Citation: Anna Tang, Yiling Shi, Jin Du, Deming Kong. Application of Hyphenated Technique in Element Speciation Analysis[J]. University Chemistry, ;2023, 38(9): 98-104. doi: 10.3866/PKU.DXHX202211088 shu

Application of Hyphenated Technique in Element Speciation Analysis

Tianjin Key Laboratory of Biosensing and Molecular Recognition, Research Center for Analytical Sciences, National Demonstration Center for Experimental Chemistry Education, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Anna Tang, tanganna@nankai.edu.cn
Received Date: 27 November 2022

This paper investigates the significance of element speciation analysis, the various hyphenated techniques used in element speciation analysis, and their application in real samples. This involves a variety of separation technologies, such as high-performance liquid chromatography, ion chromatography, size exclusion chromatography, gas chromatography, and capillary electrophoresis, as well as various detection methods, such as inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectrometry, atomic fluorescence spectrometry, and atomic absorption spectrometry. Based on this, we developed teaching experiments, combined theory with practice, and further strengthened students' understanding, mastery, and application of knowledge.
- Hyphenated technique,
- Speciation analysis,
- Teaching experiment
1. [1]
  Song, X. C.; Huang, X. J. Advances in Sample Preparation 2022, 2, 100019.
2. [2]
  Song, X. C.; Luo, Q.; Huang, X. J. Anal. Chim. Acta 2022, 1223, 340175.
3. [3]
  Chen, Y. C.; Jiang, S. J. J. Anal. At. Spectrom. 2021, 36, 938.
4. [4]
5. [5]
  Grotti, M.; Terol, A.; Todolí, J. L. Trac-Trend Anal. Chem. 2014, 61, 92.
6. [6]
7. [7]
  Nong, Q. Y.; Dong, H. Z.; Liu, Y. Q.; Liu, L. H.; He, B.; Huang, Y. S.; Jiang, J.; Luan, T. G.; Chen, B. W.; Hu, L. G. Chemosphere 2021, 263, 128110.
8. [8]
  Proch, J.; Niedzielski, P. Talanta 2021, 231, 122403.
9. [9]
  Ochsenkuhn-Petropoulou, M.; Michalke, B.; Kavouras, D.; Schramel, P. Anal. Chim. Acta 2003, 478, 219.
10. [10]
  Spanu, D.; Monticelli, D.; Binda, G.; Dossi, C.; Rampazzi, L.; Recchia, S. J. Hazard. Mater. 2021, 412, 125280.
11. [11]
  Iwai-Shimada, M.; Kobayashi, Y.; Isobe, T.; Nakayama, S. E.; Sekiyama, M.; Taniguchi, Y.; Yamazaki, S.; Michikawa, T.; Oda, M.; Mitsubuchi, H.; et al. Toxics 2021, 9, 82.
12. [12]
13. [13]
14. [14]
  Linhart, O.; Kolorosová-Mrázová, A.; Kratzer, J.; Hraníček, J.; Červený, V. Anal. Lett. 2019, 52, 613.
15. [15]
  Cossart, T.; Garcia-Calleja, J.; Worms, I. A. M.; Tessier, E.; Kavanagh, K.; Pedrero, Z.; Amouroux, D.; Slaveykova, V. I. Environ. Pollut. 2021, 288, 117771.
16. [16]
  Pinel-Raffaitin, P.; Rodriguez-Gonzalez, P.; Ponthieu, M.; Amouroux, D.; Le Hecho, I.; Mazeas, L.; Donard, O. F. X.; Potin-Gautier, M. J. Anal. At. Spectrom. 2007, 22, 258.
17. [17]
  Azemard, S.; Vassileva, E. Talanta 2021, 232,122492.
18. [18]
  Górecki, J. Measurement 2018, 117, 419.
19. [19]
  Zeng, Y.; Xu, K.; Hou, X.; Jiang, X. Microchem. J. 2014, 114, 16.
20. [20]
  Aguerre, S.; Pecheyran, C.; Lespes, G.; Krupp, E.; Donard, O. F. X.; Potin-Gautier, M. J. Anal. At. Spectrom. 2001, 16, 1429.
21. [21]
  Chamoun, J.; Hagège, A. Radiochim. Acta 2005, 93, 659.
22. [22]
  Shuai, P. Y.; Yang, X. J.; Qiu, Z. Q.; Wu, X. H.; Zhu, X.; Pokhrel, G. R.; Fu, Y. Y.; Ye, H. M.; Lin, W. X.; Yang, G. D. J. Sep. Sci. 2016, 39, 3239.
23. [23]
  Deng, B. Y.; Xiao, Y.; Xu, X. S.; Zhu, P. C.; Liang, S. J.; Mo, W. M. Talanta 2009, 79, 1265.
24. [24]
  Sanchez-Rodas, D.; Corns, W. T.; Chen, B.; Stockwell, P. B. J. Anal. At. Spectrom. 2010, 25, 933.
25. [25]
  Yan, X. P.; Yin, X. B.; Jiang, D. Q.; He, X. W. Anal. Chem. 2003, 75, 1726.
26. [26]
  Deng, B.; Li, X.; Zhu, P.; Xu, X.; Xu, Q.; Kang, Y. Electrophoresis 2008, 29, 1534.
27. [27]
28. [28]
29. [29]
  Li, F.; Wang, D. D.; Yan, X. P.; Su, R. G.; Lin, J. M. J. Chromatogr. A 2005, 1081, 232.
30. [30]
  Escudero, L. A.; Pacheco, P. H.; Gasquez, J. A. Food Chem. 2015, 169, 73.
31. [31]
  Braun, D.; Ezekiel, C. N.; Abia, W. A.; Wisgrill, L.; Degen, G. H.; Turner, P. C.; Marko, D.; Warth, B. Anal. Chem. 2018, 90, 14569.
1. [1]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
2. [2]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
3. [3]
