Base Complex with Carrying O2 and N2 Properties

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通讯作者: 陈斌, bchen63@163.com

A Study on the Co(II) Schiff Base Complex with Carrying O₂ and N₂ Properties