Citation: Wenguang Zhao, Jie Zhu, Jingxin Shi, Xianxiang Liu. 生物质能源化学品乙酰丙酸酯[J]. University Chemistry, ;2021, 36(4): 200404. doi: 10.3866/PKU.DXHX202004043 shu

生物质能源化学品乙酰丙酸酯

College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China

Corresponding author: Xianxiang Liu, lxx@hunnu.edu.cn
Received Date: 10 April 2020

生物质能源是新兴的可再生能源，是仅次于煤、石油、天然气的第四大能源。乙酰丙酸酯是从生物质资源中获得的高附加值产物，是一类重要化工中间体与新能源化学品，其应用领域十分广泛，具有潜在的商业价值。本文介绍了乙酰丙酸酯的理化性质与用途，以生物质资源为原料制备乙酰丙酸酯的三种合成方法及其反应机理。最后分析了乙酰丙酸酯目前生产与应用的不足，并展望了乙酰丙酸酯未来开发和利用的发展趋势。
- Biomass,
- Energy chemistry,
- Alkyl levulinates,
- Catalytic conversion
1. [1]
  Gaurav, N.; Sivasankari, S.; Kiran, G. S.; Ninawe, A.; Selvin, J. Sustain. Energy. Rev. 2017, 73, 205.
2. [2]
  Mika, L. T.; Cséfalvay, E. Á. Németh. Chem. Rev. 2018, 118, 505.
3. [3]
  Chatterjee, C.; Pong, F.; Sen, A. Green Chem. 2015, 17, 40.
4. [4]
  Cara, P. D.; Ciriminna, R.; Shiju, N. R.; Rothenberg, G.; Pagliaro, M. ChemSusChem 2014, 7, 835.
5. [5]
  Unlu, D.; Boz, N.; Ilgen, O.; Hilmioglu, N. Open Chem. 2018, 16, 647.
6. [6]
  Zhou, H. C.; Song, J. L.; Fan, H. L.; Zhang, B. B.; Yang, Y. Y.; Hu, J. Y.; Zhu, Q. G.; Han, B. X. Green Chem. 2014, 16, 3870.
7. [7]
  Shrivastav, G.; Khan, T. S.; Agarwal, M.; Haider, M. A. ACS Sustain. Chem. Eng. 2017, 5, 7118.
8. [8]
  Mukherjee, A.; Dumont, M. J.; Raghavan, V. Biomass Bioenergy 2015, 72, 143.
9. [9]
  Deemolis, A.; Essayem,N.; Rataboul, F. ACS Sustain. Chem. Eng. 2014, 2, 1338.
10. [10]
  Lomba, L.; Giner, B.; Bandres, I.; Lafuente, C.; Pino, M. R. Green Chem. 2011, 13, 2062.
11. [11]
  Badgujar, K. C.; Badgujar, V. C.; Bhanage, B. M. Fuel Process. Technol. 2020, 197, 106213
12. [12]
  Morawala, D. H.; Dalai, A. K.; Maheria, K. C. Catal. Lett. 2019, 150, 1049.
13. [13]
  Chermahini, A. N.; Nazeri, M. Fuel Process. Technol. 2017, 167, 442.
14. [14]
  Gao, J.; Kong, W.; Zhou, L.; He, Y.; Ma, L.; Wang, Y.; Yin, L. Y.; Jiang, Y. J. Chem. Eng. J. 2017, 309, 70.
15. [15]
  Iborra, M.; Tejero, J.; Fité, C.; Ramirez, E.; Cunill, F. J. Ind. Eng. Chem. 2019, 78, 222.
16. [16]
  Tian, Y.; Zhang, R. Q.; Zhao, W. G.; Wen S.; Xiang Y.P.; Liu X. X. Catal. Lett. 2020, 150. doi:10.1007/s10562-020-03253-5
17. [17]
  Zhou, S. L.; Jiang, D. B.; Liu, X. X.; Chen, Y. P.; Yin, D. L. RSC Adv. 2018, 8, 3657.
18. [18]
  Peng, L. C.; Gao, X. Y.; Chen, K. L. Fuel 2015, 160, 123.
19. [19]
  Huang, Y. B.; Yang, T.; Zhou, M. C.; Pan, H.; Fu, Y. Green Chem. 2016, 18, 1516.
20. [20]
  Enumula, S. S.; Koppadi, K. S.; Gurram, V. R. B.; Burri, D. R.; Kamaraju, S. R. R. Sustain. Energy Fuels 2017, 1, 644.
21. [21]
  Tiwari, M. S.; Gawade, A. B.; Yadav,G. D. Green Chem. 2017, 19, 963.
22. [22]
  Ren, D.; Fu, J.; Li, L.; Liu, Y. J.; Jin, F. M.; Huo, Z. B. RSC Adv. 2016, 6, 22174.
23. [23]
  Maldonado, G. M. G.; Assary, R. S.; Dumesic, J. A.; Curtiss, L. A. Energy Environ. Sci. 2012, 5, 8990.
24. [24]
  Zhang, Z. H.; Dong, K.; Zhao, Z. B. ChemSusChem 2011, 4, 112.
25. [25]
  Huang, Y. B.; Yang, T.; Lin, Y. T.; Zhu, Y. Z.; Li, L. C.; Pan, H. Green Chem. 2018, 20, 1323.
26. [26]
  Zhou, L. P.; Zou, H. J.; Nan, J. X.; Wu, L.; Yang, X. M.; Su, Y. L.; Lu, T. L.; Xu, J. Catal. Commun. 2014, 50, 13.
27. [27]
  Chen, X. L.; Zhang, X. Y.; Hou, T.; Han, L. J.; Xiao, W. H. J. Energy Chem. 2018, 27, 552.
28. [28]
  Hu, X.; Li, C. Z. Green Chem. 2011, 13, 1676.
29. [29]
  Ding, D. Q.; Xi, J. X.; Wang, J. J.; Liu, X. H.; Lu, G. Z.; Wang, Y. Q. Green Chem. 2015, 17, 4037.
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