Citation: WANG Muhua, LIU Junwei, HUANG Zhongping, ZHANG Jiajie, ZHU Yan. Preparation of an agglomerated ion chromatographic stationary phase with 2,3-ionene and its application in SO₄^2- analysis[J]. Chinese Journal of Chromatography, ;2015, 33(7): 678-682. doi: 10.3724/SP.J.1123.2015.02052 shu

Preparation of an agglomerated ion chromatographic stationary phase with 2,3-ionene and its application in SO₄^2- analysis

1.
1. Department of Chemistry, Lishui University, Lishui 323000, China;

Corresponding author: ZHU Yan,
Received Date: 5 February 2015

Fund Project: 浙江省自然科学基金项目(Y4110532, LY12B05003) (Y4110532, LY12B05003)浙江省高等学校访问学者专业发展项目(FX2013148) (FX2013148)国家重大科学仪器设备开发专项(2012YQ09022903) (2012YQ09022903)浙江省公益性科技计划(分析测试)项目(2012C37038). (分析测试)项目(2012C37038)

The poly-electrolyte cation functional group of 2,3-ionene was synthesized with tetramethyl ethylenediamine and 1,3-dibromopropane as the raw materials. Multiporous polystyrene-divinylbenzene microsphere particles (PS-DVB) were produced by swelling method with polystyrene as seeds and sulfonated. Then the 2,3-ionene was bonded on the sulfonated multiporous polystyrene-divinylbenzene microsphere particles by agglomeration to get the agglomerative ion-exchange stationary phase. After optimizing the synthetic conditions, the new stationary phase was characterized by the techniques including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and elemental analysis. The chromatographic column was packed by slurry method and applied in the analysis of SO₄^2- with a conductivity detector. SO₄^2- and other six common anions including F^-, Cl^-, NO₂^-, Br^-, NO₃^-, PO₄^3-, were separated and analyzed rapidly on the self-regulating chromatographic column within 8 min. The linear range was from 0.5 to 50 mg/L with correlation coefficient (r) of 0.9992. The LOD was 0.04 mg/L with S/N of 3. The relative standard deviations (RSDs, n=6) were 2.4% and 3.1% for the peak area and retention time, respectively. The recoveries were between 99.2% and 101.8%. The retention times of SO₄^2- did not change significantly after long time use of the self-regulating chromatographic column. The self-regulating chromatographic column is suitable for the detection of SO₄^2- in complex matrix samples.
- 2,3-ionene,
- agglomerative ion chromatographic stationary phase,
- sulfate ion (SO₄^2-),
- preparation
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Preparation of an agglomerated ion chromatographic stationary phase with 2,3-ionene and its application in SO42- analysis

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Preparation of an agglomerated ion chromatographic stationary phase with 2,3-ionene and its application in SO₄^2- analysis