Citation: ZHANG Hui. Application of Electronic Circular Dichroism Spectroscopic Methods in Determination of Absolute Configuration of Chiral Metal Complexes[J]. University Chemistry, ;2017, 32(3): 1-14. doi: 10.3866/PKU.DXHX201612016 shu

Application of Electronic Circular Dichroism Spectroscopic Methods in Determination of Absolute Configuration of Chiral Metal Complexes

ZHANG Hui

College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Electronic circular dichroism (ECD) spectroscopy related to electron transition energy levels has become a mainstream characterization mean of the comprehensive chiroptical spectroscopy in the study on chiral stereochemistry, because of its wider research objects and mutual complementarity with vibrational circular dichroism (VCD) spectroscopy involving vibrational energy levels. In this paper, three main methods of determination of absolute configuration of chiral metal complexes are summarized. ECD spectroscopic methods are described in detail, among them exciton chirality method is emphasized. Additionally, this review points out the developing trend of the comprehensive chiroptical spectroscopy in the future.
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沈阳化工大学材料科学与工程学院沈阳 110142