Citation: Yihan Tang, Jiawei Xu, Jiaxin Wang, Yuru Wang, Bing Xue, Zhihui Zhang. 第33届江苏省化学竞赛选拔赛有机试题解析[J]. University Chemistry, ;2021, 36(4): 200504. doi: 10.3866/PKU.DXHX202005042 shu

第33届江苏省化学竞赛选拔赛有机试题解析

Yihan Tang ¹ ,
Jiawei Xu ^2,3 ,
Jiaxin Wang ² ,
Yuru Wang ¹ ,
Bing Xue ¹ ,
Zhihui Zhang ^1,,

1.
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, China;
2.
School of Teacher Education, Nanjing Normal University, Nanjing 210023, China;
3.
Jiangsu Key Laboratory of Numerical Simulation of Large Scale Complex System, Nanjing 210023, China

Corresponding author: Zhihui Zhang, zhangzh@cczu.edu.cn
Received Date: 14 May 2020

详尽讨论了第33届中国化学奥林匹克竞赛（江苏赛区）夏令营暨选拔赛考试有机化学部分试题，并进行了多方面的拓展。同时采用计算化学方法辅助教学，供指导老师和参赛选手进行参考。
- Chemistry Olympiad Competition,
- Question analyses,
- Organic chemistry,
- Computational chemistry,
- Knowledge extension
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
  Zhao, J. X.; Méndez-Sánchez, D.; Ward, J. M.;Hailes, H. C. J. Org. Chem. 2019, 84(12), 7702.
6. [6]
  iBonD 2.0.[2020-06-11]. http://ibond.nankai.edu.cn
7. [7]
  Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.;Nakatsuji, H.; et al. Gaussian 16, Revision C.01; Gaussian, Inc.:Wallingford CT, USA, 2016.
8. [8]
  Lu, T.; Chen, F. W. J. Comput. Chem. 2012, 33 (5), 580.
9. [9]
  Humphrey, W.; Dalke, A.; Schulten, K. J. Mol. Graph. 1996, 14 (1), 33.
10. [10]
  Li, J. J. Name Reactions:A Collection of Detailed Mechanisms and Synthetic Applications. 5th ed.; Springer:Cham, Switzerland, 2014; pp. 480, 56, 593.
11. [11]
  , 53, 669, 498, 117, 762.
12. [12]
  Malin, L.; Johan, U.; Hans, E.; Susanne, W.; Johan, B.; Marianne, S.; Martin, A. H.; Luna, P. G.; Annika, W. E.; Johan, M.; et al. J. Med. Chem. 2019, 62 (9), 4325.
13. [13]
  Edward, O.; Zhu, X. Y.; Etukala, J. R.; Bricker, B. A.; Ablordeppey S. Y. Bioorgan. Med. Chem. 2016, 24(55), 5730.
14. [14]
  Teodozyj, K.; David, E. G.; Pramila, B.; Anwer, B.; Richard, A. C.; Andrew, O. S.; Jennifer, B. B.; Richard, R. H.; Keren, I. H.; Peter, E. M.; et al.J. Med. Chem. 2000, 43(17), 3322.
15. [15]
  Kerns, J. K.; Yan, H. X.; Callahan, J. F.; Heightman, T. D.; Boehm, J. C.; Woodlrod, A. J.-A. Aryl-and heteroarylalkanoic acid derivatives as NRF2 regulators and their preparation. Int. Appl. WO2016203401A1, 2016.
16. [16]
17. [17]
  Reed, A. E.; Weinstock, R. B.; Weinhold, F. J. Chem. Phys. 1985, 83 (2), 735.
18. [18]
  Lu, T.; Chen, F. W. J. Theor. Comput. Chem. 2012, 11 (1), 163.
19. [19]
  Eric, R. P.; Donald, J. H. J. Am. Chem. Soc. 1980, 102(8), 2763.
20. [20]
21. [21]
  Bentiss, F.; Lagrenee, M. J. Heterocyclic Chem. 1999, 36(4),1029.
22. [22]
  Jakopin, Z.; Dolenc, M. S. Curr. Org. Chem. 2008, 12(10), 850.
1. [1]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
2. [2]
  Gang Liu , Yongqiang Zhang , Xiaomiao Li , Qingshuang Li , Jichao Sun , Zhenghu Xu , Xiaoyan Li . Analysis of Organic Chemistry Experiment Questions in the 13th National Undergraduate Chemistry Experiment Competition Finals. University Chemistry, 2025, 40(11): 427-434. doi: 10.12461/PKU.DXHX202412125
3. [3]
  Zhilei Yin , Xinyu Song , Xuan Sun , Zhao Jin , Jin Zhang , Xuemei Ma , Bin Ge , Qisheng Song . Analysis of Inorganic and Analytical Chemistry Experiment in the 13th National Undergraduate Chemistry Experiment Competition Finals. University Chemistry, 2025, 40(11): 416-420. doi: 10.12461/PKU.DXHX202412138
4. [4]
  Meng Lin , Qisheng Song , Zhilei Yin , Bin Zhang , Baoxiang Zhao , Zhenghu Xu . Analysis of the Finals and Theoretical Examination Questions from the 13th National Chemistry Experiment Competition for College Students. University Chemistry, 2025, 40(11): 421-426. doi: 10.12461/PKU.DXHX202412126
