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Citation: Zhiqiang Dong, Chanzi Ruan, Chunyan Zhang, Bo Yi, Xin Chen, Yechao Chen, Yinyun Lü, Zhenling Xu, Rui Pan, Yuhua Weng, Wenwei Zhang, Yanping Ren. Optimization Design and Preliminary Results of Synthesis of [Ni(Me₃en)(acac)]BPh₄ Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament[J]. University Chemistry, ;2023, 38(9): 313-321. doi: 10.3866/PKU.DXHX202210040 shu

Optimization Design and Preliminary Results of Synthesis of [Ni(Me₃en)(acac)]BPh₄ Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament

Zhiqiang Dong ¹ ,
Chanzi Ruan ¹ ,
Chunyan Zhang ¹ ,
Bo Yi ¹ ,
Xin Chen ¹ ,
Yechao Chen ¹ ,
Yinyun Lü ¹ ,
Zhenling Xu ¹ ,
Rui Pan ¹ ,
Yuhua Weng ¹ ,
Wenwei Zhang ^2,, ,
Yanping Ren ^1,,

1.
National Demonstration Center for Experimental Chemistry Education (Xiamen University), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China;
2.
National Demonstration Center for Experimental Chemistry Education (Nanjing University), College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Wenwei Zhang, Yanping Ren,
Received Date: 13 October 2022

This paper mainly introduces the way of optimizating synthesis process of the [Ni(Me₃en)(acac)]BPh₄ complex and the preliminary results of initial effort. On the basis of guiding students to understand the synthetic principle, conditions and process of [Ni(Me₃en)(acac)]BPh₄ complex, we take absorbing the free water on the solid surface of Ni(NO₃)₂·6H₂O as the starting point, the effect of water on the synthetic system was discussed. Combined with the experimental principle, synthetic process and conditions, we propose several different synthetic approaches, and explore and verify them through the experiment. Through the above optimization processes, students' problem awareness and ability to solve problems can be cultivated, and we lay the foundation for the experiment to face students with different levels, different teaching needs and different teaching purposes.
- Ni(II) complex,
- Optimization design of synthesis process,
- Preliminary implementation results,
- Solvent systems,
- Solid-phase synthesis
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Optimization Design and Preliminary Results of Synthesis of [Ni(Me3en)(acac)]BPh4 Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament

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通讯作者: 陈斌, bchen63@163.com

Optimization Design and Preliminary Results of Synthesis of [Ni(Me₃en)(acac)]BPh₄ Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament