注册 English

程序升温汽化大体积进样气相色谱法同时测定空气中的甲醛及其他10种羰基污染物(英文)

Stefano DUGHERI ,  Nicola MUCCI ,  Ilenia POMPILIO ,  Giovanni CAPPELLI ,  Costanza BOSSI ,  Alessandro BONARI ,  Giulio ARCANGELI

downloadPDF
引用本文: Stefano DUGHERI,  Nicola MUCCI,  Ilenia POMPILIO,  Giovanni CAPPELLI,  Costanza BOSSI,  Alessandro BONARI,  Giulio ARCANGELI. 程序升温汽化大体积进样气相色谱法同时测定空气中的甲醛及其他10种羰基污染物(英文)[J]. 色谱, 2018, 36(12): 1311-1322. doi: 10.3724/SP.J.1123.2018.08050 shu
Citation:  Stefano DUGHERI,  Nicola MUCCI,  Ilenia POMPILIO,  Giovanni CAPPELLI,  Costanza BOSSI,  Alessandro BONARI,  Giulio ARCANGELI. Determination of airborne formaldehyde and ten other carbonyl pollutants using programmed temperature vaporization-large volume injection-gas chromatography[J]. Chinese Journal of Chromatography, 2018, 36(12): 1311-1322. doi: 10.3724/SP.J.1123.2018.08050 shu

程序升温汽化大体积进样气相色谱法同时测定空气中的甲醛及其他10种羰基污染物(英文)

  • Department of Experimental and Clinical Medicine, University of Florence, I-50141 Florence, Italy

摘要: Long-term indoor-air limit for formaldehyde stipulated by the European Commission is 1 μg/m3, while the World Health Organization has set a threshold of 100 μg/m3 that should not be exceeded for more than 30 min. To date, however, only a few analytical techniques have been developed that can be used to detect formaldehyde at these very restrictive limits. Thus, there is a need to develop for comprehensive methods for analyzing airborne formaldehyde and other carbonyl pollutants in the ambient environment. The aim of this study is to develop a highly sensitive online automated preconcentration gas chromatographic method using large-volume injection with a programmed temperature vaporization injector for the analysis of airborne formaldehyde and ten other carbonyl compounds. The influence of several parameters, such as the maximum volume injected, programmed temperature vaporization transfer time and temperature, carrier gas flow rate, and type of packing material was investigated. After optimization, highly satisfactory results in terms of the absolute and methodological detection limits were achieved, i. e. as low as the μg/m3 level for all the carbonyl pollutants studied. A commercially available sampler, originally designed for active sampling, was evaluated as a passive sampling device; this optimized technique was applied to monitor the concentrations of carbonyl pollutants in the indoor air of ten public buildings in Florence. The strength of this methodology lies both in the low detection limits reached in the simultaneous analysis of a wide group of 2,4-dinitrophenylhydrazine derivatives, and the potential adaptability of this method to other gas chromatographic applications to achieve lower sensitivity.

English

    1. [1] Merchant Research and Consulting Ltd. Formaldehyde:2016 World Market Outlook and Forecast up to 2020.[2018-08-20]. http://mcgroup.co.uk/researches/formaldehyde

    2. [2] Zhang L. Toxicology, 2018, 37:7

    3. [3] Tang X, Bai Y, Duong A, et al. Environ Int, 2009, 35(8):1210

    4. [4] IHS Markit. Chemical Economics Handbook:Formaldehyde.[2018-08-20]. https://www.ihs.com/products/formaldehyde-chemical-economics-handbook.html

    5. [5] Muller C O, Yu H, Besfield Z. Procedia Eng, 2015, 121:582

    6. [6] Huang S, Wei W, Weschler L B, et al. Sci Total Environ, 2017, 590(15):394

    7. [7] World Health Organization (WHO) International Agency for Research on Cancer. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. Vol 88:Formaldehyde, 2-Butoxyethanol and 1-tert-Butoxypropan-2-ol. WHO, 2006[2018-08-20]. https://monographs.iarc.fr/wp-content/uploads/2018/06/mono88.pdf