  Chunyang Bao , Ruoxuan Miao , Yuhan Ding , Qingfu Ban , Yusheng Qin , Jie Liu , Zhirong Xin . The Comprehensive Experiment Design of Preparation of Depolymerizable Thermosetting Polymers. University Chemistry, 2025, 40(4): 59-65. doi: 10.12461/PKU.DXHX202405087
4. [4]
  Huijuan Liao , Yulin Xiao , Dong Xue , Mingyu Yang , Jianyang Dong . Synthesis of 1-Benzyl Isoquinoline via the Minisci Reaction. University Chemistry, 2025, 40(7): 294-299. doi: 10.12461/PKU.DXHX202409092
5. [5]
  Zhenjun Mao , Haorui Gu , Haiyan Che , Xufeng Lin . Exploration on Experiment Teaching of UHPLC-IC Based on Valve Switching Method. University Chemistry, 2024, 39(4): 81-86. doi: 10.3866/PKU.DXHX202311013
6. [6]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
7. [7]
  Siwei Hou , Yaxin Niu , Guanglu Zhang , Yanmei Yang , Xu Wang , Zhenzhen Chen . Application of Solid-Phase Microextraction and Mass Spectrometry in Environmental Detection. University Chemistry, 2026, 41(3): 297-306. doi: 10.12461/PKU.DXHX202504078
8. [8]
  Zijun Huang , Feng Wu , Shaofeng Pi , Saijin Huang , Zhengjun Fang . Knowledge Graph-based Development of AI Curriculum for Inorganic Chemistry Experiments and Exploration of New Teaching Paradigm. University Chemistry, 2025, 40(9): 228-237. doi: 10.12461/PKU.DXHX202504052
9. [9]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Application of Comparative Pedagogy in Instrumental Analysis Experiment Teaching. University Chemistry, 2024, 39(3): 266-273. doi: 10.3866/PKU.DXHX202309068
10. [10]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
11. [11]
  Liqiang Huang , Peng Lin . 数-图分析法解释仪器分析实验课程教学中的难点. University Chemistry, 2025, 40(6): 353-359. doi: 10.12461/PKU.DXHX202407074
12. [12]
  Yi Yang , Shuyong Zhang , Gongke Li , Yuzhi Wang , Qiue Cao , Yijun Li , Na Li , Bin Hu , Yan Su . Suggestions on Teaching Contents and Requirements of Analytical Chemistry Laboratory for Chemistry Majors of Higher Chemistry Education. University Chemistry, 2026, 41(3): 23-30. doi: 10.12461/PKU.DXHX202603011
13. [13]
  Yan Li , Fei Ding , Jielun Yan , Qingyang Zhou , Zhe Wang , Yifan Shi , Jing Wang , Anna Tang . Improving Instrumental Analytical Chemistry Laboratory Teaching: Developing a Bilingual Classroom to Cultivate Innovative Talents. University Chemistry, 2025, 40(7): 83-89. doi: 10.12461/PKU.DXHX202409059
14. [14]
  Zisheng Xiao , Siyi Liu , Binhong He , Yi Xiao , Qiong Xu , Zhili Lan , Rong Tan , Liang Tan , Dulin Yin . Construction and Practice of Instrumental Analysis Experimental Teaching Mode with Deep Integration of Ideological and Political Education. University Chemistry, 2025, 40(11): 150-159. doi: 10.12461/PKU.DXHX202412113
15. [15]
  Yan Li , Fei Ding , Jing Wang . Application of Self-Constructed Raman Spectrometer in Instrumental Analysis Experiment Teaching. University Chemistry, 2026, 41(3): 363-372. doi: 10.12461/PKU.DXHX202505047
16. [16]
  Qizhi Yao , Gu Jin , Pingping Zhu . Modular Analytical Chemistry Experimental Teaching Based on “Comprehensive + Exploratory” Experiments: “One Student, One Plan”, Individualized Experimental Teaching Method. University Chemistry, 2024, 39(3): 143-148. doi: 10.3866/PKU.DXHX202309071
17. [17]
  Linlin Chai , Abulizi Xiao kaiti . Discussion on the Teaching of Experimental Courses Organically Integrated with Ideological and Political Elements: A Case of Analytical Chemistry Experiment Teaching at Xinjiang University. University Chemistry, 2026, 41(3): 262-267. doi: 10.12461/PKU.DXHX202504083
18. [18]
  Zhaoyang Li , Haiyan Zhao , Yali Zhang , Yuan Zhang , Shiqiang Cui . Integration of Nobel Prize Achievements in Analytical Technology with College Instrumental Analysis Course. University Chemistry, 2025, 40(3): 269-276. doi: 10.12461/PKU.DXHX202405131
19. [19]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
20. [20]
  Sen Lin , Rong Jiang , Xuefeng Lu , Guohui Jiang , Kaining Ding , Jinshui Zhang , Xinchen Wang . Promoting the Integration of Science and Education through Digital Intelligence Technology: Data-Driven Development of Efficient Water Electrolysis Catalysts in Comprehensive Chemical Experiment Teaching. University Chemistry, 2026, 41(1): 188-203. doi: 10.12461/PKU.DXHX202505090

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1524)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142