Citation: PENG Xitian, XIA Hong, ZHANG Xian, HU Xizhou, PENG Lijun, SHEN Jing. Development of a novel analytical method of cartap and its application to the residue and dissipation analysis of cartap in paddy field[J]. Chinese Journal of Chromatography, ;2016, 34(4): 436-441. doi: 10.3724/SP.J.1123.2015.12034 shu

Development of a novel analytical method of cartap and its application to the residue and dissipation analysis of cartap in paddy field

1.
Institute of Agricultural Quality Standards and Testing Technology Research, Hubei Academy of Agricultural Science/Laboratory of Quality & Safety Risk Assessment for Agro-products(Wuhan), Ministry of Agriculture, Wuhan 430064, China

Corresponding author: SHEN Jing,
Received Date: 7 January 2016

Fund Project: 湖北省农科院青-科学基金(2013NKYJJ18) (2013NKYJJ18)湖北省农业科技创新中心项目(2016-620-000-001-037). (2016-620-000-001-037)

Cartap has been widely used as a highly effective pesticide in rice fields for the control of rice stem borer and leaf folde. In this paper, a novel analytical method of cartap in rice plants, husked rice, rice hull, soil and water was developed by gas chromatography-flame photometric detector (GC-FPD). Cartap in these sample matrices was first extracted with dilute hydrochloric acid solution, and then derivatized to nereistoxin with nickel chloride (NiCl₂) under basic condition. At last, nereistoxin was extracted and concentrated by on-line combination of supported liquid-liquid extraction (SLE) and solid phase extraction (SPE). Under the optimal conditions, the recoveries of cartap in these sample matrices spiked at three levels ranged from 80.0% to 114.4% with relative standard deviations (RSDs) less than 13.7%, indicating good accuracy and precision of our proposed method. The proposed method was then applied to the analysis of residue and dissipation of cartap in rice plants, husked rice, rice hull, soil and water under field conditions. The results can provide reference for the establishment of the maximum residue level (MRL) of cartap and estimation of safety of pesticide application technology.
- supported liquid-liquid extraction (SLE),
- gas chromatography-flame photometric detector (GC-FPD),
- cartap,
- rice,
- residue and dissipation
1. [1]
  [1] Lee S J, Tomizawa M, Casida J E. J Agric Food Chem, 2003, 51:2646
2. [2]
  [2] Ferrer C, Mezcua M, Martínez-Uroz, M A, et al. Anal Bioanal Chem, 2010, 398:2299
3. [3]
  [3] Chen H P, Liu X, Wang C P, et al. Journal of Instrumental Analysis, 2013, 32(5):619 陈红平, 刘新, 王川丕, 等. 分析测试学报, 2013, 32(5):619
4. [4]
  [4] Wu G, Yu H F, Bao X X, et al. Chinese Journal of Chromatography, 2007, 25(2):288 吴刚, 虞慧芳, 鲍晓霞, 等. 色谱, 2007, 25(2):288
5. [5]
  [5] Zhou S L, Dong Q X, Li S N, et al. Aquat Toxicol, 2009, 95:339
6. [6]
  [6] Liao J W, Kang J J, Jeng C R, et al. Toxicol, 2006, 219:73
7. [7]
  [7] Park Y, Choe S, Lee H, et al. Forensic Sci Int, 2015, 252:143
8. [8]
  [8] Wang K, Wu J X, Zhang H Y. Ecotoxicol Environ Saf, 2012, 86:111
9. [9]
  [9] Fu Y, Zheng Z T, Wei P, et al. Toxicol Environ Chem, 2016, 98(1):118
10. [10]
  [10] Raza N, Aslam M, Noreen Z, et al. Int J Curr Pharm Res, 2013, 5:54
11. [11]
  [11] Jing X, Du L M, Wu H, et al. J Integr Agric, 2012, 11:1861
12. [12]
  [12] Guo J J, Liu X, Gao H T, et al. RSC Adv, 2014, 4(52):27228
13. [13]
  [13] Li W, Zhang D H, Tang Y F, et al. Talanta, 2012, 101:382
14. [14]
  [14] Mahboob S, Al-Ghanim K A, Al-Misned F, et al. Toxicol Environ Chem, 2014, 96(5):799
15. [15]
  [15] Hernando M D, Ferrer C, Ulaszewska M, et al. Anal Bioanal Chem, 2007, 389:1815
16. [16]
  [16] Wang L J, Zhou Y, Huang X Y, et al. Chinese Journal of Chromatography, 2013, 31(12):1167 王连珠, 周昱, 黄小燕, 等. 色谱, 2013, 31(12):1167
17. [17]
  [17] Asahi Y, Yoshida T. Chem Pharm Bull, 1977, 25:2211
18. [18]
  [18] Lee S J, Caboni P, Tomizawa M, Casida J E. J Agric Food Chem, 2004, 52:95
19. [19]
  [19] Wu G, Yu H F, Bao X X, et al. Journal of Chinese Institute of Food Science and Technology, 2006, 6(5):129 吴刚, 虞慧芳, 鲍晓霞, 等. 中国食品学报, 2006, 6(5):129
20. [20]
  [20] Johnson C R, Zhang B, Fantauzzi P, et al. Presented at the 5th International Symposium on Solid Phase Synthesis and Combinatorial Chemical Libraries. London, September 1997
21. [21]
  [21] Liu H T, Huang L P, Chen Y X, et al. J Chromatogr B, 2015, 992:96
22. [22]
  [22] Bao J M, Ma Z S, Sun Y, et al. Chinese Journal of Chromatography, 2012, 30:798 包建民, 马志爽, 孙莹, 等. 色谱, 2012, 30:798
23. [23]
  [23] Anastassiades M, Lehotay S J, Stajnbaher D, et al. J AOAC Int, 2003, 86:412
24. [24]
  [24] He Z Y, Wang L, Peng Y, et al. Food Chem, 2015, 169:372
1. [1]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
2. [2]
  Haiyuan Wang , Xiaoning Jin , Yajing Sun , Zhen Zhang , Wentao Zhao , Yi Li . Practical Exploration of High-Performance Liquid Chromatography Experiment Teaching Reform Empowered by Artificial Intelligence. University Chemistry, 2026, 41(4): 45-51. doi: 10.12461/PKU.DXHX202505076
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
5. [5]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-0. doi: 10.3866/PKU.WHXB202309036
6. [6]
  Siwei Hou , Yaxin Niu , Guanglu Zhang , Yanmei Yang , Xu Wang , Zhenzhen Chen . Application of Solid-Phase Microextraction and Mass Spectrometry in Environmental Detection. University Chemistry, 2026, 41(3): 297-306. doi: 10.12461/PKU.DXHX202504078
7. [7]
  Xiaojun Liu , Lang Qin , Yanlei Yu . Dynamic Manipulation of Photonic Bandgaps in Cholesteric Liquid Crystal Microdroplets for Applications. Acta Physico-Chimica Sinica, 2024, 40(5): 2305018-0. doi: 10.3866/PKU.WHXB202305018
8. [8]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
9. [9]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053
10. [10]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
11. [11]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
12. [12]
  Chenfei Li , Xu Han , Qimeng Zhang , Ben Zhang , Xinyao Huang , Mingxiao Deng , Caixia Zheng , Haizhu Sun . Measurement of Stress-Strain Curves of Polymeric Materials Using a Non-Contact Displacement Detector. University Chemistry, 2026, 41(1): 179-187. doi: 10.12461/PKU.DXHX202505101
13. [13]
  Yujing Chen , Hongqun Ouyang , Dan Zhao , Yanyan Chu , Zhengping Qiao . Recommendations for the Content and Instruction of the Physical Chemistry Experiment “Construction of Ternary Liquid-Liquid Phase Diagrams”. University Chemistry, 2025, 40(7): 359-366. doi: 10.12461/PKU.DXHX202409120
14. [14]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
15. [15]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
16. [16]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
17. [17]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
18. [18]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
19. [19]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
20. [20]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(931)
HTML views(97)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142