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Citation: Chen Congxiang*, Liu Xin, Gao Jianmi, Kong Fanao. THE MEASUREMENT OF THE RATE CONSTANT OF REACTION BETWEEN O(³P) AND N-BUTANONE[J]. Acta Physico-Chimica Sinica, ;1988, 4(05): 535-538. doi: 10.3866/PKU.WHXB19880519 shu

THE MEASUREMENT OF THE RATE CONSTANT OF REACTION BETWEEN O(³P) AND N-BUTANONE

1.
Department of Modern Chemistry; University of Science andTechnology of China; Hefei; Anhui

Received Date: 22 January 1987
Available Online: 15 October 1988

The measurement of the kinetic rate constant of the reaction of O(~3P) atoms with n-butanone at 288K is carried out. O(~3P) atoms were generated by a microwave discharge flow system and the residual concentration was detected by NO_2* chemiluminescence. The specific rate constant obtained is
κ=(6.2±1.2)×10~(-15)cm~3 molecule~(-1) s~(-1) (T=288 K).
A correlation diagram of molecular orbitals for the reaction is discussed.
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THE MEASUREMENT OF THE RATE CONSTANT OF REACTION BETWEEN O(³P) AND N-BUTANONE