Citation: HUANG Qian, HE Man, CHEN Beibei, HU Bin. Magnetic solid phase extraction combined with gas chromatography-flame photometric detection for the determination of organophosphorus pesticides in juice samples[J]. Chinese Journal of Chromatography, ;2014, 32(10): 1131-1137. doi: 10.3724/SP.J.1123.2014.07028 shu

Magnetic solid phase extraction combined with gas chromatography-flame photometric detection for the determination of organophosphorus pesticides in juice samples

1.
Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Corresponding author: HU Bin,
Received Date: 18 July 2014

Fund Project: 国家自然科学基金项目(20975076). (20975076)

A novel method for the determination of organophosphorous pesticides (OPPs) in fresh juice samples was developed. Fe₃O₄@P(St-co-MAA) magnetic microparticles were synthesized and modified with styrene (St) and methacrylic acid (MAA) by coating St and MAA on magnetic particles and characterized by a series of techniques. The results indicated that Fe₃O₄ magnetic nanoparticles (MNPs) have been successfully modified with St and MAA. Based on the prepared Fe₃O₄@P(St-co-MAA) magnetic microparticles, a novel method of magnetic solid phase extraction (MSPE)-gas chromatography (GC)-flame photometric detection (FPD) was developed for the determination of OPPs. The extraction/desorption conditions of MSPE were optimized, and the analytical performance was evaluated under the optimal conditions. The limits of detection (LODs, S/N=3) for target OPPs were in the range of 0.013-0.305 μg/L with the RSDs (n=7) ranging from 3.1% to 8.8%. The enrichment factors varied from 406 to 951. The linear ranges were over three orders of magnitudes (R²>0.99) and the reproducibilities were 7.4%-14.5% (n=5). Finally, the proposed MSPE-GC-FPD method was successfully applied to the analysis of the five OPPs in fresh tomato and strawberry juice samples, with the recoveries of target OPPs in the range of 85.4%-118.9% for the spiked samples. The proposed MSPE-GC-FPD method is featured with low cost, fast separation and high enrichment factor.
1. [1]
  [1] Jimenez J J, Bernal J L, Toribio L, et al. J Chromatogr A, 2002, 946: 247
2. [2]
  [2] Zhou T, Xiao X, Li G. Anal Chem, 2012, 84: 5816
3. [3]
  [3] Song W, Lin S S, Sun G D, et al. Chinese Journal of Chromatography (宋伟, 林姗姗, 孙广大, 等. 色谱), 2012, 30(3): 318
4. [4]
  [4] Xiong J, Hu B. J Chromatogr A, 2008, 1193: 7
5. [5]
  [5] Rodrigues F D, Mesquita P R R, de Oliveira L S, et al. Microchem J, 2011, 98: 56
6. [6]
  [6] Jiang S X, Feng J J. Chinese Journal of Chromatography (蒋生祥, 冯娟娟. 色谱), 2012, 30(3): 219
7. [7]
  [7] Rissato S R, Galhiane M S, Knoll F R, et al. J Chromatogr A, 2004, 1048: 153
8. [8]
  [8] Chen X S, Bian Z Y, Yang F, et al. Chinese Journal of Chromatography (陈晓水, 边照阳, 杨飞, 等. 色谱), 2013, 31(11): 1116
9. [9]
  [9] Yu C, Hu B. J Sep Sci, 2009, 32: 147
10. [10]
  [10] Eskandari H, Naderi-Darehshori A. Anal Chim Acta, 2012, 743: 137
11. [11]
  [11] Maddah B, Shamsi J. J Chromatogr A, 2012, 1256: 40
12. [12]
  [12] Ding L, Wang H. Chinese Journal of Chromatography (丁兰, 王慧. 色谱), 2013, 31(2): 93
13. [13]
  [13] Zhang G J, Zang X H, Zhou X, et al. Chinese Journal of Chromatography (张贵江, 臧晓欢, 周欣, 等. 色谱), 2013, 31(11): 1071
14. [14]
  [14] Chen B B, Hu B, He M, et al. J Anal At Spectrom, 2013, 28: 334
15. [15]
  [15] Luo Y B, Shi Z G, Gao Q, et al. J Chromatogr A, 2011, 1218: 1353
16. [16]
  [16] Ma Z Y, Guan Y P, Liu H Z. J Polym Sci Pol Chem, 2005, 43: 3433
17. [17]
  [17] Xiao Q, Hu B, Yu C, et al. Talanta, 2006, 69: 848
18. [18]
  [18] Zhao E, Han L, Jiang S, et al. J Chromatogr A, 2006, 1114: 269
19. [19]
  [19] Lopez F J, Pitarch E, Egea S, et al. Anal Chim Acta, 2001, 433: 217
20. [20]
  [20] Wan Ibrahim W A, Veloo K V, Sanagi M M. J Chromatogr A, 2012, 1229: 55
21. [21]
  [21] Hu C, He M, Chen B, et al. J Chromatogr A, 2013, 1275: 25
22. [22]
  [22] Simplicio A L, Boas L V. J Chromatogr A, 1999, 833: 35
23. [23]
  [23] Li B N.[MS Dissertation]. Shanghai: Shanghai Jiao Tong University (李贝妮.[硕士学位论文]. 上海: 上海交通大学), 2008
1. [1]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
4. [4]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
5. [5]
  Junyuan Zhang , Zhiwei Miao . 有机磷杀虫剂的前世今生. University Chemistry, 2025, 40(6): 129-138. doi: 10.12461/PKU.DXHX202408118
6. [6]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
7. [7]
  Fengxiao Wang , Zhiwei Miao , Yaofeng Yuan . 有机磷化学与化学教学. University Chemistry, 2025, 40(8): 158-168. doi: 10.12461/PKU.DXHX202410077
8. [8]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
9. [9]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
10. [10]
  Shuai Yuan , Yaofeng Yuan . Academician Chengye Yuan and Organic Phosphorus Chemistry. University Chemistry, 2025, 40(7): 393-400. doi: 10.12461/PKU.DXHX202409123
11. [11]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
12. [12]
  Zelin Wang , Gang Liu , Mengran Wang , Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . Application of Instrumental Analysis in the Detection of Organic Components in Liquor. University Chemistry, 2025, 40(11): 318-326. doi: 10.12461/PKU.DXHX202502077
13. [13]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
14. [14]
  Yuanchun Pan , Xinyun Lin , Leyi Yang , Wenya Hu , Dekui Song , Nan Liu . Artificial Intelligence Science Practice: Preparation of Electronic Skin by Chemical Vapor Deposition of Graphene. University Chemistry, 2025, 40(11): 272-280. doi: 10.12461/PKU.DXHX202412052
15. [15]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
16. [16]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
17. [17]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
18. [18]
  Zhanxiang Liu , Chengshan Yuan , Jie Han , Shuanglian Cai , Qihan Zhang , Lin Wu , Yuan Zheng , Xingwen Sun , Qingwen Liu , Ying Xiong , Guangao Yu , Xin Du , Houjin Li , Jianrong Zhang , Shuyong Zhang . Recommendations for Basic Operations and Standards for Organic Chemical Extraction and Washing Experiments. University Chemistry, 2025, 40(5): 55-65. doi: 10.12461/PKU.DXHX202410039
19. [19]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
20. [20]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(363)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142