Home

Citation: HUANG Kevin, WANG Hefang. Explanation of Spin Coupling Splitting Phenomenon in ¹H-NMR Spectra via Quantum Mechanics[J]. University Chemistry, ;2018, 33(12): 83-88. doi: 10.3866/PKU.DXHX201804021 shu

Explanation of Spin Coupling Splitting Phenomenon in ¹H-NMR Spectra via Quantum Mechanics

HUANG Kevin ,
WANG Hefang

Tianjin Key Laboratory of Biosensing and Molecular Recognition, Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 16 April 2018

Hydrogen nuclear magnetic resonance spectroscopy (¹H-NMR) is an important content in the university course of instrumental analysis and organic structure analysis. The splitting law of spin coupling between hydrogen nuclei is the focus of teaching and learning. Most textbooks explain that the cause of spin coupling splitting is due to the local magnetic field produced by the different spin orientation of other adjacent nuclei (nuclei magnetic dipole-dipole interaction, direct nuclear spin coupling), and a few monograph on Nuclear Magnetic Resonance refers to electron spin polarization mediated nuclear spin coupling (indirect nuclear spin coupling). Here we introduce quantum mechanics for explanation of the splitting law of spin coupling between hydrogen nuclei.
- ¹H-NMR,
- Spin coupling,
- Spin splitting,
- Quantum mechanics
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
1. [1]
  Chenxu Gong , Chunfa Xu , Hong Yan , Yuanming Li , Yaofeng Yuan , Yu-wu Zhong , Keyin Ye . 核磁共振碳谱中¹⁹F-¹³C自旋耦合效应及实例分析. University Chemistry, 2026, 41(9): 457-464. doi: 10.12461/PKU.DXHX202509072
2. [2]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
3. [3]
  Peifeng Su , Xin Lu . Development of Undergraduate Quantum Mechanics Module in Chemistry Department under the “Double First Class” Initiative. University Chemistry, 2024, 39(8): 99-103. doi: 10.3866/PKU.DXHX202401087
4. [4]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
5. [5]
  Zelin Wang , Gang Liu , Mengran Wang , Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . Application of Instrumental Analysis in the Detection of Organic Components in Liquor. University Chemistry, 2025, 40(11): 318-326. doi: 10.12461/PKU.DXHX202502077
6. [6]
  Weizhe Liu , Minghui Shi , Ruiqi Zhu , Bin Pan , Guofu Huang . 抗癌药物艾乐替尼的生物电子等排体的合成. University Chemistry, 2026, 41(5): 210-221. doi: 10.12461/PKU.DXHX202510066
7. [7]
  Xinhe Wu , Chang Cheng . Chiral COF-based S-scheme heterojunction for spin-polarized photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2026, 42(9): 100303-0. doi: 10.1016/j.actphy.2026.100303
8. [8]
  Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
9. [9]
  Huiduan Li , Zenghua Li , Hongrui Wang . 融合BOPPPS模型与学习通平台的结构化学教学模式探索与实践——以“量子力学基础”为例. University Chemistry, 2026, 41(9): 421-432. doi: 10.12461/PKU.DXHX202509008
10. [10]
  Wei Ren , Jinhe Li , Chengzhang Zhu , Weikang Wang , Qinqin Liu . Tailored spin states: a transformative paradigm for sustainable catalysis. Acta Physico-Chimica Sinica, 2026, 42(4): 100178-0. doi: 10.1016/j.actphy.2025.100178
11. [11]
  Jinkang Jin , Yidian Sheng , Ping Lu , Zhan Lu . Introducing a Website for Learning Nuclear Magnetic Resonance (NMR) Spectrum Analysis. University Chemistry, 2024, 39(11): 388-396. doi: 10.12461/PKU.DXHX202403054
12. [12]
  Haiyang Jin , Yonghai Hui , Yongfei Zhang , Lijun Gao , Yun Wang . Application and Exploration of Nuclear Magnetic Resonance Spectrometer in Undergraduate Basic Laboratory Teaching. University Chemistry, 2025, 40(3): 245-250. doi: 10.12461/PKU.DXHX202406022
13. [13]
  Haolin Zhan , Qiyuan Fang , Jiawei Liu , Xiaoqi Shi , Xinyu Chen , Yuqing Huang , Zhong Chen . Noise Reduction of Nuclear Magnetic Resonance Spectroscopy Using Lightweight Deep Neural Network. Acta Physico-Chimica Sinica, 2025, 41(2): 100017-0. doi: 10.3866/PKU.WHXB202310045
14. [14]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
15. [15]
  Jiageng Li , Putrama . 数值积分耦合非线性最小二乘法一步确定反应动力学参数. University Chemistry, 2025, 40(6): 364-370. doi: 10.12461/PKU.DXHX202407098
16. [16]
  Hao Ren , Wen Zhao , Fangna Dai , Wenyue Guo . Finite Difference Solution of One-Dimensional Quantum Systems: (1) Fundamental Concepts and Infinite Square Well. University Chemistry, 2025, 40(3): 124-131. doi: 10.12461/PKU.DXHX202405145
17. [17]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
18. [18]
  Meiran Li , Yingjie Song , Xin Wan , Yang Li , Yiqi Luo , Yeheng He , Bowen Xia , Hua Zhou , Mingfei Shao . Nickel-Vanadium Layered Double Hydroxides for Efficient and Scalable Electrooxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Generation. Acta Physico-Chimica Sinica, 2024, 40(9): 2306007-0. doi: 10.3866/PKU.WHXB202306007
19. [19]
  Zihao Xu , Jia Yao , Xiaogang Peng . Statistical thermodynamics of heat capacity of liquid and gas. University Chemistry, 2026, 41(6): 92-99. doi: 10.12461/PKU.DXHX202511181
20. [20]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1392)
HTML views(226)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Explanation of Spin Coupling Splitting Phenomenon in 1H-NMR Spectra via Quantum Mechanics

Metrics

通讯作者: 陈斌, bchen63@163.com

Explanation of Spin Coupling Splitting Phenomenon in ¹H-NMR Spectra via Quantum Mechanics