Citation: Xiaohan Wang, Dongxiao Cao, Wei Li, Yan Chen, Anna Tang, Deming Kong. Synthesis and Application of Morphology Controllable Covalent Organic Frameworks[J]. University Chemistry, ;2023, 38(5): 110-118. doi: 10.3866/PKU.DXHX202206098 shu

Synthesis and Application of Morphology Controllable Covalent Organic Frameworks

Tianjin Key Laboratory of Biosensing and Molecular Recognition, Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Anna Tang, tanganna@nankai.edu.cn
Received Date: 29 June 2022

Covalent organic frameworks (COFs), a new type of crystalline porous materials, have attracted considerable attention in many fields such as separation, catalysis, drug release, and optoelectronics. The crystallinity and morphology of COFs determine their application. In this study, the synthetic methods and applications of COFs with different morphologies (spherical, thin film, rod, tubular, fibrous, belt, cage, and roll) are reviewed. Existing problems are also discussed and their potential solutions are proposed.
- Morphology controllable,
- Covalent organic frameworks,
- Synthesis,
- Application
1. [1]
  Cote, A. P.; Benin, A. I.; Ockwig, N. W.; O'Keeffe, M.; Matzger, A. J.; Yaghi, O. M. Science 2005, 310, 1166.
2. [2]
  Ma, W. D.; Zheng, Q.; He, Y. T.; Li, G. R.; Guo, W. J.; Lin, Z.; Zhang, L. J. Am. Chem. Soc. 2019, 141, 18271.
3. [3]
  Li, Y. X.; Zhang, H. N.; Chen, Y. T.; Huang, L.; Lin, Z.; Cai, Z. W. ACS Appl. Mater. Interfaces 2019, 11, 22492.
4. [4]
  Liang, H.; Xu, H. B.; Zhao, Y. T.; Zheng, J.; Zhao, H.; Li, G. L.; Li, C. P. Biosens. Bioelectron. 2019, 144, 111691.
5. [5]
  Li, W.; Wang, R.; Jiang, H. X.; Chen, Y.; Tang, A. N.; Kong, D. M. Talanta 2022, 236, 122829.
6. [6]
  Wang, K.; Wang, W.; Pan, S.; Fu, Y.; Dong, B.; Wang, H. Appl. Mater. Today 2020, 19, 100550.
7. [7]
  Li, M. M.; Qiao, S.; Zheng, Y. L.; Andaloussi, Y. H.; Li, X.; Zhang, Z. J.; Li, A.; Cheng, P.; Ma, S. Q.; Chen, Y. J. Am. Chem. Soc. 2020, 142, 6675.
8. [8]
  Yin, Z. J.; Xu, S. Q.; Zhan, T. G.; Qi, Q. Y.; Wu, Z. Q.; Zhao, X. Chem. Commun. 2017, 53, 7266.
9. [9]
  Li, W.; Jiang, H. X.; Cui, M. F.; Wang, R.; Tang, A. N.; Kong, D. M. J. Hazard. Mater. 2022, 432, 128705.
10. [10]
  Kandambeth, S.; Venkatesh, V.; Shinde1, D. B.; Kumari, S.; Halder, A.; Verma, S.; Banerjee, R. Nat. Commun. 2015, 6, 6786.
11. [11]
  Sasmal, H. S.; Halder, A.; Kunjattu, S.; Dey, K.; Nadol, A.; Ajithkumar, T. G.; Bedadur, P. R.; Banerjee, R. J. Am. Chem. Soc. 2019, 141, 20371.
12. [12]
  Shinde, D. B.; Cao, L.; Wonanke, A. D. D.; Li, X.; Kumar, S.; Liu, X. W.; Hedhili, M. N.; Emwas, A. H.; Addicoat, M.; Huang, K. W.; et al. Chem. Sci. 2020, 11, 5434.
13. [13]
  Wang, X. H.; Li, W.; Jiang, H. X.; Chen, Y.; Gao, R. Z.; Tang, A. N.; Kong, D. M. Microchim. Acta 2021, 188, 235.
14. [14]
  Hao, Q.; Li, Z. J.; Lu, C.; Sun, B.; Zhong, Y. W.; Wan, L. J.; Wang, D. J. Am. Chem. Soc. 2019, 141, 19831.
15. [15]
  Chen, D. D.; Huang, S.; Zhong, L.; Wang, S. J.; Xiao, M.; Han, D. M.; Meng, Y. Z. Adv. Funct. Mater. 2020, 30, 1907717.
16. [16]
  Pachfule, P.; Kandmabeth, S.; Mallick, A.; Banerjee, R. Chem. Commun. 2015, 51, 11717.
17. [17]
  Gole, B.; Stepanenko, V.; Rager, S.; Grune, M.; Medina, D. D.; Bein, T.; Wurthner, F.; Beuerle, F. Angew. Chem. Int. Ed. 2018, 57, 846.
18. [18]
  Rodriguez-San-Miguel, D.; Abrishamkar, A.; Navarro, J. A. R.; Rodriguez-Trujillo, R.; Amabilino, D. B.; Mas-Ballesté, R.; Zamora, F.; Puigmartí-Luis, J. Chem. Commun. 2016, 52, 9212.
19. [19]
  Huang, W.; Jiang, Y.; Li, X.; Li, X.; Wang, J.; Wu, Q.; Liu, X. ACS Appl. Mater. Interfaces 2013, 5, 8845.
20. [20]
  Wan, S.; Guo, J.; Kim, J.; Ihee, H.; Jiang, D. L. Angew. Chem. Int. Ed. 2008, 47, 8826.
21. [21]
  Zhang, F. Y.; Zhang, J. L.; Zhang, B. X.; Tan, X. N.; Shao, D.; Shi, J. B.; Tan, D. X.; Liu, L. F.; Feng, J. Q.; Han, B. X.; et al. ChemSusChem 2018, 11, 3576.
22. [22]
  Jennings, J.; Beija, M.; Richez, A. P.; Cooper, S. D.; Mignot, P. E.; Thurecht, K. J.; Jack, K. S.; Howdle, S. M. J. Am. Chem. Soc. 2012, 134, 4772.
23. [23]
  Li, H. Y.; Bredas, J. L. Chem. Mater. 2019, 31, 3265.
24. [24]
  Florian, B.; Bappaditya, G. Angew. Chem. Int. Ed. 2018, 57, 4850.
25. [25]
  Ma, J. X.; Li, J.; Chen, Y. F.; Ning, R.; Ao, Y. F.; Liu, J. M.; Sun, J. L.; Wang, D. X.; Wang, Q. Q. J. Am. Chem. Soc. 2019, 141, 3843.
26. [26]
  Unterlass, M. M. Angew. Chem. Int. Ed. 2018, 57, 2292.
27. [27]
  Chen, Y.; Li, W.; Wang, X. H.; Gao, R. Z.; Tang, A. N.; Kong, D. M. Mater. Chem. Front. 2021, 5, 1253.
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