Citation: WEI Feng, WU Song, YU Xi, YIN Xianggang, GE Mingqiao. Determination of fluorescent whitening agents in disposable sanitary products by high performance liquid chromatography[J]. Chinese Journal of Chromatography, ;2015, 33(2): 158-163. doi: 10.3724/SP.J.1123.2014.10003 shu

Determination of fluorescent whitening agents in disposable sanitary products by high performance liquid chromatography

WEI Feng ^1,2,3,, ,
WU Song ³ ,
YU Xi ³ ,
YIN Xianggang ³ ,
GE Mingqiao ²

1.
1. Wuxi Entry-Exit Inspection and Quarantine Bureau, Wuxi 214101, China;

Corresponding author: WEI Feng,
Received Date: 10 October 2014
Available Online: 17 November 2014
Fund Project: 江苏省博士后科研资助计划项目(1302164C). (1302164C)

A method for the determination of four fluorescent whitening agents (FWAs) (FWA 357, FWA 220, FWA 204 and FWA 113) in disposable sanitary products by high performance liquid chromatography with diode array detection (HPLC-DAD) was developed. The sample was extracted with a 20 mL ultrapure water by sonication for 30 min at 80 ℃. The HPLC method was performed on an SB Phenyl column (250 mm×4.6 mm, 5 μm) by gradient elution using 5 mmol/L ammonium acetate and acetonitrile as mobile phases, which can separate the target analytes successfully. The target analytes showed good linearity in the range of 0.025-400 mg/L with the correlation coefficients (r²) greater than 0.9999. The limits of detection (LODs, S/N=3) were 0.02-0.1 mg/L, and the method limits of quantification (MLOQs) were 1.0-5.0 mg/kg for the target analytes. The feasibility of this method was demonstrated by the determination of FWAs in samples with spiked recoveries. The recoveries were in the range between 83.7% and 101.0%, and the relative standard deviations (RSDs) (n=6) ranged from 2.4% to 7.0%. This method is simple, and has high recoveries for the determination of FWAs in disposable sanitary products.
- high performance liquid chromatography (HPLC),
- fluorescent whitening agents (FWAs),
- disposable sanitary products,
- textiles
1. [1]
  [1] Liang R L. China Textile (梁瑞丽. 中国纺织), 2013(10): 104
2. [2]
  [2] Zhang Y. China Textile Leader (张艳. 纺织导报), 2011(5): 52
3. [3]
  [3] Chen L Y. Chemical Enterprise Management (陈礼英. 化工管理), 2014(19): 92
4. [4]
  [4] Yuan Y H, Zhu Y J, Tian M Z. Journal of Shanxi Datong University: Natural Science (袁跃华, 朱永军, 田茂忠. 山西大同大学学报: 自然科学版), 2010, 26(5): 40
5. [5]
  [5] Jiao Y N, Ding L, Zhu S H, et al. Chinese Journal of Chromatography (焦艳娜, 丁利, 朱绍华, 等. 色谱), 2013, 31(1): 83
6. [6]
  [6] Liu R Q, Gao L H, Wang W X, et al. Guangzhou Chemical Industry (刘荣琴, 高磊红, 王未肖, 等. 广州化工), 2013, 41(15): 135
7. [7]
  [7] Pan K L, Yang L, Liu Y, et al. Chemical Research and Application (潘可亮, 杨利, 刘勇, 等. 化学研究与应用), 2010, 22(9): 1210
8. [8]
  [8] Chen H C, Wang S P, Ding W H. J Chromatogr A, 2006, 1102: 135
9. [9]
  [9] Shu W C, Ding W H. J Chromatogr A, 2005, 1088: 218
10. [10]
  [10] Deng K F, Ren J L, Peng X L, et al. Food & Machinery (邓凯芬, 任佳丽, 彭湘莲, 等. 食品与机械), 2012, 28(3): 96
11. [11]
  [11] Du Z F, Xian Y P, Liu F J, et al. Chinese Journal of Analytical Chemistry (杜志峰, 冼燕萍, 刘付建, 等. 分析化学), 2014, 42(5): 636
12. [12]
  [12] Guo X D, Xian Y P, Luo H Y, et al. Anal Methods, 2013(5): 6086
13. [13]
  [13] Liang C X, Li C X, Li Q C, et al. Preventive Medicine Tribune (梁春霞, 李彩苋, 郦其昌, 等. 预防医学论坛), 2010, 16(3): 205
14. [14]
  [14] Xian Y P, Guo X D, Luo H Y, et al. Chinese Journal of Chromatography (冼燕萍, 郭新东, 罗海英, 等. 色谱), 2013, 31(2): 162
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