引用本文:
易希璋, 丁世良, 马力, 燕子杰, 邓从豪. 分子间散射问题的李代数处理 关于AB+CD系统的振动-振动能量传递[J]. 物理化学学报,
1990, 6(02): 209-214.
doi:
10.3866/PKU.WHXB19900215
Citation: Yi Xi-Zhang, Ding Shi-Liang, Ma Li, Yan Zi-Jie, Deng Cong-Hao. Lie Algebraic Approach to the Molecular Scattering Vibration-Vibration Energy Transfer for the System AB+CD[J]. Acta Physico-Chimica Sinica, 1990, 6(02): 209-214. doi: 10.3866/PKU.WHXB19900215
Citation: Yi Xi-Zhang, Ding Shi-Liang, Ma Li, Yan Zi-Jie, Deng Cong-Hao. Lie Algebraic Approach to the Molecular Scattering Vibration-Vibration Energy Transfer for the System AB+CD[J]. Acta Physico-Chimica Sinica, 1990, 6(02): 209-214. doi: 10.3866/PKU.WHXB19900215
分子间散射问题的李代数处理 关于AB+CD系统的振动-振动能量传递
摘要:
采用半经典近似方法所给出的关于AB+CD散射系统的相互作用势, 构造系统的一种动力学代数h_(15), 利用这种代数计算了在非反应情况下系统的跃迁几率及势能的统计平均值, 并在群参量的一次近似下探讨了跃迁过程中的选择定则。
English
Lie Algebraic Approach to the Molecular Scattering Vibration-Vibration Energy Transfer for the System AB+CD
Abstract:
A dynamic algebraic h_(15) is formed by using the semiclassical potential surface for AB+CD. The V-V energy transfer and the expectation of the potential are calculated; the selection rules are discussed under the first-order approximation of the group parameters.
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