Citation: Xuechun Li,  Fang Sun. Introduction and Progress of Free Radical Photoinitiators[J]. University Chemistry, ;2021, 36(6): 200707. doi: 10.3866/PKU.DXHX202007078 shu

Introduction and Progress of Free Radical Photoinitiators

  • With the improvement of environmental protection consciousness, the photopolymerization technology has greatly developed over the past ten years due to its high efficiency and environmental protection, and become one of the most advanced technologies. In the present paper, the kinds and related initiating mechanisms of photoinitiators as the key component in photopolymerization system were discussed, and furthermore the progress of photoinitiators for free radical photopolymerization in the recent years was reviewed.
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    1. [1]

      Pan, H. Y.; Chen, S. Q.; Jin, M.; Malval, J.; Wan, D. C.; Morlet-Savary, F. Polym. Chem. 2019, 10 (13), 1599.

    2. [2]

      Ma, X. Y.; Cao, D.; Hu, X. T.; Nie, J.; Wang, T. Prog. Org. Coat. 2020, 144, 105651.

    3. [3]

      Encinas, M. V.; Lissi, E. J. Polym. Sci. 1984, 22, 2469.

    4. [4]

      Ikemura, K.; Ichizawa, K.; Yoshida M.; Ito, S.; Endo, T. Dent. Mater. J. 2008, 27 (6), 765.

    5. [5]

      Dietlin, C.; Trinh, T. T.; Schweizer, S.; Graff, B.; Morlet-Savary, F.; Noirot, P.; Lalevée, J. Macromolecules 2019, 52 (20), 7886.

    6. [6]

      Liu, T. Y.; Wang, T. T.; Xie, C. B.; Tian, X. J.; Song, L.; Liu, L.; Wang, Z. W.; Yu, Q. Prog. Org. Coat. 2020, 142, 105603.

    7. [7]

      Esen, D. S.; Arsu, N.; Da, S. J. P.; Jockusch, S.; Turro, N. J. J. Polym. Sci. Pol. Chem. 2013, 51 (8), 1865.

    8. [8]

    9. [9]

      Lewis, F. D.; Lauterbach, R. T.; Heine, H.; Hartmann, W.; Rudolph, H. J. Am. Chem. Soc. 1975, 97 (6), 1519.

    10. [10]

      Xiao, P.; Zhang, J.; Dumur, F.; Tehfe, M. A.; Morlet-Savary, F.; Graff, B.; Gigmes, D.; Fouassier, J. P.; Lalevée, J. Prog. Polym. Sci. 2015, 41, 32.

    11. [11]

    12. [12]

      Liu, S.; Brunel, D.; Sun, K.; Xu, Y. Y.; Morlet-Savary, F.; Graff, B.; Xiao, P.; Dumur, F.; Lalevée, J. Polym. Chem. 2020, 11 (21), 3551.

    13. [13]

      Dadashi-Silab, S.; Bildirir, H.; Dawson, R.; Thomas, A.; Yagci, Y. Macromolecules 2014, 47 (14), 4607.

    14. [14]

      Zhang, J.; Lalevée, J.; Hill, N. S.; Kiehl, J.; Zhu, D.; Cox, N.; Langley, J.; Stenzel, M. H.; Coote, M. L.; Xiao, P. Macromol. Rapid Commun. 2020, 2000166.

    15. [15]

      Zhao, X.; Huang, W.; Song, D.; Lin, R.; Huang, H.; Huang, J.; Wu, B.; Huang, Y.; Ye, G. J. Mol. Model. 2020, 26 (3), 56.

    16. [16]

      Dadashi-Silab, S.; Aydogan, C.; Yagci, Y. Polym. Chem. 2015, 6 (37), 6595.

    17. [17]

    18. [18]

      Li, J.; Li, W.; Gao, X.; Liu, L.; Shen, M.; Chen, H.; Zhu, M.; Zeng, L.; Zeng, E. Y. Environ. Int. 2020, 136, 105462.

