Home

Citation: Helong Jiang, Can Liu, Lixu Lei. 少溶剂固态化学反应制备铵光卤石[J]. University Chemistry, ;2021, 36(12): 210200. doi: 10.3866/PKU.DXHX202102008 shu

少溶剂固态化学反应制备铵光卤石

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: Lixu Lei, Lixu.lei@seu.edu.cn
Received Date: 3 February 2021

固态化学反应的热力学分析指出，固态化学反应具有“一旦发生，就必完全”的特征；该特征不会因为少量溶剂的存在而消失。本文使用按1：1摩尔比混合的氯化铵和六水合氯化镁的固体进行反应，只使用刚刚淹没固体的水来促进二者之间的反应，结果发现，在室温下30 min左右，它们全部转化成了铵光卤石（NH₄Cl·MgCl₂·6H₂O，六水合氯化铵镁）。本实验有助于将少溶剂固态化学反应的概念引入学生的知识库，并籍此推进化学过程的绿色化。它还可以使学生学到如何冻结化学反应，使之适合于离位化学反应动力学研究的方法。
- Magnesium chloride,
- Ammonium chloride,
- Ammonium magnesium chloride hexahydrate,
- Solid state reaction,
- Green chemical process
1. [1]
  Kaupp, G. Top. Curr. Chem. 2005, 254, 95.
2. [2]
  Toda, F. Acc. Chem. Res. 1995, 28 (12), 480.
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
1. [1]
  Linlin Wu , Yonghua Zhou , Zhongbei Li , Liu Deng , Younian Liu , Limiao Chen , Jianhan Huang . Digital Education Promoting Applied Chemistry Comprehensive Experiments: A Case Study of Catalytic Oxidation of Hydrogen Chloride and Reaction Kinetics. University Chemistry, 2025, 40(9): 273-278. doi: 10.12461/PKU.DXHX202411018
2. [2]
  Jihua Deng , Xinshi Wu , Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046
3. [3]
  Zongsheng LI , Yichao WANG , Yujie WANG , Wenhao ZHU , Xiaoyao YIN , Wudan YANG , Songzhi ZHENG , Weihai SUN . Preparation of CsPbBr₃ perovskite solar cells via bottom interface modification with methylammonium chloride. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1805-1816. doi: 10.11862/CJIC.20250066
4. [4]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
5. [5]
  Jian Huang , Mingjue Zhang , Shangchu Ma , Jia Dong , Guanzi Wu , Aiming Wen , Zhuoliang Liu . Data-Driven Approach for the Determination of Chemical Reaction Rate Constant. University Chemistry, 2026, 41(1): 213-226. doi: 10.12461/PKU.DXHX202505110
6. [6]
  Wenbo Liao , Jie Chao , Shaona Zheng , Lili Zhao , Xiaobo Fu . Reform and Practice of Ideological and Political Education in Chemical Reaction Engineering Courses. University Chemistry, 2026, 41(3): 233-241. doi: 10.12461/PKU.DXHX202504019
7. [7]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
8. [8]
  Jingxuan Zhang , Weihao Jiang , Siyuan Zhang , Hongye Tian , Ziye Huang , Lin Huang , Qikun Wu , Jing Yang , Yibin Jiang , Cheng Wang . Automation and AI-Assisted Investigation of the Chemical Reactivity of Sulfosalicylic Acid. University Chemistry, 2026, 41(1): 332-345. doi: 10.12461/PKU.DXHX202505108
9. [9]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
10. [10]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
11. [11]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
12. [12]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
13. [13]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
14. [14]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . Accelerated Interfacial Electron Transfer in Perovskite Solar Cell by Ammonium Hexachlorostannate Modification and fs-TAS Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-0. doi: 10.3866/PKU.WHXB202402006
15. [15]
  Qingtao Niu , Xinyao Xu , Weiyue Yu , Shuxiang Meng , Zhiguo Lv , Manman Jin . Exploration and Practice of Science-Education Integration in Chemical Engineering Thermodynamics Teaching for Chemical Engineering Majors: A Case of Chemical Engineering Physical Property Data Estimation and Chemical Reaction Equilibrium. University Chemistry, 2025, 40(10): 1-9. doi: 10.12461/PKU.DXHX202412029
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Jianmin Hao , Ruifeng Wu , Ying Wang , Yijia Bai , Xuechuan Gao , Yuying Du . Reform and Practice of Physical Chemistry Course Based on Enhanced Process Assessment and Evaluation. University Chemistry, 2024, 39(8): 78-83. doi: 10.3866/PKU.DXHX202311103
18. [18]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
19. [19]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
20. [20]
  Zhican Lu , Junyu Li , Zijun Huang , Ziyi Zeng , Chi Huang , Chuqing Gong , Yalan Zhong . Digital Experimental Design of Decomposition of Ammonium Perchlorate Catalyzed by MOFs. University Chemistry, 2026, 41(1): 133-143. doi: 10.12461/PKU.DXHX202506017

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1651)
HTML views(264)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return