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Citation: Zhanhui Yang, Yang Chen. 端炔的硼化-迁移加成-氧化和硼化-氧化[J]. University Chemistry, ;2021, 36(4): 200502. doi: 10.3866/PKU.DXHX202005028 shu

端炔的硼化-迁移加成-氧化和硼化-氧化

Zhanhui Yang ^, ,
Yang Chen

Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Zhanhui Yang, zhyang@mail.buct.edu.cn
Received Date: 11 May 2020

端炔的硼氢化-氧化是基础有机化学授课的重要内容。本文在此基础上，介绍端炔的硼化-迁移加成-氧化和硼化-氧化。前一类反应可将端炔转化为醛，后两类则转化为酮、羧酸、酯和酰胺。本文所涉及内容与基础有机化学知识密切结合，又有一定程度的拔高。教师同时讲授三类反应，可丰富学生的知识积累，提高学生的认知能力。
- 1-Alkyne,
- Hydroboration,
- Boration,
- Migratory addition,
- Oxidation
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