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Citation: WANG Zhou, SHI Jian-Xin, PENG Min, ZHENG Sai-Li, LAI Rong, LI Lian-Yun, CHEN Liu-Ping. Synthesis, Characterization and Luminescence Properties of 8-Hydroxyquinoline and Tris(8-hydroxyquinolinato) Aluminum: A Comprehensive Chemistry Experiment[J]. University Chemistry, ;2017, 32(12): 53-59. doi: 10.3866/PKU.DXHX201704010 shu

Synthesis, Characterization and Luminescence Properties of 8-Hydroxyquinoline and Tris(8-hydroxyquinolinato) Aluminum: A Comprehensive Chemistry Experiment

School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China

First, 8-hydroxyquinoline(HQ) was synthesized by the Skraup method, which involves basic skills of organic chemistry experiment such as reflux heating, steam distillation, crystallization and recrystallization. Secondly, the synthesized 8-hydroxyquinoline was used to prepare AlQ₃ in which Al content was measured by back titration. Finally, infrared spectra, hydrogen nuclear magnetic resonance spectra, UV-Vis absorption spectra and fluorescence emission spectra of 8-hydroxyquinoline as well as AlQ₃ were measured. This experiment covers synthesis, characterization and performance testing, facilitating students to understand and complete a basic research process.
- Tris(8-hydroxyquinolinato) aluminum,
- Luminescence,
- Comprehensive chemistry experiment
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