Citation: Jie Zhang, Zequn Yin, Libo Sun, Yan Zhang, Yue Gao, Zhiting Xu, Wei Song. 聚苯胺负载纳米金催化剂的制备及其催化性能研究综合实验设计[J]. University Chemistry, ;2022, 37(3): 210503. doi: 10.3866/PKU.DXHX202105033 shu

聚苯胺负载纳米金催化剂的制备及其催化性能研究综合实验设计

College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, Shandong Province, China

Corresponding author: Libo Sun, sunlibo@ytu.edu.cn
Received Date: 12 May 2021

将科研课题“聚苯胺负载纳米金催化剂的制备及其催化性能研究”设计成应用化学专业综合实验，将科研课题的创新性和教学可行性有机结合，以推进创新型人才的培养。实验以苯胺单体（ANI）为原料，以过硫酸铵（APS）为氧化剂，制备聚苯胺（PANI）载体。采用金胶负载法、PANI原位还原法、ANI原位还原法三种载金方式分别制备PANI负载纳米金催化剂，并以NaBH₄存在条件下，对硝基酚（4-NP）还原制备对氨基酚反应（4-AP）为探针评价催化剂的催化性能。实验内容多学科交叉融合，涉及催化剂的制备、催化剂的结构表征、催化剂的活性评价等多种内容。通过本次实验，学生可以经历催化学科科学研究的全过程，掌握催化材料的制备方法，并熟练运用红外光谱（FT-IR）、紫外光谱（UV-Vis）、X射线衍射光谱（XRD）等大型设备对所制备催化材料进行分析，进而激发学生的学习兴趣，提高学生的科研素养。
- Comprehensive experiment,
- Nano gold catalyst,
- Polyaniline,
- Catalytic activities
1. [1]
  Haruta, M. Chin. J. Catal. 2016, 37 (9), 1441.
2. [2]
  Sun, L. B.; Sun, X.; Zheng, Y. H.; Lin, Q. Q.; Qi, C. X. Synth. Met. 2017, 224, 1.
3. [3]
  Sun, L. B.; Peng, S.; Jiang, L.; Zheng, Y. H.; Sun, X.; Su, H. J.; Qi, C. X. Colloid Polym. Sci. 2019, 297, 651.
4. [4]
  Sun, L. B.; Jiang, L.; Zhang, J.; Murayama, T.; Qi, C. X. Top. Catal. 2021, 64, 215.
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
  Wang, Y.; Shi, Y. C.; Xu, X. K.; Liu, F.; Yao, H. Y.; Zhai, G. Y.; Hao, J. C.; Li, G. Z. Colloid Surf. A-Physicochem. Eng. Asp. 2009, 345 (1-3), 71.
15. [15]
  Sun, L. B.; Sun, X.; Zheng, Y. H.; Lin, Q. Q.; Su, H. J.; Wang, Y. X.; Qi, C. X. J. Appl. Polym. Sci. 2017, 134 (19), 44812.
16. [16]
  Sun, L. B.; Jiang, L.; Peng, S.; Zheng, Y. H.; Sun, X.; Su, H. J.; Qi, C. X. Synth. Met. 2019, 248, 20.
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