Home

Citation: Zhiqiang Dong, Chanzi Ruan, Chunyan Zhang, Bo Yi, Xin Chen, Yechao Chen, Yinyun Lü, Zhenling Xu, Rui Pan, Yuhua Weng, Wenwei Zhang, Yanping Ren. Optimization Design and Preliminary Results of Synthesis of [Ni(Me₃en)(acac)]BPh₄ Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament[J]. University Chemistry, ;2023, 38(9): 313-321. doi: 10.3866/PKU.DXHX202210040 shu

Optimization Design and Preliminary Results of Synthesis of [Ni(Me₃en)(acac)]BPh₄ Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament

Zhiqiang Dong ¹ ,
Chanzi Ruan ¹ ,
Chunyan Zhang ¹ ,
Bo Yi ¹ ,
Xin Chen ¹ ,
Yechao Chen ¹ ,
Yinyun Lü ¹ ,
Zhenling Xu ¹ ,
Rui Pan ¹ ,
Yuhua Weng ¹ ,
Wenwei Zhang ^2,, ,
Yanping Ren ^1,,

1.
National Demonstration Center for Experimental Chemistry Education (Xiamen University), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China;
2.
National Demonstration Center for Experimental Chemistry Education (Nanjing University), College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Wenwei Zhang, Yanping Ren,
Received Date: 13 October 2022

This paper mainly introduces the way of optimizating synthesis process of the [Ni(Me₃en)(acac)]BPh₄ complex and the preliminary results of initial effort. On the basis of guiding students to understand the synthetic principle, conditions and process of [Ni(Me₃en)(acac)]BPh₄ complex, we take absorbing the free water on the solid surface of Ni(NO₃)₂·6H₂O as the starting point, the effect of water on the synthetic system was discussed. Combined with the experimental principle, synthetic process and conditions, we propose several different synthetic approaches, and explore and verify them through the experiment. Through the above optimization processes, students' problem awareness and ability to solve problems can be cultivated, and we lay the foundation for the experiment to face students with different levels, different teaching needs and different teaching purposes.
- Ni(II) complex,
- Optimization design of synthesis process,
- Preliminary implementation results,
- Solvent systems,
- Solid-phase synthesis
1. [1]
2. [2]
3. [3]
  Fukuda, Y.; Sone, K. J. Inorg. Nucl. Chem. 1972, 34, 2315.
4. [4]
5. [5]
6. [6]
1. [1]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
2. [2]
  Wan Li , Mei Shi , Yanping Ren , Faqiong Zhao , Min Hu , Xiuyun Wang , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Wenwei Zhang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on Heating and Heating Instruments (Part V): Solid-State Synthesis and High-Temperature Heating Using Muffle and Tube Furnaces. University Chemistry, 2026, 41(3): 182-190. doi: 10.12461/PKU.DXHX202507046
3. [3]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
4. [4]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
5. [5]
  Yinxia SUN , Liping LIU , Xue BAI , Yu SUN , Wanhong SUN , Zhepeng DENG , Jianghai CHEN , Jianjun WANG , Li XU , Shuzhen ZHANG . Synthesis and crystal structures of Co(Ⅱ)/Cu(Ⅱ) coordination polymers based on solvent and ligand concentration regulation strategy. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 340-354. doi: 10.11862/CJIC.20250226
6. [6]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
7. [7]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
8. [8]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
9. [9]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
10. [10]
  Kaimin WANG , Na HE , Shiyi LI , Xuling BAI , Weiqing SUN , Yanqing YE , Yulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178
11. [11]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
12. [12]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
13. [13]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
14. [14]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
15. [15]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
16. [16]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
17. [17]
  Cun WANG , Shaohan XU , Yuqian ZHANG , Yaoyao ZHANG , Tao GONG , Rong WEN , Yuhang LIAO , Yanrong REN . Terbium complex electrochemiluminescent emitters: Synthesis and application in the detection of epinephrine. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1351-1360. doi: 10.11862/CJIC.20240427
18. [18]
  Wenjuan SHI , Yuxuan LEI , Lei HOU , Yaoyu WANG . Synthesis, structure, and luminescence properties of trinucluear Cu(Ⅰ)-pyrazole complexes containing different substituent groups. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 543-550. doi: 10.11862/CJIC.20250270
19. [19]
  Jianqiang Zheng , Yongbin Huang , Wencan Ming , Yingju Liu . Intelligent Reaction Optimization: Synthesis of Acetylsalicylic Acid Driven by Deep Learning and Optimization Algorithms. University Chemistry, 2025, 40(9): 87-98. doi: 10.12461/PKU.DXHX202411062
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1948)
HTML views(368)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Optimization Design and Preliminary Results of Synthesis of [Ni(Me3en)(acac)]BPh4 Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament

Metrics

通讯作者: 陈斌, bchen63@163.com

Optimization Design and Preliminary Results of Synthesis of [Ni(Me₃en)(acac)]BPh₄ Complex: The Optimization and Preliminary Implementation of Synthesis Process for the Inorganic and Analytical Chemistry Experiment of the 10th National Undergraduate Chemistry Laboratory Tournament