    19. [19]

      Liu, R.; Mabury, S. A. Environ. Sci. Technol. Lett. 2019, 6 (12), 702.

    20. [20]

      Bonardi, A. H.; Dumur, F.; Grant, T. M.; Noirbent, G.; Gigmes, D.; Lessard, B. H.; Fouassier, J. P.; Lalevée, J. Macromolecules 2018, 51 (4), 1314.

    21. [21]

      Clark, E. A.; Alexander, M. R.; Irvine, D. J.; Roberts, C. J.; Wallace, M. J.; Sharpe, S.; Yoo, J.; Hague, R. J. M; Tuck, C. J.; Wildman, R. D.Int. J. Pharm. 2017, 529 (1-2), 523.

    22. [22]

      Shih, H.; Lin, C. C. Macromol. Rapid Commun. 2013, 34 (3), 269.

    23. [23]

      Tomal, W.; Ortyl, J. Polymers 2020, 12 (5), 1073.

    24. [24]

      Tehfe, M. A.; Dumur, F.; Graff, B.; Morlet-Savary, F.; Gigmes, D.; Fouassier, J. P.; Lalevée, J. Polym. Chem. 2013, 4 (12), 3866.

    25. [25]

      Al, M. A.; Dumur, F.; Garra, P.; Toufaily, J.; Hamieh, T.; Graff, B.; Gigmes, D.; Fouassier, J. P.; Lalevée, J. Macromolecules 2017, 50 (7), 2747.

    26. [26]

      Li, K. B.; Qu, W. B.; Shen, Q. X.; Zhang, S. Q.; Shi, W.; Dong, L.; Han, D. M. Dyes. Pigments 2020, 173, 107918.

    27. [27]

      Zang, S.; Kong, X.; Cui, J.; Su, S.; Shu, W.; Jing, J.; Zhang, X. J. Mater. Chem. B 2020, 8 (13), 2660.

    28. [28]

      Li, C.; Wang, J.; Lu, X.; Ge, H.; Jin, X.; Guan, Q.; Su, Y.; Pan, R.; Li, P.; Cai, W.; et al. Biomaterials 2020, 255, 120071.

    29. [29]

      Bonardi, A. H.; Zahouily, S.; Dietlin, C.; Graff, B.; Morlet-Savary, F.; Ibrahim-Ouali, M.; Gigmes, D.; Hoffmann, N.; Dumur, F.; Lalevée, J. Catalysts 2019, 9 (8), 637.

    30. [30]

      Zhang, J.; Zivic, N.; Dumur, F.; Xiao, P.; Graff, B.; Fouassier, J. P.; Gigmes, D.; Lalevée, J. ChemPhotoChem 2018, 2 (6), 481.

    31. [31]

      Yang, J. J.; Xu, C.; Xiong, Y.; Wang, X. L.; Xie, Y. J.; Li, Z.; Tang, H. D. Macromol. Chem. Phys. 2018, 219 (24), 1800256.

    32. [32]

      Yu, J.; Gao, Y.; Jiang, S.; Sun, F. Macromolecules 2019, 52 (4), 1707.

    33. [33]

      Breloy, L.; Losantos, R.; Sampedro, D.; Marazzi, M.; Malval, J. P.; Heo, Y.; Akimoto, J.; Ito, Y.; Brezová, V.; Versace, D. L. Polym. Chem. 2020, 11 (26), 4297.

    34. [34]

      Li, X. Y.; Shi, J.; Wu, K.; Luo, F. B.; Zhang, S. H.; Guan, X. X.; Lu, M. G. J. Photochem. Photobiol. A 2017, 333, 18.

    35. [35]

      Liu, Y.; Huang, X.; Han, K. C.; Dai, Y. H.; Zhang, X. Q.; Zhao, Y. X. ACS Sustainable Chem. Eng. 2019, 7 (4), 4004.

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