Citation: SHI Leimeng, GAO Yuan, HOU Xiaohong, ZHANG Haijun, Zhang Yichi, CHEN Jiping. Determination of short-chain chlorinated paraffins in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry[J]. Chinese Journal of Chromatography, ;2016, 34(2): 202-208. doi: 10.3724/SP.J.1123.2015.08032 shu

Determination of short-chain chlorinated paraffins in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry

SHI Leimeng ^1,2 ,
GAO Yuan ² ,
HOU Xiaohong ¹ ,
ZHANG Haijun ² ,
Zhang Yichi ² ,
CHEN Jiping ^1,2,,

1.
1. Shenyang Pharmaceutical University, Shenyang 110016, China;
2.
2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Corresponding author: CHEN Jiping,
Received Date: 27 August 2015

Fund Project: 国家自然科学基金项目(21307128,21337002). (21307128,21337002)

An analytical method for quantifying short-chain chlorinated paraffins (SCCPs) in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry (HRGC-ECNI-LRMS) was developed. An acidified silica gel column and a basic alumina column were used to optimize the cleanup procedures. The results showed a good linearity (R²＞0.99) between the total response factors and the degree of chlorination of SCCPs in the content range of 58.1%-63.3%. The limits of detection (S/N≥3) and the limits of quantification (S/N≥10) were 4.2 and 12 pg, respectively. The method detection limit (MDL) for SCCPs was 0.34ng/m³ (n=7). The recoveries of SCCPs in air samples were in the range of 81.9% to 94.2%. It is demonstrated that the method is suitable for the quantitative analysis of SCCPs in air samples.
1. [1]
  [1] Santos F J, Parera J, Galceran M T. Anal Bioanal Chem, 2006, 386(4): 837
2. [2]
  [2] Zencak Z, Oehme M. TrAC-Trends Anal Chem, 2006, 25(4): 310
3. [3]
  [3] Feo M L, Eljarrat E, Barceló D, et al. TrAC-Trends Anal Chem, 2009, 28(6): 778
4. [4]
  [4] Barber J L, Sweetman A J, Thomas G O, et al. Environ Sci Technol, 2005, 39(12): 4407
5. [5]
  [5] Houde M, Muir D C G, Tomy G T, et al. Environ Sci Technol, 2008, 42(10): 3893
6. [6]
  [6] Zeng L X, Wang T, Wang P, et al. Environ Sci Technol, 2011, 45(13): 5529
7. [7]
  [7] European Commission. A Frameworkfor Community Action in the Field of Water Policy. (2000-10-23) [2000-12-22]. http://eur-lex.europa.eu/resource.html?uri=cellar:5c835afb-2ec6-4577-bdf8-756d3d694eeb.0004.02/DOC_1&format=PDF
8. [8]
  [8] United Naitons Environment Programme. Relevant Developments for Action by the Conference of the Parties. (2007-01-23) [2007-04-30]. http://www.pops.int/documents/meetings/cop_3/meetingdocs/cop3_12/12-K0760200%20POPS-COP3.pdf
9. [9]
  [9] Zhang W Y, Wan X, Li L X, et al. Chinese Journal of Chromatography, 2014, 32(10): 1152 张伟亚, 万昕, 李丽霞, 等. 色谱, 2014, 32(10): 1152
10. [10]
  [10] Hu J X, Liao H Y, Han W Y, et al. Environmental Protection, 2010, 23(4): 16 胡建信, 廖虹云, 韩文亚, 等. 环境保护, 2010, 23(4): 16
11. [11]
  [11] Chen M Y, Luo X J, Zhang X L, et al. Environ Sci Technol, 2011, 45(23): 9936
12. [12]
  [12] Zeng L X, Wang T, Han W Y, et al. Environ Sci Technol, 2011, 45(6): 2100
13. [13]
  [13] Stejnarova P, Coelhan M, Kostrhounova R, et al. Chemosphere, 2005, 58(3): 253
14. [14]
  [14] Reth M, Zencak Z, Oehme M. Chemosphere, 2005, 58(7): 847
15. [15]
  [15] Thomas G O, Farrar D, Braekevelt E, et al. Environ Int, 2006, 32(1): 34
16. [16]
  [16] Gao Y, Zhang H J, Su F, et al. Environ Sci Technol, 2012, 46(7): 3771
17. [17]
  [17] Yuan B, Wang T, Zhu N L, et al. Environ Sci Technol, 2012, 46(12): 6489
