Citation: LIU Zhenzhen, QI Peipei, WANG Xinquan, CHEN Wenxue, WU Liyu, WANG Qiang. Determination of pesticide multiresidue in kiwifruit by magnetic nanoparticles adsorbent purification and ultra performance liquid chromatography- tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2016, 34(8): 762-772. doi: 10.3724/SP.J.1123.2016.03026 shu

Determination of pesticide multiresidue in kiwifruit by magnetic nanoparticles adsorbent purification and ultra performance liquid chromatography- tandem mass spectrometry

LIU Zhenzhen ^1,2 ,
QI Peipei ² ,
WANG Xinquan ² ,
CHEN Wenxue ¹ ,
WU Liyu ² ,
WANG Qiang ^1,2,,

1.
1. Food College, Hainan University, Haikou 570228, China;
2.
2. Institute of Quality and Standard of Agro-Products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China

Corresponding author: WANG Qiang,
Received Date: 18 March 2016

Fund Project:

A simple and fast sample purification method was developed based on magnetic nanoparticles. The present work aimed at purifying the analytes by removing the matrix interferences. Magnetite Fe₃O₄ nanoparticles modified with N-(n-propyl)ethylenediamine (Fe₃O₄-PSA) and the commercial C18 were selected as the cleanup adsorbents. They can remove the target interferences of the matrixes, such as organic acids and non-polar compounds. The amounts of Fe₃O₄-PSA and C18 were systematically optimized for selecting the suitable purification conditions. The simultaneous determination of 52 pesticides and 8 related metabolites in kiwifruit was established by ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). Method validation was performed including the linearity, sensitivity and matrix effect of the method. The results displayed that these pesticides showed good linearities ranging from 2 to 250 μ g/L. The recoveries of the kiwifruit samples at three spiked levels ranged from 76.0% to 121% with the relative standard deviations (RSDs) less than 13.8%. Compared with the QuEChERS method based on PSA and C18, the present method can save the pretreatment time, giving the high throughput analysis possible. It can also satisfy the requirement of the pesticide residue analysis, displaying good application prospect and provide a novel method for rapid determination of pesticide multiresidue in kiwifruit.
1. [1]
  [1] Zhong D L, Tang F B, Shen D Y, et al. Journal of Zhejiang Agricultural Sciences, 2011, 36(6): 1356 钟冬莲, 汤富彬, 沈丹玉, 等. 浙江农业科学, 2011, 36(6): 1356
2. [2]
  [2] Wang N, Hu P, Guo X, et al. Food Industry, 2014, 35(5): 234 王楠, 胡坪, 国欣, 等. 食品工业, 2014, 35(5): 234
3. [3]
  [3] Wang L Z, Huang X Y, Chen Y, et al. Journal of Instrumental Analysis, 2014, 33(10): 1102 王连珠, 黄小燕, 陈泳. 分析测试学报, 2014, 33(10): 1102
4. [4]
  [4] Ma J W, Yan D L. Journal of Anhui Agricultural Sciences, 2008, 36(26): 11195 马纪伟, 闫冬良. 安徽农业科学, 2008, 36(26): 11195
5. [5]
  [5] Anastassiades M, Lehotay S J, Stajnbaher D, et al. J AOAC Int, 2003, 86(2): 412
6. [6]
  [6] Shen W J, Yu K Y, Gui Q W, et al. Chinese Journal of Chromatography, 2009, 27(4): 391 沈伟健, 余可垚, 桂茜雯, 等. 色谱, 2009, 27(4): 391
7. [7]
  [7] Huang H H, Zhang J, Xu D M, et al. Chinese Journal of Chromatography, 2014, 32 (7): 707 黄何何, 张缙, 徐敦明, 等. 色谱, 2014, 32 (7): 707
8. [8]
  [8] Psoma A K, Pasias I N, Bletsou A A, et al. Food Anal Methods, 2014, 8(3): 624
9. [9]
  [9] Nguyen T D, Yu J E, Lee D M, et al. Food Chem, 2008, 110(1): 207
10. [10]
  [10] Wang Z, Wang C. Chinese Journal of Chromatography, 2012, 30(10): 977 王志, 王春. 色谱, 2012, 30(10): 977
11. [11]
  [11] Song Y, Zhao S L, Tchounwou P, et al. J Chromatogr A, 2007, 1166: 79
12. [12]
  [12] Zheng H B, Zhao Q, Mo J Z, et al. J Chromatogr A, 2013, 1300: 127
13. [13]
  [13] Qi P P, Wang Z W, Yang G L, et al. Microchimi Acta, 2015, 182(15): 2521
14. [14]
  [14] Ahmadi F, Rajabi M, Faizi F, et al. Int J Environ An Ch, 2014, 94(11): 1123
15. [15]
  [15] Wang Q, Huang L J, Yu P F, et al. J Chromatogr B, 2013, 912(11): 33
16. [16]
  [16] Abdolmohammad-Zadeh H, Talleb Z. Talanta, 2015, 134(134): 387
17. [17]
  [17] Li Y, Xiao L H, Zhou N Y, et al. Chinese Journal of Analytical Chemistry, 2013, 41(1): 63 李媛, 肖乐辉, 周乃元, 等. 分析化学, 2013, 41(1): 63
18. [18]
  [18] Zhang X, Wang H, Yang C, et al. 2013, 41(6): 669
19. [19]
  [19] Eskandari H, Naderi-Darehshori A. Anal Chim Acta, 2012, 743(18): 137
20. [20]
  [20] Zhang G J, Zang X H, Zhou X, et al. Chinese Journal of Chromatography, 2013, 31(11): 1071 张贵江, 臧晓欢, 周欣, 等. 色谱, 2013, 31(11): 1071
21. [21]
  [21] Deng X J, Guo Q J, Chen X P, et al. Food Chem, 2014, 145(7): 853
22. [22]
  [22] Wu Q H, Zhao G Y, Feng C, et al. J Chromatogr A, 2011, 1218: 7936
23. [23]
  [23] Gao Q, Feng Y Q. Chinese Journal of Chromatography, 2014, 32(10): 1043 高强, 冯钰锜. 色谱, 2014, 32(10): 1043
24. [24]
  [24] Wang S H, Niu H Y, Cai Y Q. Journal of Instrumental Analysis, 2015, 34(2): 127 王赛花, 牛红云, 蔡亚岐. 分析测试学报, 2015, 34(2): 127
25. [25]
  [25] Li H F, Yang H Y, Zhang Y, et al. Chinese Journal of Chromatography, 2014, 32(4): 413 李海芳, 杨红云, 张英, 等. 色谱, 2014, 32(4): 413
26. [26]
  [26] Zhang Y Y, Zhang Z, Chen Z Z, et al. Journal of Food Safety & Quality, 2014, 5(9): 2711 张媛媛, 张卓, 陈忠正, 等. 食品安全质量检测学报, 2014, 5(9): 2711
27. [27]
  [27] Wang L Z, Zhou Y, Huang X Y, et al. Chinese Journal of Chromatography, 2013, 31(12): 1167 王连珠, 周昱, 黄小燕, 等. 色谱, 2013, 31(12): 1167
28. [28]
  [28] Gosetti F, Mazzucco E, Zampieri D, et al. J Chromatogr A, 2010, 1217: 3929
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