Home

Citation: H.Ti Tien, Bi Zhichu. THE PHOTOELECTRIC EFFECT OF POLYCARBONATE MEMBRANE CONTANING CdS[J]. Acta Physico-Chimica Sinica, ;1987, 3(03): 330-333. doi: 10.3866/PKU.WHXB19870319 shu

THE PHOTOELECTRIC EFFECT OF POLYCARBONATE MEMBRANE CONTANING CdS

H.Ti Tien ,
Bi Zhichu

1.
Michigan State University; U.S.A.
Institute of Photographic Chemistry; Academia Sinica

Received Date: 3 February 1986
Available Online: 15 June 1987

CdS deposited polycarbonate membranes were made by a very simple way: separation of a Lucite cell into two compartments by two pieces of Teflon sheets which were tightly inserted into the slot of the cell. The membrane was placed between holes of the Teflon sheets. The cadmium nitrate aqueous solution were poured into one compartment, and sodium sulfide aqueous solution to the other chamber, were introduced simultaneously. The CdS precipitates formed in situ blocked the tiny holes of the membrane. On illumination, about 150 mV photovoltage (V_(op)) and 0.5 μAcm~(-2) photocurrent (I_(sc)) could be produced, one side of the membrane acted as photoanode and the other side photocathode. By means of coprecipitating CdS and FeS (the ratio of FeS to CdS in the mixture wasabout 1 : 1000) onto the membrane, the maximum V_(op) and I_(sc) of the membrane could reach 500 mV and 3.0 μAcm~(-2), respectively. CdS_xSe_(1-x) mixture deposited membrane has also been tested and found to have both the advantages ofhigh photovoltage (over 400 mV) and od stability after modification. The essential aspect of the system, modelled after the photosynthetic thylakoid membrane, contains an asymmetrical, ultrathin semiconductor polycrystallites membrane separating two aqueous solutions.
-----------------------------
* To whom all correspondence should should be addressed.
1. [1]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
2. [2]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
3. [3]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
4. [4]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
5. [5]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
6. [6]
  Changyan Sun , Hualei Zhou , Bin Dong . Application of “PBL” Teaching Mode in Inorganic Chemistry Experimental Education in the Perspective of Course Ideology and Politics: Taking Preparation of Manganese Carbonate as an Example. University Chemistry, 2024, 39(11): 378-383. doi: 10.12461/PKU.DXHX202402016
7. [7]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
8. [8]
  Minglei Sun , Zhong-Yong Yuan . Valorization strategies for electrodegradation of nitrogenous wastes in sewage. Acta Physico-Chimica Sinica, 2025, 41(9): 100108-0. doi: 10.1016/j.actphy.2025.100108
9. [9]
  Wen Jiang , Jieli Lin , Zhongshu Li . 低配位含磷官能团的研究进展. University Chemistry, 2025, 40(8): 138-151. doi: 10.12461/PKU.DXHX202409144
10. [10]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
11. [11]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 2309047-0. doi: 10.3866/PKU.WHXB202309047
12. [12]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
13. [13]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
14. [14]
  Minghui Wu , Markus Mühlinghaus , Xuechao Li , Chaojie Xu , Qiang Chen , Haiming Zhang , Klaus Müllen , Lifeng Chi . On-Surface Synthesis of Chevron-Shaped Conjugated Ladder Polymers Consisting of Benzo[a]azulene Units. Acta Physico-Chimica Sinica, 2024, 40(8): 2307024-0. doi: 10.3866/PKU.WHXB202307024
15. [15]
  Ruilan Fan , Xiaoling Huang . 磷源的选择及三种含磷阻燃剂的合成与阻燃性. University Chemistry, 2025, 40(8): 181-191. doi: 10.12461/PKU.DXHX202410025
16. [16]
  Yuhang Zhang , Weiwei Zhao , Hongwei Liu , Junpeng Lü . Progress on Self-Powered Photodetectors Based on Low-Dimensional Materials. Acta Physico-Chimica Sinica, 2025, 41(3): 2310004-0. doi: 10.3866/PKU.WHXB202310004
17. [17]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 2309045-0. doi: 10.3866/PKU.WHXB202309045
18. [18]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . Photomultiplication-Type All-Polymer Photodetectors and Their Applications in Photoplethysmography Sensor. Acta Physico-Chimica Sinica, 2025, 41(1): 100007-0. doi: 10.3866/PKU.WHXB202311021
19. [19]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
20. [20]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010

Get Citation

PDF

XML

Metrics

PDF Downloads(1610)
Abstract views(3220)
HTML views(195)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return