Home

Citation: Xie En-Hai, Meng Qing-Shui, Wang Zhi-Pu. Kinetics of Oxidation of Sodium Tartrate by Ni(IV) Periodate Complex in Aqueous Alkaline Medium[J]. Acta Physico-Chimica Sinica, ;1992, 8(04): 500-504. doi: 10.3866/PKU.WHXB19920414 shu

Kinetics of Oxidation of Sodium Tartrate by Ni(IV) Periodate Complex in Aqueous Alkaline Medium

1.
Department of Chemistry, Hebei University, Baoding 071002

Received Date: 16 December 1990
Available Online: 15 August 1992

The kinetics and mechanism of electron transfer from sodium tartrate to Ni(Ⅳ) periodate complex have been studied in aqueous alkaline medium using spectroscopic and stopped-flow method. The kinetics exhibits a pseudo first order for the disap-pearance of Ni(Ⅳ) periodate complex when substrate is present in excess. The order for the substrate found is not an integer. Additon of NaIO_4 and NaOH affects the reaction rates. Results are interpreted in terms of a mechanism involving two separated steps of one-electron transfer from the substrate to the species containing Ni(IV). The activation parameters of this reaction have been calculated.
- Diperiodatonicolate; Stopped-Flow method; Kinetics and mechanism; Redox reaction
1. [1]
  Linlin Wu , Yonghua Zhou , Zhongbei Li , Liu Deng , Younian Liu , Limiao Chen , Jianhan Huang . Digital Education Promoting Applied Chemistry Comprehensive Experiments: A Case Study of Catalytic Oxidation of Hydrogen Chloride and Reaction Kinetics. University Chemistry, 2025, 40(9): 273-278. doi: 10.12461/PKU.DXHX202411018
2. [2]
  Gengwei Zhang , Jun Cao . 化学反应动力学方程的AI辅助发现——以蔗糖水解反应为例. University Chemistry, 2026, 41(9): 396-404. doi: 10.12461/PKU.DXHX202508037
3. [3]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
4. [4]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
5. [5]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
6. [6]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
7. [7]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
8. [8]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
9. [9]
  Jiageng Li , Putrama . 数值积分耦合非线性最小二乘法一步确定反应动力学参数. University Chemistry, 2025, 40(6): 364-370. doi: 10.12461/PKU.DXHX202407098
10. [10]
  Xinxin Dai , Di Lan , Xingliang Chen , Xingwei Wang , Guangbin Ji . One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids. Acta Physico-Chimica Sinica, 2026, 42(8): 100302-0. doi: 10.1016/j.actphy.2026.100302
11. [11]
  Yunhan Gao , Xing Sun , Mengxia Ji , Xingchang Qiu , Tiange Wei , Qing Xu , Sheng Yin , Jiexiang Xia , Huaming Li . Hierarchical ZIF-derived carbon/Bi₁₂O₁₇Cl₂ heterostructures synergistically enhance electron dynamics and optical properties to boost CO₂ photoreduction in pure water. Acta Physico-Chimica Sinica, 2026, 42(10): 100264-0. doi: 10.1016/j.actphy.2026.100264
12. [12]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
13. [13]
  Yukai SHEN , Zhaochao YAN , Yangjun ZHOU , Mei HUANG . Nickel foam-supported NiFeP/NiFcDCA heterojunction electrocatalyst for efficient urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 237-246. doi: 10.11862/CJIC.20250257
14. [14]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
15. [15]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
16. [16]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
17. [17]
  Ruikang Su , Muyan Bai , Zhiqing Liu , Fang Fang , Yuena Yu . Wittig反应与可见光氧化还原催化融合构建烯烃. University Chemistry, 2026, 41(8): 370-379. doi: 10.12461/PKU.DXHX202507075
18. [18]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
19. [19]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
20. [20]
  Chonghang Sun , Xingfang Zheng , Lin Li , Xiaolei Jiang , Fangdong Hu . 类比法在有机化学机理教学中的应用——以羰基化合物及羧酸衍生物为例. University Chemistry, 2026, 41(9): 382-391. doi: 10.12461/PKU.DXHX202508095

Get Citation

PDF

XML

Metrics

PDF Downloads(2413)
Abstract views(4016)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return