Citation: JIANG Xinhua, NI Chengzhu, ZHU Binhe, ZHAO Xunyan, CHEN Suqing, LV Weide, ZHANG Jiajie, ZHANG Peimin, LI Gang, ZHU Yan. Determination of fluoride in soil water extract by ion chromatography with column-switching technique[J]. Chinese Journal of Chromatography, ;2016, 34(4): 442-446. doi: 10.3724/SP.J.1123.2015.12025 shu

Determination of fluoride in soil water extract by ion chromatography with column-switching technique

JIANG Xinhua ¹ ,
NI Chengzhu ² ,
ZHU Binhe ² ,
ZHAO Xunyan ² ,
CHEN Suqing ³ ,
LV Weide ⁴ ,
ZHANG Jiajie ² ,
ZHANG Peimin ² ,
LI Gang ⁵ ,
ZHU Yan ^2,,

1.
1. Zhejiang Quhua Hospital, Quzhou 324004, China;
2.
2. Department of Chemistry, Zhejiang University, Hangzhou 310028, China;
3.
3. School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 317000, China;
4.
4. School of Linjiang, Hangzhou Vocational & Technical College, Hangzhou 310018, China;
5.
5. Shaoxing Environmental Monitoring Central Station, Shaoxing 312000, China

Corresponding author: ZHU Yan,
Received Date: 22 December 2015

Fund Project: 国家重大科学仪器设备开发专项(2012YQ09022903) (2012YQ09022903)浙江省微量有毒化学物健康风险评估技术研究重点实验室项目(2014006,2014007) (2014006,2014007)浙江省自然科学基金项目(LZ16B050001,LY15B050001,LY12B05003,LQ13B050001,LY13B020001) (LZ16B050001,LY15B050001,LY12B05003,LQ13B050001,LY13B020001)浙江省公益性技术应用研究(分析测试)项目(2015C37022). (分析测试)项目(2015C37022)

A new method was proposed for the determination of fluoride in soil water extract by ion chromatography with column-switching technique. A reversed-phase column was used as a pretreatment column on-line to separate fluoride and organic acids as well as to eliminate organics. Fluoride was collected by a collection loop and delivered to the analytical system. Under the optimum conditions, the linear range of the method for fluoride was 0.05-10.0 mg/L (r=0.9999), and the limit of detection (S/N=3) was 5.50 μg/L. The recovery was in the range of 103.4%-105.3% with the relative standard deviation of 2.0%-2.1%. The method could be applied to determine fluoride in complicated samples.
- ion chromatography (IC),
- column-switching,
- fluoride,
- water extract,
- soil
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