Citation:
Le Qing-Hua, Xu Jin-Lin, Shi Ya-Jun. Catalytic Activity of Vanadium Pentoxide for the Absorption of Carbon Dioxide by Potassium Carbonate Solution[J]. Acta Physico-Chimica Sinica,
;1992, 8(06): 753-759.
doi:
10.3866/PKU.WHXB19920608
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The chemical mechanism that vanadium pentoxide, as an additive, enhances the absorption rate of carbon dioxide in aqueous potassium carbonate solution has been suggested.
Experiments proved that V_2O_5 exists as V_2O_7~(4-) and V_4O_(12)~(4-) in the carbonate solution, as pH value is in the range of 9—12. The catalytic action of V_2O_5 is only related to the concentration of V_2O_7~(4-) and pH value of the solution, the optimum range of pH value is 10.6 to 10.8, and the quantity of V_2O_5 added has to be restricted in order to maintain the optimized pH range. -
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