5. [5]
  Jiantuo Chen , Fanpeng Shang . Analysis and Tracing of Question 1 from the 38th China Chemistry Olympiad (Preliminary). University Chemistry, 2025, 40(10): 303-308. doi: 10.12461/PKU.DXHX202411052
6. [6]
  Jian He , Dinglin Zhang , Liping Wu , Ying Bao , Xiaochao Yang . 知识网络构建策略在有机化学教学中的应用及效果分析. University Chemistry, 2025, 40(8): 66-71. doi: 10.12461/PKU.DXHX202410092
7. [7]
  Danwei Zhang . Development and Implementation of the Organic Chemistry Smart Curriculum: Taking the Development of Tröger Base Knowledge Platform as an Example. University Chemistry, 2025, 40(12): 168-173. doi: 10.12461/PKU.DXHX202509096
8. [8]
  Xiaoli Li , Zhongyi Li , Yanbing Wang . Exploration and Practice of Blended Learning in Organic Chemistry Based on Advanced and Basic Knowledge Points: A Case Study of the Animal Medicine Major. University Chemistry, 2026, 41(2): 131-139. doi: 10.12461/PKU.DXHX202501013
9. [9]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
10. [10]
  Fuxian Wan , Ying Li , Yuanhong Zhang , Shuhua Zhu , Jing Xu , Yanfang Wang , Lili Zhang . Exploration and Practice of Teaching in Agricultural Characteristic Organic Chemistry Course. University Chemistry, 2024, 39(2): 298-306. doi: 10.3866/PKU.DXHX202308041
11. [11]
  Zhichang Xiao , Xiaohui Li , Ling Zhang , Huimin Liu . Exploration of Ideological and Political Construction in University Foundation Course of Organic Chemistry. University Chemistry, 2024, 39(2): 314-320. doi: 10.3866/PKU.DXHX202308058
12. [12]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
13. [13]
  Shuixing Dai , Jilei Jiang , Yuxiao Wang , Jinqi Hu , Minghua Huang . Application of Knoevenagel Reaction in Organic Chemistry Teaching. University Chemistry, 2025, 40(5): 334-341. doi: 10.12461/PKU.DXHX202405208
14. [14]
  Zhenxing Liu , Jiaen Hu , Zishi Cheng , Xinqi Hao . 基础有机化学教学中烯烃的氧化反应. University Chemistry, 2025, 40(6): 139-144. doi: 10.12461/PKU.DXHX202408107
15. [15]
  Linlin Wang , Yanqin Chen , Feng Li , Ruikang Tan . Practical Exploration of Graded Teaching in the Public Organic Chemistry Course for Agricultural Science Students. University Chemistry, 2025, 40(7): 48-54. doi: 10.12461/PKU.DXHX202409054
16. [16]
  Qi Lin , Jianhua Liu , Liyun Yao , Xiuyan Yang , Weina He , Ruolin Yang . Exploring the Application of Superstar AI Teaching Assistant in Medical Organic Chemistry Courses. University Chemistry, 2025, 40(9): 142-147. doi: 10.12461/PKU.DXHX202502035
17. [17]
  Di Xu , Li Dai , Wenzhi Yao , Li Wang , Fang Zhang , Xin Gao . Exploration and Application of Smart Teaching in Organic Chemistry. University Chemistry, 2025, 40(9): 189-195. doi: 10.12461/PKU.DXHX202412072
18. [18]
  Yuwei Song , Wan He , Kaiyue Jiang , Mengzhao Xi , Xinyue Wang , Jie Li , Yan Zhang . Learning and Memorizing Common Named Reactions in College Organic Chemistry. University Chemistry, 2026, 41(2): 400-410. doi: 10.12461/PKU.DXHX202501004
19. [19]
  Hanni Zhou , Juanjuan Lu , Xinrui Zhao , Huilin Li , Junlong Zhao . Oil-Splashed Chili: A Symphony of Traditional Cuisine and Organic Chemistry. University Chemistry, 2026, 41(3): 357-362. doi: 10.12461/PKU.DXHX202504010
20. [20]
  Jia Zhou . Design and Practice of a Comprehensive Computational Chemistry Experiment Based on High-Throughput Computation and Machine Learning. University Chemistry, 2025, 40(9): 69-75. doi: 10.12461/PKU.DXHX202411067

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(746)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142