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Citation: Yizhen Zhao, Haocheng Yang, Yukun Ye, Jiangong Ma, Xiaohang Qiu. 热致变色自旋转换材料的制备与表征[J]. University Chemistry, ;2022, 37(5): 210910. doi: 10.3866/PKU.DXHX202109100 shu

热致变色自旋转换材料的制备与表征

1.
College of Chemistry, Nankai University, Tianjin 300071, China;
2.
National Demonstration Center for Experimental Chemistry Education (Nankai University), Tianjing 300071, China

Corresponding author: Xiaohang Qiu, qiuxh@nankai.edu.cn
Received Date: 28 September 2021

设计包含Fe （II）自旋转换配合物的合成及热致变色性质研究，探究了温度、溶剂对配合物自旋状态的影响；进一步制备了具有一定加工性能的热致变色复合高分子材料，并通过多种手段加以表征。实验从验证基本原理到设计改性实用材料，涉及无机、分析、高分子、材料等多学科交叉，通过合成-表征-性质调控-应用的全流程实现对学生知识、技能、素养的全面训练。
- Thermochromism,
- Spin crossover,
- Coordination field,
- Hydrogen bond,
- Polymer film
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