固相微萃取-气相色谱-质谱法鉴别海南黄花梨木与越南黄花梨木

引用本文: 侯思润, 黄晓兰, 马艳芳, 黄芳, 林晓珊, 马叶芬, 朱志鑫, 罗辉泰, 林少彬. 固相微萃取-气相色谱-质谱法鉴别海南黄花梨木与越南黄花梨木[J]. 色谱, 2018, 36(5): 493-498. doi: 10.3724/SP.J.1123.2017.11058 shu

Citation: HOU Sirun, HUANG Xiaolan, MA Yanfang, HUANG Fang, LIN Xiaoshan, MA Yefen, ZHU Zhixin, LUO Huitai, WU Huiqin. Identification of dalbergia odorifera and dalbergia spp by solid phase microextraction-gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, 2018, 36(5): 493-498. doi: 10.3724/SP.J.1123.2017.11058 shu

固相微萃取-气相色谱-质谱法鉴别海南黄花梨木与越南黄花梨木

广东省测试分析研究所, 广东省化学危害应急检测技术重点实验室, 广东广州 510070
基金项目:
国家认监委认证认可科技支撑计划项目（2017RJWKJ32）.

摘要: 采用固相微萃取-气相色谱-质谱法（SPME-GC-MS）研究了海南黄花梨木与越南黄花梨木中的挥发性成分，并对二者进行了鉴别。用电钻在黄花梨木上钻取少量粉末，采用SPME富集挥发性成分，经AB-FFAP极性毛细管气相色谱柱分离，共鉴定出20种挥发性成分，并发现了可用于鉴别海南黄花梨木与越南黄花梨木的两对特征成分：2-（1，1-二甲基乙基）-5-庚基-5-甲基-1，3-二氧戊环-4-酮与2，6，10-三甲基-7，10-环氧-2，11-十二碳二烯-6-醇、2-甲基亚丁基-环戊烷与2-（5-甲基-2-呋喃基）丙醛，并利用其相对含量的关系对海南黄花梨木与越南黄花梨木进行鉴别。该方法具有样品用量小、操作简便快速、不损害整体结构等特点，可用于黄花梨木挥发性成分的分析研究，亦适用于海南黄花梨木与越南黄花梨木的树种鉴别，在家具、工艺品及原木等的鉴别中具有广泛的应用前景。

关键词:

English

Identification of dalbergia odorifera and dalbergia spp by solid phase microextraction-gas chromatography-mass spectrometry

Guangdong Institute of Analysis, Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals, Guangzhou 510070, China
Received Date: 28 November 2017
Fund Project:
Science and Technology Support Project of the Certification and Accreditation Administration of the People's Republic of China (No. 2017RJWKJ32).

Abstract: In addition to species identification, the volatile components of dalbergia odorifera and dalbergia spp, were investigated by solid phase microextraction-gas chromatography-mass spectrometry (SPME-GC-MS). Small amounts of powder samples were acquired by drilling from dalbergia, then the volatile components of the powder samples were concentrated by SPME, and separated by AB-FFAP polar capillary GC column. Of all the volatile components, twenty types were identified, and two pairs of them, 2-(1,1-dimethylethyl)-5-heptyl-5-methyl-1,3-dioxolan-4-one and 2,6,10-trimethyl-7,10-epoxy-2,11-dodecadien-6-ol, 2-methylbutylidene-cyclopentane and 2-(5-methyl-furan-2-yl)-propionaldehyde, could be considered specific volatile components for the identification of dalbergia odorifera and dalbergia spp, and the relative contents of these two pairs were compared for the species identification analysis. The method has the advantages of less sample requirement, simple operation, and no construction damage. The method is suitable for the research of volatile components and species identification analysis of dalbergia odorifera and dalbergia spp, and has broad prospective application in the analysis of furniture, art collections and raw wood of dalbergia.

Key words:

gas chromatography-mass spectrometry (GC-MS)
/ solid phase microextraction (SPME)
/ dalbergia odorifera
/ dalbergia spp
/ specific components
/ identification

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固相微萃取-气相色谱-质谱法鉴别海南黄花梨木与越南黄花梨木

English

Identification of dalbergia odorifera and dalbergia spp by solid phase microextraction-gas chromatography-mass spectrometry

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

固相微萃取-气相色谱-质谱法鉴别海南黄花梨木与越南黄花梨木

English

Identification of dalbergia odorifera and dalbergia spp by solid phase microextraction-gas chromatography-mass spectrometry

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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