Citation: ZHU Binhe, ZHANG Peimin, GUO Weiqiang, LI Gang, JIANG Xinhua, WU Shuchao, ZHU Yan. Determination of anion impurities in barium carbonate by ion chromatography with membrane treatment[J]. Chinese Journal of Chromatography, ;2016, 34(5): 498-501. doi: 10.3724/SP.J.1123.2016.01026 shu

Determination of anion impurities in barium carbonate by ion chromatography with membrane treatment

ZHU Binhe ^1,2 ,
ZHANG Peimin ¹ ,
GUO Weiqiang ¹ ,
LI Gang ³ ,
JIANG Xinhua ⁴ ,
WU Shuchao ⁵ ,
ZHU Yan ^1,2,,

1.
1. Department of Chemistry, Zhejiang University, Hangzhou 310028, China;
2.
2. Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic Chemicals, Zhejiang University, Hangzhou 310028, China;
3.
3. Shaoxing Environmental Monitoring Station, Shaoxing 312000, China;
4.
4. Juhua Hospital, Quzhou 324004, China;
5.
5. Zhejiang Institute of Geology and Mineral Resources, Hangzhou 310007, China

Corresponding author: ZHU Yan,
Received Date: 19 January 2016

Fund Project: 国家自然科学基金项目(21405141) (21405141)国家重大科学仪器设备开发专项(2012YQ09022903) (2012YQ09022903)浙江省自然科学基金项目(LZ16B050001,LY15B050001,S16H180002). (LZ16B050001,LY15B050001,S16H180002)

An ion chromatographic (IC) method with membrane treatment was developed for the simultaneous determination of anions (F^-, SO₄^2- and NO₃^-) in barium carbonate. The cation exchange membrane was applied in providing H⁺ in hydrochloric acid to dissolve barium carbonate and to prevent anions dissolving into the solution from hydrochloric acid. After pre-treatment by acid dissolution and membrane treatment, the sample was diluted for 100 times and filtrated by a 0.22 μ m membrane, then analyzed by IC using 20 mmol/L KOH as the eluent. The target anions were separated by an Ion Pac AG11-HC (50 mm×4 mm) and an Ion Pac AS11-HC (250 mm×4 mm) ion-exchange columns and detected by suppressed conductivity detection with 50 mA current. Under the optimized separation conditions, the calibration curves showed good linearity (R²≥0.9996) in the range of 0.01-5.00 mg/L. The limits of detection were in the range of 1.37-9.45 μ g/L with the relative standard deviations (RSDs) of 1.87%-2.19%. The recoveries of F^-, SO₄^2- and NO₃^- anions were between 84.0% and 106.2%. This method can determine the three inorganic anions (F^-, SO₄^2- and NO₃^-) in barium carbonate fast and accurately. It is suitable for the simultaneous separation and detection of trace inorganic anions in insoluble products.
- membrane treatment,
- ion chromatography (IC),
- anions,
- barium carbonate
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