    8. [8] Nielsen G D, Larsen S T, Wolkoff P. Arch Toxicol, 2017, 91(1):35

    9. [9] Kotzias D, Koistinen K, Kephalopoulos S, et al. The INDEX Project. Critical Appraisal of the Setting and Implementation of Indoor Exposure Limits in the EU. European Commission, Institute for Health and Consumer Protection, Physical and Chemical Exposure Unit. Ispra, Italy, 2005:1

    10. [10] Arts J H E, Muijser H, Kuper C F, et al. Regul Toxicol Pharmacol, 2008, 52:189

    11. [11] Palmes E D, Gunnison A F. Am Ind Hyg Assoc J, 1973, 34:78

    12. [12] Fan Z, Jung K H, Lioy P J. Environ Sci Technol, 2006, 40(19):6051

    13. [13] Bohlin P, Audy O, Skrdlíkova L, et al. Environ Sci Process Impacts, 2014, 16(11):2617

    14. [14] McAlary T, Groenevelt H, Disher S, et al. Environ Sci Process Impacts, 2015, 17(5):896

    15. [15] Casale T, Sacco C, Ricci S, et al. Chemosphere, 2016, 152:392

    16. [16] Sekine Y, Ohnishi M, Sugihara K, et al. Indoor Air Supplement, 2005:2650

    17. [17] Chiappini L, Dagnelie R, Sassine M, et al. Air Qual Atmos Health, 2011, 4(3/4):211

    18. [18] Mullen N A, Russell M L, Lunden M M, et al. Atmospheric Environment, 2013, 80:184

    19. [19] Lee E G, Magrm R, Kusti M, et al. Occup Environ Hyg, 2017, 14(1):31

    20. [20] Dugheri S, Bonari A, Pompilio I, et al. Saf Health Work, 2018, in press

    21. [21] Szulejko J E, Szulejko K H. Trends Analyt Chem, 2015, 64:29

    22. [22] National Institute for Occupational Safety and Health (NIOSH). Aldehydes, 2539 Method, 1994.[2018-08-22]. https://www.cdc.gov/niosh/docs/2003-154/pdfs/2539.pdf

    23. [23] DeGraff I, Nolan L, Fiorante A. The Reporter, Supelco, 1996, 15:5.[2018-08-22]. https://www.sigmaaldrich.com/content/dam/sigma-aldrich/docs/Supelco/The_Reporter/7663.pdf

    24. [24] Bourdin D, Desauziers V. Anal Bioanal Chem, 2014, 406:317

    25. [25] Dalene M, Persson P, Skarping G. J Chromatogr, 1992, 626:284

    26. [26] Suliman F E, Soma Y. J Environ Monit, 2000, 2:470

    27. [27] Shiraishi T, Soma Y, Ishitani O, et al. J Environ Monit, 2001, 3:654

    28. [28] Jeong J Y, Paik N W J. Occup Environ Hyg, 2005, 2:244

    29. [29] Zhang C, Yu J, Zhai M. Chinese Journal of Chromatography, 1998, 16(4):363

    30. [30] Curylo J, Wardencki W. Chem Analityczna, 2005, 50(4):735

    31. [31] Uralets V P, Rijks J A, Leclercq P A. J Chromatogr, 1980, 194:135

    32. [32] Dugheri S, Bonari A, Pompilio I, et al. Acta Chromatogr, 2017, 29(4):511

    33. [33] Deutsche Forschungsgemeinschaft DFG. Analytical Methods for Testing Harmful Substances-Air Analysis, Vol. I, Method No. 2 Aldehyde. Weinheim:VCH, 1996

    34. [34] The French National Research and Safety Institute for the Prevention of Occupational Accidents and Diseases (INRS). Aldehydes. MétroPol, 2004, 001.[2018-08-22]. http://www.inrs.fr/publications/bdd/metropol/fiche.html?refINRS=METROPOL_4

