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表面分子印迹材料和技术在分离分析中的应用进展

侯会卿 ,  苏黎明 ,  黄嫣嫣 ,  金钰龙 ,  赵睿

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引用本文: 侯会卿,  苏黎明,  黄嫣嫣,  金钰龙,  赵睿. 表面分子印迹材料和技术在分离分析中的应用进展[J]. 色谱, 2016, 34(12): 1206-1214. doi: 10.3724/SP.J.1123.2016.09016 shu
Citation:  HOU Huiqing,  SU Liming,  HUANG Yanyan,  JIN Yulong,  ZHAO Rui. Recent applications of surface molecularly imprinting materials and techniques for separation and analysis[J]. Chinese Journal of Chromatography, 2016, 34(12): 1206-1214. doi: 10.3724/SP.J.1123.2016.09016 shu

表面分子印迹材料和技术在分离分析中的应用进展

  • 1.

    中国科学院化学研究所, 中国科学院活体分析化学重点实验室, 北京 100190;

  • 2.

    中国科学院大学, 北京 100049

  • 基金项目:

    国家自然科学基金（21375134，21475140，21675161）；国家重点基础研究发展计划项目（“973”计划）（2015CB856303）.

摘要: 复杂体系的高选择性分析对分离新材料和新方法提出了迫切需求。分子印迹聚合物（MIPs）以其特异性高、化学稳定性好、制备简单且成本低等优点，在高选择性分离分析中展现出巨大的应用前景。但以本体聚合为代表的传统合成方法获得的MIPs存在识别位点位于聚合物内部难以识别、模板分子洗脱不彻底、传质速率慢、结合容量低等问题。表面印迹技术制备的核-壳型表面分子印迹材料是解决上述难题的有效途径。通过核体和壳层结构的设计和构建，表面分子印迹材料还可具备多功能、多响应的特性，适于现代分离分析对快速、高效、高选择性的要求。该文主要综述了近几年表面分子印迹技术在样品前处理、化学/生物传感分析及靶向药物递送领域的应用进展。

English

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  • 收稿日期:  2016-09-05
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