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Citation: SHENG Liyan, LIU Tingting, LI Meihua, PAN Jie, LUO Yong. Regularity of effective carbon numbers of alkanes, alcohols and ethers and its application to determination without authentic standards by gas chromatography[J]. Chinese Journal of Chromatography, ;2017, 35(8): 875-880. doi: 10.3724/SP.J.1123.2017.04023 shu

Regularity of effective carbon numbers of alkanes, alcohols and ethers and its application to determination without authentic standards by gas chromatography

SHENG Liyan ^1, ,
LIU Tingting ^1,2 ,
LI Meihua ¹ ,
PAN Jie ¹ ,
LUO Yong ^1,2

1.
Shanghai Research Institute of Chemical Industry Co. Ltd., Shanghai 200062, China;
2.
State Key Laboratory of Polyolefins and Catalysis, Shanghai 200062, China

Received Date: 20 April 2017

Fund Project: Shanghai Natural Science Foundation (No. 15ZR1421500)

To realize quantitative analysis without authentic standards by gas chromatography, a calculation method of effective carbon numbers (ECNs) was developed by determining the relative response factors of 66 alkanes, alcohols, ethers with GC-FID and studying the relation between ECNs and chemical structures. The correlation coefficient of 0.9998 (N=66) was achieved between theoretical values and experimental values of ECNs. Fifty-seven percent of determined compounds had relative deviations within ±1% and all of them had relative deviations within ±3%. This method is as accurate as common internal-standard method while used in the determination of oxygenated chemicals in gasoline samples, but with far less time and economical cost. It could be used to solve the problem of lacking authentic standards or surrogates.
- gas chromatography-flame ionization detection (GC-FID),
- alkanes,
- alcohols,
- ethers,
- effective carbon number (ECN),
- relative response factor (RRF),
- determination without authentic standards
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