    35. [35] Occupational Safety and Health Administration (OSHA). Formaldehyde, Method No:1007, 2005.[2018-08-22]. https://www.osha.gov/dts/sltc/methods/mdt/mdt1007/1007.pdf

    36. [36] Huynh C K, Vu-Duc T. Anal Bioanal Chem, 2002, 372(5/6):654

    37. [37] Hafkenscheid T L, van Oosten J A. Anal Bioanal Chem, 2002, 372(5/6):658

    38. [38] Ewald J C, Heux S, Zamboni N. Anal Chem, 2009, 81(9):3623

    39. [39] Vallecillos L, Pocurull E, Borrull F. J Chromatogr A, 2012, 1264:87

    40. [40] Cavalheiro J, Prieto A, Monperrus M, et al. Anal Chim Acta, 2013, 773:68

    41. [41] Klimowska A, Wielgomas B. Talanta, 2018, 176:165

    42. [42] Bernarda J R, Ahmad S M, Almeida C, et al. J Braz Chem Soc, 2015, 26(10):2150

    43. [43] Ma W, Gao P, Fan J, et al. Biomed Chromatogr, 2015, 29(6):961

    44. [44] Cacho J, Campillo N, Viñas P, et al. J Chromatogr A, 2016, 1456:27

    45. [45] Mol H G J, Hans G J, Cramers C A, et al. J High Resolut Chromatogr, 1995, 18(1):19

    46. [46] Mol H G J, Hans G J, Janssen H G, et al. J High Resolut Chromatogr, 1995, 18(2):124

    47. [47] Lee P H, Po-on Tang H. Chromatographia, 2015, 78(9/10):695

    48. [48] Terán-Baamonde J, Bouchet S, Tessier E, et al. J Chromatogr A, 2018, 1547:77

    49. [49] Hankemeier T, Kock S J, Vreuls R J, et al. J Chromatogr A, 1998, 811(1/2):105

    50. [50] Hankemeier T, Kock S J, Vreuls R J, et al. J Chromatogr A, 1999, 841(1):75

    51. [51] Jing H, Amirav A. Anal Chem, 1997, 69(7):1426

    52. [52] de Koning S, Lach G, Linkerhägner M, et al. J Chromatogr A, 2003, 1008(2):247

    53. [53] Cavagnino D, Magni P, Zilioli G, et al. J Chromatogr A, 2003, 1019(1/2):211

    54. [54] de Koning S, Kurano M, Janssen H G, et al. J Chromatogr A, 2004, 1023(2):165

    55. [55] Pérez M, Alario J, Vázquez A, et al. J Microcolumn Sep, 1999, 11(80):582

    56. [56] Kim H, Hong Y, Sang B, et al. Anal Methods, 2015, 7(16):6678

    57. [57] Mol H G J, Janssen H G, Cramers C A, et al. TrAC-Trends Anal Chem, 1996, 15(4):206

    58. [58] Korenková E, Matisová E, Slobodník J. J Chromatogr Sci, 2004, 42(10):531

    59. [59] Hoh E, Mastovska K. J Chromatogr A, 2008, 1186(1/2):2

    60. [60] Dong J, Pan Y, Qin Y, et al. Chinese Journal of Chromatography, 2010, 28(7):654

    61. [61] Cao Z, Mou R, Wu L, et al. Chinese Journal of Chromatography, 2014, 32(12):1390

    62. [62] Pacenti M, Dugheri S, Gagliano-Candela R, et al. Acta Chromatogr, 2009, 21(3):379

    63. [63] Shinohara N, Kumagai K, Yamamoto N, et al. J Air Waste Manag Assoc, 2004, 54(4):419

    64. [64] Staniewski J, Rijks J A. J Chromatogr A, 1992, 623(1):105

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  8
  • 文章访问数:  602
  • HTML全文浏览量:  38
文章相关
  • 收稿日期:  2018-08-29
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net