Citation: DA Jing, WANG Gangli, CAO Jin, ZHANG Qingsheng. Determination of 30 carbamate pesticide residues in vegetative foods by QuEChERS-liquid chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(8): 830-837. doi: 10.3724/SP.J.1123.2015.04013 shu

Determination of 30 carbamate pesticide residues in vegetative foods by QuEChERS-liquid chromatography-tandem mass spectrometry

1.
National Institutes for Food and Drug Control, Beijing 100050, China

Corresponding author: WANG Gangli, CAO Jin,
Received Date: 9 April 2015

Via the classification of vegetative foods in British Standard EN 15662, six representative food matrices were chosen in the current study. The QuEChERS method for each matrix was optimized. The 30 carbamate pesticide residues in the samples after pretreatment were determined by liquid chromatography-tandem mass spectrometry in positive ionization mode. According to the experimental results, the linear ranges were 1-100 μg/kg for aldicarb sulfone and 2-100 μg/kg for the others. The recoveries at three spiked levels of 5, 20 and 100 μg/kg in the six representative matrices were between 56.13% and 127.6%, with the RSDs between 0.47% and 16%. The limits of quantification (S/N≥10) were in the range of 0.041-1.9 μg/kg. In conclusion, this method provides a sensitive and efficient way suitable for the analysis of the 30 carbamate pesticide residues in vegetative foods.
- liquid chromatography-tandem mass spectrometry (LC-MS/MS),
- QuEChERS,
- carbamate pesticides,
- vegetative foods
1. [1]
  [1] Huang Z Q. Guidance for Detection of Pesticide Residues in Food. Beijing: China Standards Press (黄志强. 食品中农药残留检测指南. 北京: 中国标准出版社), 2010
2. [2]
  [2] Buchberger W W. Anal Chim Acta, 2007, 593(2): 129
3. [3]
  [3] Li N. [MS Dissertation]. Beijing: University of Science and Technology of China (李娜. [硕士学位论文]. 北京: 中国科学技术大学), 2011
4. [4]
  [4] Pareja L, Cesio V, Heinzen H, et al. Talanta, 2011, 83(5): 1613
5. [5]
  [5] Zhang F, Li Y, Yu C, et al. Bull Environ Contam Toxicol, 2012, 88(6): 885
6. [6]
  [6] Da J, Wang G L, Cao J, et al. Chinese Journal of Pharmaceutical Analysis (达晶, 王钢力, 曹进, 等. 药物分析杂志), 2014, 34(5): 760
7. [7]
  [7] Wang L Z, Zhou Y, Huang X Y, et al. Chinese Journal of Chromatography (王连珠, 周昱, 黄小燕, 等. 色谱), 2013, 31(12): 1167
8. [8]
  [8] Mastovska K, Dorweiler K J, Lehotay S J, et al. J Agric Food Chem, 2010, 58(10): 5959
9. [9]
  [9] Payá P, Anastassiades M, Mack D, et al. Anal Bioanal Chem, 2007, 389(6): 1697
10. [10]
  [10] Kwon H, Lehotay S J, Geis-Asteggiante L. J Chromatogr A, 2012, 1270: 235
11. [11]
  [11] Kmellár B, Fodor P, Pareja L, et al. J Chromatogr A, 2008, 1215(1/2): 37
12. [12]
  [12] Agilent Technologies. Training Materials of Rapid Detection of Multi-Pesticide Residues in Fresh Fruits and Vegetables. [2015-04-09]. http://wenku.baidu.com/link?url=57aywD0Q6WTnl7XKbIHuEwWENnSuPS32QO8X0a0gHpO OzdnNt_K0mK2cucVaEHVSl5Skc03WlPmdXQoQg0QirnBsO plkY9l3mh0FqwnxmJW
13. [13]
  [13] Jurgen H G. Mass Spectrometry. 2nd ed. New York: Springer, 2010
1. [1]
  Simin Fang , Hong Wu , Sizhe Sheng , Lingling Li , Yuxi Wang , Hongchun Li , Jun Jiang . The Food Kingdom Lecture Series: The Science behind Color. University Chemistry, 2024, 39(9): 177-182. doi: 10.12461/PKU.DXHX202402012
2. [2]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
3. [3]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
4. [4]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
5. [5]
  Siwei Hou , Yaxin Niu , Guanglu Zhang , Yanmei Yang , Xu Wang , Zhenzhen Chen . Application of Solid-Phase Microextraction and Mass Spectrometry in Environmental Detection. University Chemistry, 2026, 41(3): 297-306. doi: 10.12461/PKU.DXHX202504078
6. [6]
  Qi Liang , Xinxin Wang , Xinmiao Zhao , Mohan Yu , Yue Sun . 电子圆二色谱结合量子化学计算的氨基酸手性解析——介绍一个计算化学综合实验. University Chemistry, 2026, 41(5): 380-390. doi: 10.12461/PKU.DXHX202511096
7. [7]
  Haiyuan Wang , Xiaoning Jin , Yajing Sun , Zhen Zhang , Wentao Zhao , Yi Li . Practical Exploration of High-Performance Liquid Chromatography Experiment Teaching Reform Empowered by Artificial Intelligence. University Chemistry, 2026, 41(4): 45-51. doi: 10.12461/PKU.DXHX202505076
8. [8]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
9. [9]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
10. [10]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
11. [11]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-0. doi: 10.3866/PKU.WHXB202309036
12. [12]
  Chunyang Zheng , Shiyu Liu , Nuo Yi , Hong Shang . The Adventures in the Kingdom of Plant Pigments. University Chemistry, 2024, 39(9): 170-176. doi: 10.3866/PKU.DXHX202308085
13. [13]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
14. [14]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
15. [15]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
16. [16]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053
17. [17]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
18. [18]
  Jian Cao , Chang Liu , Danling Wang , Haichao Li , Lina Xu , Hongping Xiao , Shaoqi Zhan , Xiao He , Guoyong Fang . Machine learning potentials for property predictions of two-dimensional group-Ⅲ nitrides. Acta Physico-Chimica Sinica, 2026, 42(4): 100224-0. doi: 10.1016/j.actphy.2025.100224
19. [19]
  Linghua Chen . 基于双联动“三学”模式的食品专业分析化学教学改革. University Chemistry, 2025, 40(8): 78-91. doi: 10.12461/PKU.DXHX202409095
20. [20]
  Nian LIU , Biao ZHENG , Kun WANG , Chunbao ZHENG , Qingyan HAN , Enjie HE , Saidong XUE . Synthesis and spectroscopic performance of double perovskite Li_0.5La_0.5MgSrWO₆∶Mn⁴⁺ phosphors for plant growth lighting. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 129-140. doi: 10.11862/CJIC.20250069

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(737)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142