18. [18]
  [18] Zeng L X, Zhao Z S, Li H J, et al. Environ Sci Technol, 2012, 46(18): 9898
19. [19]
  [19] Harada K H, Takasuga T, Hitomi T, et al. Environ Sci Technol, 2011, 45(16): 7019
20. [20]
  [20] Xing Y N, Lin Z H, Feng A H, et al. Chinese Journal of Chromatography, 2015, 33(2): 182 幸苑娜, 林志惠, 冯岸红, 等. 色谱, 2015, 33(2): 182
21. [21]
  [21] Tomy G T, Stern G A, Muir D C G, et al. Anal Chem, 1997, 69(14): 2762
22. [22]
  [22] Reth M, Zencak Z, Oehme M. J Chromatogr A, 2005, 1081: 225
23. [23]
  [23] Gao Y, Zhang H J, Chen J P, et al. Anal Chim Acta, 2011, 703(2): 187
24. [24]
  [24] Ma X D, Zhang H J, Zhou H Q, et al. Atmos Environ, 2014, 90: 10
25. [25]
  [25] Li X M, Wang P,Li Y M, et al. Chinese Journal of Chromatography, 2010, 28(5): 449 李晓敏, 王璞, 李英明, 等. 色谱, 2010, 28(5): 449
26. [26]
  [26] Wang T, Han S L, Yuan B, et al. Environ Pollut, 2012, 171: 38
27. [27]
  [27] Li Q L, Li J, Wang Y, et al. Environ Sci Technol, 2012, 46(21): 11948
1. [1]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
2. [2]
  Meng-Yin Wang , Ruo-Bei Huang , Jian-Feng Xiong , Jing-Hua Tian , Jian-Feng Li , Zhong-Qun Tian . Critical Role and Recent Development of Separator in Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2307017-0. doi: 10.3866/PKU.WHXB202307017
3. [3]
  Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
4. [4]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
5. [5]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004
6. [6]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
7. [7]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
8. [8]
  Yan Long , Wenbo Zhao , Qing Cao , Xiangyu Li , Fukui Li , Yanwei Hu , Shiyu Song , Kaikai Liu . Phosphorescent carbon nanodot inks for scalable and high-resolution invisible printing. Acta Physico-Chimica Sinica, 2026, 42(3): 100198-0. doi: 10.1016/j.actphy.2025.100198
9. [9]
  Yuanchun Pan , Xinyun Lin , Leyi Yang , Wenya Hu , Dekui Song , Nan Liu . Artificial Intelligence Science Practice: Preparation of Electronic Skin by Chemical Vapor Deposition of Graphene. University Chemistry, 2025, 40(11): 272-280. doi: 10.12461/PKU.DXHX202412052
10. [10]
  Siwei Hou , Yaxin Niu , Guanglu Zhang , Yanmei Yang , Xu Wang , Zhenzhen Chen . Application of Solid-Phase Microextraction and Mass Spectrometry in Environmental Detection. University Chemistry, 2026, 41(3): 297-306. doi: 10.12461/PKU.DXHX202504078
11. [11]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
12. [12]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-0. doi: 10.3866/PKU.WHXB202309036
13. [13]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
14. [14]
  Linlin Wu , Yonghua Zhou , Zhongbei Li , Liu Deng , Younian Liu , Limiao Chen , Jianhan Huang . Digital Education Promoting Applied Chemistry Comprehensive Experiments: A Case Study of Catalytic Oxidation of Hydrogen Chloride and Reaction Kinetics. University Chemistry, 2025, 40(9): 273-278. doi: 10.12461/PKU.DXHX202411018
15. [15]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
16. [16]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
17. [17]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
18. [18]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
19. [19]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
20. [20]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(471)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142