有机-无机杂化聚离子液体材料制备及其对染料吸附性能的评价

引用本文: 陈玉洁, 谢明雪, 冯卓, 邓启良. 有机-无机杂化聚离子液体材料制备及其对染料吸附性能的评价[J]. 色谱, 2017, 35(12): 1240-1244. doi: 10.3724/SP.J.1123.2017.08010 shu

Citation: CHEN Yujie, XIE Mingxue, FENG Zhuo, DENG Qiliang. Preparation of organic-inorganic hybrid poly(ionic liquids) material and evaluation of the adsorption to dyes[J]. Chinese Journal of Chromatography, 2017, 35(12): 1240-1244. doi: 10.3724/SP.J.1123.2017.08010 shu

有机-无机杂化聚离子液体材料制备及其对染料吸附性能的评价

天津科技大学化工与材料学院, 天津 300457
基金项目:
国家自然科学基金项目（21375094）.

摘要: 以烯丙基三乙氧基硅烷与1-乙烯基-3-辛基咪唑溴盐离子液体为单体通过自由基聚合及溶胶-凝胶制备了有机-无机杂化聚离子液体材料。通过红外光谱和扫描电镜对所制备的杂化聚离子液体材料进行了表征，并考察了其对柠檬黄、日落黄、苋菜红以及诱惑红等常见染料的吸附性能。研究结果表明：所制备的聚离子液体材料对日落黄和诱惑红具有优异的吸附性能，其吸附容量分别为29.20和86.17 mg/g；当吸附时间为5 min时，该材料对诱惑红和日落黄的吸附分别达到平衡时吸附量的87.5%和72.8%，显示了较快的吸附速率。

关键词:

English

Preparation of organic-inorganic hybrid poly(ionic liquids) material and evaluation of the adsorption to dyes

College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China
Received Date: 13 August 2017
Fund Project:
National Natural Science Foundation of China (No. 21375094).

Abstract: An organic-inorganic hybrid poly(ionic liquids) material was prepared by using allyl triethoxysilane and 1-vinyl-3-octyl imidazolium bromide ionic liquids via combining free radical polymerization with sol-gel process. The prepared hybrid poly(ionic liquids) material was characterized by infrared spectroscopy and scanning electron microscopy. The adsorption properties of the prepared material to common dyes such as tartrazine, sunset yellow, amaranth and allura red were investigated. The results showed that the prepared poly(ionic liquids) material had excellent adsorption properties to sunset yellow and allura red. The adsorption capacities were 29.20 and 86.17 mg/g, respectively. When the adsorption time was 5 min, the material showed a fast adsorption rate to allura red and sunset yellow, which were 87.5% and 72.8% of the balance adsorption capacities, respectively.

Key words:

1. [1] He X Y, Xu X J, Zhou W R, et al. Polymer Bulletin, 2013(5):17何晓燕, 徐晓君, 周文瑞, 等. 高分子通报, 2013(5):17
2. [2] Li T Q. Friend of Chemical Industry, 2007(9):56李潭清. 化工之友, 2007(9):56
3. [3] Welton T. Chem Rev, 1999, 99(8):2071
4. [4] Welton T. Coord Chem Rev, 2004, 248:2459
5. [5] Handy S T. Current Org Chem, 2005, 9(10):959
6. [6] Fox D M, Awad W H, Gilman H W, et al. Green Chem, 2003, 5(6):724
7. [7] Zhang H Y, Liu W W, Wang H P, et al. Polymer Bulletin, 2007(3):17张红燕, 刘崴崴, 王华平, 等. 高分子通报, 2007(3):17
8. [8] Jain N, Kumar A, Chauhan S, et al. Tetrahedron, 2005, 61:1015
9. [9] Raut D, Wankhede K, Vaidya V, et al. Catal Commun, 2009, 10:1240
10. [10] Hsu S C N, Su C J, Yu F L, et al. Electrochim Acta, 2009, 54:1744
11. [11] Zhang X M. Journal of Chengdu Medical College, 2012, 7(2):276张晓曼. 成都医学院学报, 2012, 7(2):276
12. [12] Yu X M, Shen L P, Li Q Z, Wool Textile Journal, 2008(6):18余雪满, 沈兰萍, 李清政. 毛纺科技, 2008(6):18
13. [13] Liang C J, Xu J, Liu Y. Textile Auxiliaries, 2006, 23(1):39梁成军, 徐军, 刘瑜. 印染助剂, 2006, 23(1):39
14. [14] Sahiner N, Sagbas S. Separation and Purification Technology. Amsterdam:Elsevier, 2017:1383
15. [15] Yuan J Y, Mecerreyes D, Antonietti M. Prog Polym Sci, 2013, 38(7):1009
16. [16] Dang M, Deng Q L, Fang G Z, et al. J Mater Chem B, 2017, 5:6339
17. [17] Mecerreyes D. Applications of Ionic Liquids in Polymer Science and Technology. Heidelberg:Springer, 2015
18. [18] Yang S M, Zhang J Y, Li F, et al. Chinese Journal of Chromatography, 2016, 34(1):103杨四梅, 张佳瑶, 李菲, 等. 色谱, 2016, 34(1):103
19. [19] Wang J, Yang X Z, Wu J C, et al. Chinese Journal of Chromatography, 2015, 33(12):1301王军, 杨许召, 武金超, 等. 色谱, 2015, 33(12):1301
20. [20] Ma X H, Wang Q, Li X P, et al. Chinese Journal of Chromatography, 2015, 33(11):1192马晓红, 王强, 李晓萍, 等. 色谱, 2015, 33(11):1192
21. [21] Li X P, Wang Q, Li L, et al. Chinese Journal of Chromatography, 2015, 33(1):58李晓萍, 王强, 李玲, 等. 色谱, 2015, 33(1):58
22. [22] Chen S P, Wang S W, Wang S J, et al. Fine Chemical Intermediates, 2004, 34(5):10陈双平, 王寿武, 汪守建, 等. 精细化工中间体, 2004, 34(5):10
23. [23] Mecerreyes D. Prog Polym Sci, 2011, 36(12):1629
24. [24] Liu C C, Deng Q L, Fang G Z, et al. Anal Chim Acta, 2013, 804:313
25. [25] Han H F, Wang Q, Liu X, et al. J Chromatogr A, 2012, 1246:9
26. [26] Liu C C, Guo T, Su R N, et al. Chinese Journal of Chromatography, 2015, 33(11):1126刘翠翠, 郭婷, 苏日娜, 等. 色谱, 2015, 33(11):1126
27. [27] Su R N, Xie M X, Li H J, et al. Chinese Journal of Chromatography, 2016, 34(6):545苏日娜, 谢明雪, 李海杰, 等. 色谱, 2016, 34(6):545
28. [28] Guo Y L, Gu Y C, Deng Q L. Chinese Journal of Chromatography, 2016, 34(5):456郭艳玲, 顾雨辰, 邓启良. 色谱, 2016, 34(5):456
29. [29] Qian H L, Fang G Z, Deng Q L, et al. RSC Adv, 2014, 4:15518

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沈阳化工大学材料科学与工程学院沈阳 110142

有机-无机杂化聚离子液体材料制备及其对染料吸附性能的评价

English

Preparation of organic-inorganic hybrid poly(ionic liquids) material and evaluation of the adsorption to dyes

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