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Citation: LIU Jinghua, SUN Zhenzhong, HUANG Xueling, GUO Xia, SUN Jianhua. Determination of 11 sulfonamide residues in aquaculture water and sediments by high performance liquid chromatography coupled with post-column derivatization[J]. Chinese Journal of Chromatography, ;2015, 33(4): 434-440. doi: 10.3724/SP.J.1123.2014.12022 shu

Determination of 11 sulfonamide residues in aquaculture water and sediments by high performance liquid chromatography coupled with post-column derivatization

  • 1.

    Shanghai Fisheries Research Institute, Shanghai Fisheries Technical Extension Station, Shanghai 200433, China

  • Corresponding author: LIU Jinghua, 
  • Received Date: 15 December 2014
    Available Online: 15 January 2015

  • An analytical method was developed for the determination of 11 sulfonamide compounds in aquaculture water and sediments by high performance liquid chromatography (HPLC) coupled with post-column derivatization. The filtered water sample was purified and concentrated with HLB cartridge, while the sediment sample was extracted with a mixture of methanol and EDTA-Mcllvaine buffer (1:1, v/v), and then purified and enriched through HLB solid-phase extraction. The sulfonamides were separated on a C18 column by HPLC and on-line derivatized with a fluorescamine and detected with a fluorescence detector. The parameters of post-column derivatization system were optimized, and the fluorescamine solution concentration, velocity of reagent solution and reaction temperature were 0.2 g/L, 0.15 mL/min and 50 ℃, respectively. The calibration curves of the method showed good linearity in the range of 0.01-1.0 mg/L, with the correlation coefficients (r2) all above 0.99995. The recoveries were 79.3%-100.7% and 74.6%-95.3% with RSD values of 2.2%-11.0% and 2.6%-10.3% for the 11 sulfonamides in aquaculture water and sediments, respectively. The respective limits of detection (LODs, S/N=3) were 0.9-5.5 ng/L and 0.3-1.3 μg/kg and the limits of quantification (LOQs, S/N=10) were 3.0-18.1 ng/L and 1.0-4.4 μg/kg. The method can be applied to the determination of sulfonamides in the aquaculture environment, and it has a good practicability.
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    1. [1]

      [1] Rodgers C, Furones M D. Opt Medit, 2009, A/86: 41

    2. [2]

      [2] Holmstrom K, Graslund S, Wahlstrom A, et al. Int J Food Sci Tech, 2003, 38(3): 255  

    3. [3]

      [3] Tamtam F, Mercier F, Le Bot B, et al. Sci Total Environ, 2008, 393(1): 84  

    4. [4]

      [4] Chang H, Hu J Y, Wang L Z, et al. Chin Sci Bull, 2008, 53(4): 514  

    5. [5]

      [5] Schwaiger J, Ferling H, Mallow U, et al. Aquat Toxicol, 2004, 68(2): 141  

    6. [6]

      [6] Mimeault C, Woodhouse A J, Miao X S, et al. Aquat Toxicol, 2005, 73: 44  

    7. [7]

      [7] He X T, Wang Q, Nie X P, et al. Environmental Science (何秀婷, 王奇, 聂湘平, 等. 环境科学), 2014, 35(7): 2728

    8. [8]

      [8] Ruan Y F, Chen J M, Guo C S, et al. Journal of Agro-Environment Science (阮悦斐, 陈继淼, 郭昌胜, 等. 农业环境科学学报), 2011, 30(12): 2586

    9. [9]

      [9] Wang M, Yu S, Hong Y W, et al. Ecology and Environmental Sciences (王敏, 俞慎, 洪有为, 等. 生态环境学报), 2011, 20(5): 934

    10. [10]

      [10] Pastor-Navarro N, Gallego-Iglesias E, Maquieira A, et al. Talanta, 2007, 71(2): 923  

    11. [11]

      [11] Cannavan A, Hewitt S A, Blanchflower W J, et al. Analyst, 1996, 121(10): 1457  

    12. [12]

      [12] Zhou A X, Su X S, Gao S, et al. Chinese Journal of Analytical Chemistry (周爱霞, 苏小四, 高松, 等. 分析化学), 2014, 42(3): 397

    13. [13]

      [13] Kung T A, Tsai C W, Ku B C, et al. Food Chem, 2015, 175: 189  

    14. [14]

      [14] Ebrahimpour B, Yamini Y, Rezazadeh M. Environ Monit Assess, 2015, 187(1): 4162  

    15. [15]

      [15] Natalia A M, Laura G G, Ana M G C. Food Chem, 2014, 143: 459  

    16. [16]

      [16] Sun H, Ai L F, Wang F C. Chromatographia, 2007, 66(5/6): 333

    17. [17]

      [17] Nebot C, Regal P, Miranda M J, et al. Food Chem, 2013, 141(3): 2294  

    18. [18]

      [18] Marisol J B, Periche A, Donmenech E, et al. Food Control, 2015, 50: 243  

    19. [19]

      [19] Li W H, Shi Y L, Gao L H, et al. Journal of Instrumental Analysis (厉文辉, 史亚利, 高立红, 等. 分析测试学报), 2010, 29(10): 987

    20. [20]

      [20] Huang X J, Chen L L, Yuan D X. Anal Bioanal Chem, 2013, 405(21): 6885  

    21. [21]

      [21] Du Y, Yang H Y, Xu W D. Chinese Journal of Pharmaceutical Analysis (杜玥, 杨慧元, 徐伟东. 药物分析杂志), 2010, 30(3): 471

    22. [22]

      [22] Tang C M, Huang Q X, Yu Y Y, et al. Journal of Instrumental Analysis (唐才明, 黄秋鑫, 余以义, 等. 分析测试学报), 2009, 28(8): 909

    23. [23]

      [23] Lu K, Tong Q Y. Journal of Instrumental Analysis (卢坤, 童群义. 分析测试学报), 2011, 30(11): 1320

    24. [24]

      [24] Yang X L, Li J, Li X W, et al. Journal of Environment and Health (杨晓蕾, 李杰, 李学文, 等. 环境与健康杂志), 2012, 29(4): 357

    25. [25]

      [25] Liu H X. Food Science (刘海新. 食品科学), 2009, 30(2): 204

    26. [26]

      [26] Li X D, Xian Q M, Liu H L, et al. Chinese Journal of Analytical Chemistry (李学德, 鲜啟明, 刘红玲, 等. 分析化学), 2010, 38(3): 429

    27. [27]

      [27] Huang D M, Huang X Y, Gu R R, et al. Chinese Journal of Chromatography (黄冬梅, 黄宣运, 顾润润, 等. 色谱), 2014, 32(8): 874

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