Citation: Jie Li, Huida Qian, Deyang Pan, Wenjing Wang, Daliang Zhu, Zhongxue Fang. Efficient Synthesis of Anethaldehyde Induced by Visible Light[J]. University Chemistry, ;2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076 shu

Efficient Synthesis of Anethaldehyde Induced by Visible Light

School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, Jiangsu Province, China

Received Date: 19 October 2023
Revised Date: 11 December 2023

Anisaldehyde, also known as p-anisaldehyde, is widely used in the synthesis of pharmaceuticals and perfume formulation. However, the drawbacks of traditional methods for synthesizing anisaldehyde make it challenging to adapt them for undergraduate laboratory teaching. This experiment presents a novel approach to preparing anisaldehyde by mild and metal-free conditions, utilizing visible light-induced oxidation of p-anisyl alcohol. This not only offers a new method for alcohol oxidation and aldehyde preparation but also expands students’ knowledge in the fields of photochemistry and radical chemistry, which provides a support for cultivating new engineering talents with scientific research thinking and innovation capacity.
- Visible-light-induced,
- Oxidation of alcohol,
- Metal-free,
- Anisaldehyde
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
  Zhang, R.; Zhang, R.; Jian, R.; Zhang, L.; Zhang, M.; Xia, Y.; Luo, S. Nat. Commun. 2022, 13, 428.
9. [9]
  Mondal, A.; Lai, R.; Fedoseyenko, D.; Giri, N.; Begley, T. J. Am. Chem. Soc. 2023, 145(8), 4421.
10. [10]
  Koutani, M.; Hayashi, E.; Kamata, K.; Hara, M. J. Am. Chem. Soc. 2022, 144 (31), 14090.
11. [11]
  Li, Z.; Yan, Y.; Xu, S.; Zhou, H.; Xu, M.; Ma, L.; Shao, M.; Kong, X.; Wang, X.; Wang, B.; et al. Nat. Commun. 2022, 13, 147.
12. [12]
  Chan, A. Y.; Perry, I. B.; Bissonnette, N. B.; Buksh, B. F.; Edwards, G. A.; Frye, L. I.; Garry, O. L.; Lavagnino, M. N.; Li, B.; Liang, Y.; et al. Chem. Rev. 2022, 122 (2), 1485.
13. [13]
  Beil, S. B.; Chen, T.; Intermaggio, N. E.; MacMillan, D. W. C. Acc. Chem. Res. 2022, 55 (23), 3481.
14. [14]
15. [15]
  Yadav, V. R.; Prasad, S.; Sung, S. B.; Aggarwal, B. B. Int. Immunopharmacol. 2011, 11 (3), 295.
1. [1]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
2. [2]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
3. [3]
  Tongyan Yu , Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070
4. [4]
  Xiaofei Zhang , Shanhao Xu , Zhiyuan Wang , Long He , Tiangcheng Huang , Yongming Xu , Yucui Bian , Yike Li , Haijun Chen , Zhongjun Li . Surface doping of graphene into BiOCl for efficient photocatalytic amine coupling under visible light. Acta Physico-Chimica Sinica, 2026, 42(5): 100202-0. doi: 10.1016/j.actphy.2025.100202
5. [5]
  Junjian Wang , Qingquan Yu , Shunyao Liu , Yuke Chen , Xiaoyu Liu , Guodong Li , Xiaoyan Liu , Hong Liu , Weijia Zhou . Laser-Induced Carbonization of Hydroxyapatite Sandwich Paper for Inkless Printing. Acta Physico-Chimica Sinica, 2024, 40(4): 2304024-0. doi: 10.3866/PKU.WHXB202304024
6. [6]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
7. [7]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-0. doi: 10.3866/PKU.WHXB202408004
8. [8]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
9. [9]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
10. [10]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
11. [11]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
12. [12]
  Yanan Fan , Jingjing Huang . Interactive Electronic Courseware Facilitates the Development of Integrated Undergraduate-Graduate Instrumental Analysis Laboratory Courses: A Case Study of UV-Vis Spectroscopy Analysis Experiment. University Chemistry, 2025, 40(10): 282-287. doi: 10.12461/PKU.DXHX202411009
13. [13]
  Zehui JIA , Bin WEN , Shuting ZHANG , Zhengliang ZHAO , Hongfei HAN , Chuntao WANG , Caimei FAN . Mechanism of carbon quantum dots-modified BiOCl/diatomite composites for ciprofloxacin degradation under visible light irradiation. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 317-330. doi: 10.11862/CJIC.20250199
14. [14]
  Ruoxi RUN , Jikai ZHU , Lixia HAN , Zhiyin XIAO , Xiujuan JIANG , Jing JIN . Red light-induced CO-release from manganese carbonyl complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2575-2583. doi: 10.11862/CJIC.20250132
15. [15]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-0. doi: 10.3866/PKU.WHXB202402016
16. [16]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040
17. [17]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
18. [18]
  Xinwan Zhao , Yue Cao , Minjun Lei , Zhiliang Jin , Tsubaki Noritatsu . Constructing S-scheme heterojunctions by integrating covalent organic frameworks with transition metal sulfides for efficient noble-metal-free photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(12): 100152-0. doi: 10.1016/j.actphy.2025.100152
19. [19]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
20. [20]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(486)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142